大型电站汽轮发电机板翅式空-空冷却器优化设计

研究了大型电站汽轮发电机板翅式空ˉ空冷却器最优设计问题；建立了以最小质量为目标函数的最优设计数学模型，采用复形调优法编制了考虑工作条件、几何约束、热力参数约束的不同换热翅型的优化设计软件包，为扩大大型电站汽轮发电机的使用环境提供了条件。经比较分析，在给定约束条件下，锯齿形型面为最佳，其优化设计结果质量可减少约１６％。     

各种排样方式下顶点算法的研究

多边形顶点算法是冲裁排样优化问题的一种新算法。本文在单排顶点算法的基础上，对其它常用排样方式进行了研究，通过对原图形数组的适当拆分和重组构成新的多边形，即可采用在图形内求多边形顶点处宽度的算法。该算法不仅简化了计算，提高了运算速度，而且保证了最优解。     

刚性有限元与有限元耦合求解方法

提出刚性有限元（RFEM）与有限元（FEM）耦合求解方法，从能量原理导出了耦合矩阵方程，通过极限分析算例说明了该方法的可行性及有效性。     

非确定性 TS 模糊神经模型鲁棒性的统计判据

非确定性情况下的鲁棒性是智能控制系统不可避免的一个问题．本文将ＴＳ模型的模糊神经网络表达加以拓展，提出并证明了一种基于信息论统计测度的鲁棒性描述判据，该判据是由模糊神经网络、子波变换和信息论统计测度３个部分组成，着重体现了神经信号处理、可变分辨率和随机信号处理的综合，这就为分析智能控制系统的鲁棒性提供了一种有效的数学形式．该结论有助于非确定性智能控制系统的建模与智能控制器的设计．     

Electrochemical behavior of a series of azobenzene self-assembled monolayers on gold

Conclusion This work shows that the structures of C_n AzoC₂ (n = 1, 2, 3, 4) SAMs are significantly different and influence the observed electrochemical behavior of these novel azobenzene systems. The sluggish electron-transfer kinetics of azobenzene SAMs were explained by the alkyl spacer between azobenzene and electrode, the spatial inhibition for structural change in the redox process of azobenzene, as well as the ion-transportation barriers. For decrease of the apparent electrontransfer rate constants with increasing the length of end-groups, and the electrochemical inaccessibility of C₄AzoC₂ SAMs, the spatial inhibition for structure conformational change and ion-transportation was considered as the predominant factor.     

Organic solvents enhanced spectrofluorimetric method for determination of laccase activity

A novel fluorimetric method for determination of laccase activity in organic solvents is proposed, based on the oxidation ofo-phenylenediamine (1,2-diaminobenzene, OPDA) catalyzed by laccase yielding 2,3-diaminophenazine. The optimal conditions for laccase in organic media areT=55°C, pH=6.5, 1.0×10⁻²mol/L OPDA, 1.25 mL ethanol, 1.25 mL 1,4-dioxane and 1.25 mL acetone. The linear range of the method proposed in ethanol, 1,4-dioxane and acetone media were 0.44–19.33, 0.11–20.85, 0.38–21.05 U with the detection limit of 0.088, 0.022, 0.076 U, respectively. The proposed method has been applied to the analysis of laccase activity of real samples with more accurate and sensitive than that of the previous method reported. Supported by the National Natural Science Foundation of China and the Special Founds of State Education Committee for Doctorate Research Huang Zuyun: born in 1963, Ph.D     

The dissociation of nickel-oxine in surfactant micelles

The dissociation kinetics of Ni complex (NiL₂) of Oxine (HL) by H⁺ was investigated in neutral (Brij-35), cationic (CTAN), and anionic (SDS) micelles. The kinetic results have been interpreted by using the distribution model. The relevant distribution constants were determined independently by spectrophotometry. Supported by Natidnal Science Foundation of China Cai Ruxiu: born in Nov. 1939, Professor     

关于虚位移独立性的研究

从虚位移方程的基础解系出发探讨虚位移的独立性，并根据Четаев定义将其结果推广到高阶非完整系统。同时，根据对实位移的相应讨论，明确指出实位移是不相互独立的。     

己内酰胺与酰氯和酸酐反应的研究

己内酰胺在碱性介质中与酰氯反应,生成 N—酰基取代己内酰胺,后者也可以用相应的酸酐与己内酰胺在加热条件下制得。己内酰胺与等摩尔的邻苯二甲酰氯在碱性介质中的反应产物经水解后,和己内酰胺与等摩尔的邻苯二甲酸酐在加热条件下制得的产物不同。本文应用有机合成法并侧重用近代波谱解析阐明上述各步反应中的产物分子结构,澄清了文献中的分岐,合成了一些新化合物,提出上述有关反应的机理。     

工业企业热电联产系统评价准则的研究

评价热电联产系统的准则可分为能量利用性评价准则,经济性评价准则,以及能量利用与经济性相结合的评价准则。本文对现有各种准则进行了分析,找出了适用于评价工业企业热电联产系统的能量利用性准则和经济性准则,并在此基础上提出了新的能量利用与经济性相结合的评价准则——修正净现值。该新准则适用于评价工业企业热电联产系统,而现有的该类准则只能评价区域性热电厂。