MOLECULAR DESIGN STUDY ON THE NEW ORGANIC NONLINEAR OPTICAL MATERIALS

In this paper, the second-order nonlinear-optical coefficients of a series of conjugated substituted polyenes have been calculated by the semi-empirical CNDO/S-CI method, we have studied in detail the influence on the number of substituents, the location of the substituents and the conjugation length in molecules to the NLO coefficient β The results showed that the introduction of the electronic donor and acceptor groups and the increase in the distance between the substituents and the conjugated length may lead to enhanced NLO responses. It is also shown that the calculated ln β_(vec) is linear with the number of double bonds in planar and linear trans substituted polyenes. A saturation effect in substitution is also presented. Based on these discussion one can provide the theoritical guidelines for designing and synthesizing of molecules with larger NLO coefficients.     

Graft Modification of N,N''''-methylene- bisacrylamide onto Silk in the Presence of Air

The graft modification of N, N'-methylene-bisacrylamide (NNMBAA) onto silk using eerie ammonium sulfate, potassium persulfate, ammonium persulfate and 2, 2-azobis (isobutyronitrile) as the initiators has been studied in the presence of air. To establish reaction conditions for the graft modification of NNMBAA onto silk, the effect of different variables such as the initiator concentration, monomer concentration, acetic acid concentration, time of polymerization, reaction temperature and liquor ratio (fabric: liq.) have been studied. The optimum grafting conditions were found. As evidence of grafting, analyses of amino acid composition and alkali solubility have been carried out. Grafting caused changes in amino acid composition and alkali solubility of silk. The observation has been explained in relation to structural changes in the grafted silk.     

Lotka—Volterra自催化振荡模型分析

本文对Lotka—Volterra提出的自催化振荡模型机理进行动力学分析,看化学振荡的线性和非线性特征。     

千山核桃叶中挥发油成份分析

利用水蒸汽馏方法提取了辽宁千山核桃叶中的挥发油，用毛细管ＧＣ／ＭＳ法从核桃叶的挥发油中分离鉴定了３２种化合物，占总量的７９．０９％。     

聚酯—聚氨酯稀溶液性质的研究——Ⅰ.单分散Mark—Houwink关系式的订定

本文采用特性粘数[η],重均分子量Mw和GPC,以宽分布的高聚物试样得到单分散的粘度—分子量关系式的方法,建立了由聚已二酸丁二醇酯(Mn=1750),4,4′—二苯基甲烷二异氰酸酯(MDI)和扩链剂1,4—丁二醇(BDO)形成的低硬含量聚氨酯在25℃时五种溶剂中的单分散Mark—Houwink关系式: DMF[η]=1.540×10~(-2) Mw0.748 THF[η]=1.211×10~(-2)Mw0.783 二氧六环:[η]=7.623×10~(-3)Mw0.820 环已酮[η]=1.157×10~(-2)Ww0.785 DMSO[η]=4.550×10~(-2)MW0.647 按照上述式子计算得到的Mη与单分散的Mark—Houwink关系式相吻合,而与试样的分布宽度无关。     

聚酯型脂肪族聚氨酯的合成及其表征

本工作分别利用本体一步和本体预聚法探索合成出一种新的组成变化范围较大的聚酯型脂肪族多嵌段聚氨酯(Aliphatic Segmented Polyurethane,简称ASPU)。利用元素分析、IR、~1HNMR,WAXD、DMA、SEM等对样品进行了较为全面的表征,发现ASPU与芳香族聚氨酯最大的不同是其抗溶剂性强,硬段结晶度高,并且硬段的晶胞参数与纯硬段相同。也不随硬段含量而变化。     

硝酸洗涤剂对磷钼酸铵沉淀组成的影响

本文通过实验证实,磷钼酸铵沉淀与硝酸洗涤剂之间发生离子交换作用。经用稀硝酸洗涤后,部分沉淀的组成由(NH_4)_3PO_4·12MoO_3·nH_2O转变成为(NH_4)_2HPO_4·12MoO_3·nH_2O。并由此提出化学式(NH_4)_2HPO_4·12MoO_3·nH_2O不能代表磷钼酸铵沉淀的初始组成。     

色心晶体微弱信号测试抗干扰技术的研究

色心晶体红外荧光信号在检测过程中,尤其检测其变化值会遇到一种十分微弱的光信号。为了将这种微弱光信号从各种干扰噪声中准确地检测记录下来,本文分析了各种干扰的起因,研究了相应的抗干扰技术,并在色心晶体荧光光谱仪组装过程中得到实际应用,提高了整机的信噪比,结果较为满意。     

嵌段聚酯型聚脲氨酯弹性体的合成与表征

本研究首先利用先本体预聚后溶液扩散链聚合的两步法合成了基于MDl,乙二胺和聚已二酸丁二醇酯(分子量1975和1228)的两系列嵌段聚酯型聚脲氨酯(PUU)弹性体,接着用元素分析,力学试验,GPC,IR,WAXD和SEM等技术对样品进行了全面表征.结果表明:PUU材料具有优异的力学性能.由WAXD和SEM研究发现:PUU中的软、硬段都是部分结晶的,晶体的尺寸依赖于硬段含量和软段分子量的变化.认为:PUU中存在着软、硬段两相微区,硬段微区被分散在由软段形成的基体中充当物理交联作用使材料表现出橡胶弹性性质.     

交联苯乙烯—4—乙烯基吡啶共聚物配位性能的研究

本文报导了交联苯乙烯-4-乙烯基吡啶共聚物(CSVPC)的配位性能的研究。实验中测定了CSVPC在一些有机溶剂中的溶涨度。本文制备了CSVPC第一过渡金属配合物,并用IR光谱证实不配合物的生成。观察了有机溶剂的溶涨度对CSVPC与第一过渡金属的配合反应的影响。