一种新型咔唑衍生物的合成、表征和光学性质研究

介绍一种新型功能性的咔唑二羧酸配体--9-乙基-3,6-咔唑二甲酸(L1)的合成,用元素分析、红外光谱、质谱和核磁共振谱进行表征,测定其紫外吸收光谱和单光子荧光光谱.研究表明,该化合物具有好的紫外吸收和单光子吸收荧光效应.     

Effects of sulfur addition methods and Ca-Si treatment on the microstructure and properties of 30MnVS

The effects of sulfur addition methods and Ca-Si treatment on the microstructure and properties of free-cutting non-quenched and tempered steel 30MnVS were investigated by using optical microscopy, SEM and tensile test methods. The results show that sulfur addition methods influence the morphology of sulfides and the properties of 30MnVS slightly. Ca-Si treatment is beneficial for the formation of complex sulfides which normally have oxide cores, therefore, improving the distribution of sulfides in the tested steel and enhancing its toughness. The two methods, pyrite addition during LF process and S wire feeding during VD process, slightly influence the morphology and distribution of sulfides and the properties of 30MnVS; Ca addition not only promotes the nucleation of sulfides on the cores of calcium aluminate inclusions, but also creates modification effect on MnS, reducing the relative plasticity and hot deformability of sulfides during hot rolling process, thereby reducing the length/width value of sulfides and improving their distribution, and significantly enhancing its mechanical properties, in particular, the impact toughness increased by 30%.     

Fabrication of high nitrogen austenitic stainless steels with excellent mechanical and pitting corrosion properties

A series of high nitrogen austenitic stainless steels were successfully developed with a pressurized electroslag remelting furnace. Nitride additives and deoxidizer were packed into the stainless steel pipes, and then the stainless steel pipes were welded on the surface of an electrode with low nitrogen content to prepare a compound electrode. Using Si₃N₄ as a nitrogen alloying source, the silicon contents in the ingots were prone to be out of the specification range, the electric current fluctuated greatly and the surface qualities of the ingots were poor. The surface qualities of the ingots were improved with FeCrN as a nitrogen alloying source. The sound and compact macrostructure ingot with the maximum nitrogen content of 1.21wt% can be obtained. The 18Cr18Mn2Mo0.9N high nitrogen austenitic stainless steel exhibits high strength and good ductility at room temperature. The steel shows typical ductile-brittle transition behavior and excellent pitting corrosion resistance properties.     

四平市青少年学生余暇体育活动现状的调查及其对策研究

运用问卷调查和数理统计方法,对四平市青少年学生余暇体育活动的内容、时间、频数、场所、动因及影响因素等情况进行调查与分析,针对四平市青少年学生余暇体育活动的特点和现状提出了相应的对策和建议.     

低渗透双重介质垂直裂缝井产能分析

针对低渗透双重介质地层进行水力压裂后形成的有限导流垂直裂缝,结合沃伦-鲁特模型,利用质量守恒和椭圆流法建立了低渗透双重介质油藏椭圆流数学模型,并应用拉普拉斯变换,求得了低渗透双重介质有限导流垂直裂缝井无因次产量表达式。运用Stefest数值反演,绘制了无因次产量随时间变化的双对数特征曲线图,对影响低渗透双重介质油藏有限导流垂直裂缝井井底压力动态的诸多影响因素进行了分析。分析结果表明,随着生产时间推移,启动压力梯度对产能影响越来越显著。     

Reduction of 1-3 mm iron ore by H2 in a fluidized bed

The reduction of 1-3 mm fine powder of iron ore by H₂ was conducted in a lab-fabricated kg class high temperature fluidized bed. The results show that the differential pressure in the fluidized bed, which has small fluctuation with time, increases with the increase of gas flowing velocity. The utilization ratio of gas decreases when the reaction lasts longer time indicating that the reaction is faster at the beginning of reduction and becomes slower in the latter process. The higher the reaction temperature is, the higher the utilization ratio of gas is, but the difference of utilization ratio among the different temperatures becomes smaller with time. The utilization ratio of gas and the metallization ratio can reach 9% and 84% respectively at 750℃ for 20 min, which shows the reduction reaction by H₂ is very fast. The increase of metallization ratio with gas velocity performs quite good linearity, which shows that a higher velocity of reducing gas can be used to improve the productivity of the reactor when H₂ is used as reducing gas. With the increase of charge height, the metallization ratio decreases, but the utilization ratio of gas increases. The reaction temperature can be reduced to 700-750℃ from 800-850℃ when H₂ is used as reducing gas.     

发挥新疆旅游资源优势，打造欧亚大陆腹部旅游胜地

新疆维吾尔族自治区,幅员辽阔、汇聚了欧亚大陆多样而神奇的自然景观和各种民族文化风情,拥有得天独厚的旅游资源．近年来新疆的旅游业有了很大的发展,但尚有许多不足之处．文章认为,新疆旅游业的发展,应以千姿百态的自然景观和丰富多彩的民族文化为主线．努力发展快速交通、提高景点旅游基础设施档次,充分发挥多民族旅游资源优势,借助新疆地域特色开辟更多旅游品牌项目,尽快把新疆建成世界知名的欧亚大陆腹部旅游胜地．     

一种基于Petri网的服务组合流程分析方法

虽然业务流程执行语言(BPEL)有很多特征使它适合组合流程的描述,但它缺乏形式化语义,从而不能对组合流程进行严格的分析和验证。本文提出了一种基于Petri网的BPEL语言所对应的组合流程分析方法。应用Petri网来描述BPEL所定义的组合流程,描述组合流程的基本活动及它们之间关系,进而分析了组合流程结构上的合理性。通过实例网的构建,给出了流程可组合性的判定定理,并提出减少服务搜索空间的算法。最后,应用具体实例模拟组合流程的分析过程,展示了该方法的有效性。     

用户期望质量驱动的Web服务优化选取

提出了一种基于用户期望的服务质量评价方法。该评价方法仅考虑具有相似期望的用户,允许期望相似的评价影响服务的信誉度评价,以利于得到客观、准确的服务质量评估。在此基础上,提出一种基于用户期望的QoS驱动的服务选取算法。该算法实现了在满足用户偏好和期望的前提下Web服务的最优选取。电子购物的实例展示了该方法的可行性。     

CP自由基与C6H6反应机理的理论研究

在B3LYP/6-311++G(d,p)水平下研究了CP自由基与C6H6反应体系的产物分布和反应机理.得到了详细标注反应物、产物、中间体和过渡态的势能面示意图.计算结果表明CP+C6H6体系的主要产物是C6H5CP+H,次要产物是HCP+C6H5.与深入研究的CN+C6H6反应体系相比,CP和CN反应体系的机理完全相似.本理论计算可以为将来实验室分离和研究一些含有不饱和CP基团的物种提供非常有价值的信息.