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151.
采用密度泛函理论,在B3LYP/6—31G(d)水平下,对苯并[1,2-b:4,5-b’]二噻吩(BDT)-thieno[3,4-b]thiadiaz01e(TD)的低聚物和聚合物进行了理论计算.其中,BDT为电子供体,TD为电子受体,以1:2的方式结合形成化合物,并计算了二面角、分子内的电荷传输、桥键键长和中心键电荷密度.结果显示:随着聚合链增长,共轭程度增加.NICSs值显示:中心环比边环的共轭程度更大.聚合物的能带结构表明:该聚合物的带隙比较低(0.87eV),故其可以作为潜在的导电材料. 相似文献
152.
Xiaohui Shi Cong Zhao Zuhan Cao Tuanwei Zhang Zhihua Wang Junwei Qiao 《自然科学进展(英文版)》2019,29(4):432-439
Dynamic compression tests under strain rates from 870 s?1 to 2100 s?1 were conducted for a near α Ti–8Al–1Mo–1V titanium alloy with equiaxed microstructure. Compression behavior, adiabatic shearing and band microstructure were investigated via characterization and calculation. The results demonstrate that all dynamic constitutive curves exhibited obvious stress fluctuation phenomenon with double increase-decrease changing stages at the primary stage of compression. The dislocation multiplication theory can be used to explain this phenomenon. After the stress fluctuation period, work hardening coexisted with the thermal softening, resulting in the slow hardening tendency in constitutive curves. J-C model was utilized to quantify the dynamic constitutive curves. The deviations between the predicted and experimental curves under high strain rates may be attributed to the over-consideration of thermal softening effect in J-C model. Adiabatic shearing band (ASB) began to form under the strain rate of 2100 s?1. A total shearing strain of 8.1 within ASB achieved in 8.9 μs, corresponding to a local strain rate of about 9.1 × 105 s?1 and is over 430 times of the macro strain rate. Post annealing was conducted on ASB before EBSD characterization. Due to the static recrystallization during annealing, the α phase within ASB generally presented as ultra-fine grains less than 1 μm in diameter. 相似文献
153.
James Bowers Hui Cao Geng Qiao Qi Li Gan Zhang Ernesto Mur Yulong Ding 《自然科学进展(英文版)》2018,28(2):225-234
Flow and heat transfer of aqueous based silica and alumina nanofluids in microchannels were experimentally investigated. The measured friction factors were higher than conventional model predictions at low Reynolds numbers particularly with high nanoparticle concentrations. A decrease in the friction factor was observed with increasing Reynolds number, possibly due to the augmentation of nanoparticle aggregate shape arising from fluid shear and alteration of local nanoparticle concentration and nanofluid viscosity. Augmentation of the silica nanoparticle morphology by fluid shear may also have affected the friction factor due to possible formation of a core/shell structure of the particles. Measured thermal conductivities of the silica nanofluids were in approximate agreement with the Maxwell-Crosser model, whereas the alumina nanofluids only showed slight enhancements. Enhanced convective heat transfer was observed for both nanofluids, relative to their base fluids (water), at low particle concentrations. Heat transfer enhancement increased with increasing Reynolds number and microchannel hydraulic diameter. However, the majority of experiments showed a larger increase in pumping power requirements relative to heat transfer enhancements, which may hinder the industrial uptake of the nanofluids, particularly in confined environments, such as Micro Electro-Mechanical Systems (MEMS). 相似文献
154.
This paper is concerned with the problem of guaranteed cost finite-time control of fractionalorder nonlinear positive switched systems(FONPSS) with D-perturbation. Firstly, the proof of the positivity of FONPSS with D-perturbation is given, the definition of guaranteed cost finite-time stability is firstly given in such systems. Then, by constructing linear copositive Lyapunov functions and using the mode-dependent average dwell time(MDADT) approach, a static output feedback controller is constructed, and sufficient conditions are derived to guarantee that the corresponding closed-loop system is guaranteed cost finite-time stable(GCFTS). Such conditions can be easily solved by linear programming. Finally, an example is provided to illustrate the effectiveness of the proposed method. 相似文献
155.
基于一种新定义的可调节二次隶属函数,研究了一类带有模糊资源约束的模糊二次规划模型,同时给出了两种相应的求解方法—扩展的Zimmermann算法和扩展的参数规划法。实例表明,两类方法均有一定的合理性和有效性。 相似文献
156.
微藻是生物柴油理想的原料,但微藻尺寸较小,细胞密度较低,导致微藻采收困难。为提高微藻的采收率,节约成本,实验采用自絮凝斜生栅藻Scenedesmus sp.-BH与富油小球藻C.vulgaris XJB共培养技术来提高小球藻C.vulgaris XJB的絮凝率,同时与调节p H、添加Fe Cl3和添加壳聚糖3种化学絮凝法对比。结果表明:3种化学絮凝法60 min时的最佳絮凝率分别为84.2%、96.5%和72.9%;共培养最佳条件下小球藻C.vulgaris XJB 60 min时的絮凝率为33.3%,8 h后的絮凝率可达73.2%。共培养条件下小球藻C.vulgaris XJB的絮凝率比化学絮凝法的稍低,但该方法不会引入有害化学物质,后期分离成本低,是一种经济、环保的絮凝方法。 相似文献
157.
曹文宏 《曲靖师范学院学报》2010,29(2):96-99
霍布斯基于人的自然性,运用机械唯物主义的方法,形成其完整独特的人性理论。他先从人性的“自然欲望公理”推出“一切人对一切人的战争”的自然状态;再由人的“自然理性公理”归结出的自我保全原则,导出人们为了摆脱这一自然状态而付诸理性发现的自然法。 相似文献
158.
发电用煤质量严重下降,已引起国家有关部门的高度重视,文章就如何客观公正、科学准确的做好电煤质量检验工作提出了一些建议. 相似文献
159.
创新型湖南评价系统分析 总被引:1,自引:0,他引:1
建设创新型湖南是一个非常复杂的系统工程,要实施好这个系统工程需要一个严谨科学的评价系统.创新型湖南的评价系统为"四个子系统、四过程、一整合"的模型,即"441"系统模型. 相似文献
160.
科技型中小企业技术创新的资金支持——基于生命周期视角的研究 总被引:1,自引:0,他引:1
基于生命周期的视角分析了科技型中小企业发展过程中各个阶段的特点,以及各个阶段中技术创新与资金支持的矛盾.在新的经济环境与政策条件下,构建了解决这种矛盾的资金支持体系,探讨了企业发展和技术创新过程中具体的融资方式,并且提出了相关的政策建议. 相似文献