润扬长江大桥结构损伤预警系统的设计与实现

研究了润扬长江大桥结构损伤预警系统的功能、体系结构、数据库和应用软件的设计与实现方法.提出了结构损伤预警系统的两级架构设计和两阶段实现方法,以保证结构损伤预警的实时性和准确性.建议采用Client/Server和扩展Browser/Server两种系统模式相结合的形式将结构健康监测系统与损伤预警系统相互结合,并采用MIMOSA数据库规范进行损伤预警数据库的设计.针对基于扩展Browser/Server模式的损伤预警软件特点,提出分别采用ActiveX技术和ASP技术实现客户端和服务器端应用的软件设计方法,并在此基础上编制了润扬长江大桥结构损伤预警系统软件.     

综合运输网络中合理路径优化模型

为了提高多式联运经营人运输决策的科学性和可行性,建立了一个含路径合理性约束的联合运输路径优化模型.从货运生产实践角度出发,提出了联合运输合理路径概念.基于联合运输的实现流程,指出除了运输效益最大化外,合理的换装序列和换装次数限制是联合运输路径选择和优化必须要考虑的另外2个重要特性.对于一般联合运输问题,研究了运输总费用的构成,即直线运输费用、节点中转费用和超期惩罚费用.通过构建直观的联合运输网络图,以总运输成本最少为优化目标,将多方式联合运输合理路径的选择和优化问题转化为含有超期惩罚因子的广义最短路模型,对模型的假设和数学形式做了详细的描述,并提供了简要的求解思路和参考算法.     

智能型太阳能充电电路设计

针对油田无线示功仪及其无线网络节点的供电问题,采用开关电源技术实现了太阳能组件电压变化或负载波动时自动调节占空比的供电网络,运用自动控制技术设计了过电压保护电路、过放电保护电路与应急充电电路等,采用充电管理技术实现了锂电池充电及电压调节电路,根据光敏传感器输出差值比较电压设计了太阳自动跟踪控制器.该太阳能充电电路思路新颖,在应用上是一种突破,工作效率达到92%,输出电压精度为98%,系统运行一年来,工作性能安全、稳定.应用证明具有较高的实用和推广价值.     

Optical nonlinearity and ultrafast dynamics of ion exchanged silver nanoparticles embedded in soda-lime silicate glass

Ag nanoparticles embedded in soda-lime silicate glass were fabricated by ion-exchange and subse-quently annealing method. Z-scan technique, femtosecond time-resolved optical Kerr effect （OKE） technique and femtosecond pump-probe experiment were used to investigate the effects of laser wavelength and laser pulse duration as well as annealing temperature on the third-order optical nonlinearity and ultrafast dynamics of the composites. It was found that the third-order susceptibility of Ag nanoparticles composite glass measured by 400 nm pulse source is larger than that measured by 800 nm pulse source due to an enhancement effect of local field near surface plasmon resonance of Ag nanoparticles in silicate glass. The third-order optical nonlinearity measured by ns laser source is about two orders of magnitude larger than that measured from fs pulse. The annealing temperature has an important effect on the third-order optical nonlinearity and ultrafast dynamics of the composites. Third-order nonlinear susceptibility up to 10^-l0 esu and fast relaxation process up to 0.2 ps have been obtained in Ag nanoparticles doped glass.     

SHRIMP U-Pb zircon age of tuff at the bottom of the Lower Cambrian Niutitang Formation,Zunyi, South China

A SHRIMP U-Pb zircon geochronology study of the tuff at the bottom of the Lower Cambrian Niutitang Formation at Songlin, Zunyi, South China yielded a mean ^206Pb/^238U age of 518±5 Ma. It is significantly younger than the Re-Os ages of 537--542 Ma for the overlying polymetallic Ni-Mo-PGE-rich layer in the basal Niutitang Formation at Songlin, suggesting that the Re-Os ages might represent that of the original magma chamber for the Ni-Mo-PGE-rich layer rather than the formation age of the strata. The intra-basinal stratigraphic correlation also implies that the absolute age of the Chengjiang biota should be younger than 518±5 Ma. Our new result, together with the SHRIMP U-Pb zircon age for the K-bentonite in the Zhongyicun member of the Zhujiaqing Formation at the Meishucun section, Yunnan Province, provides a temporal constraint for the Lower Cambrian of the Yangtze Platform in South China.     

Solvent effects on photophysical properties of copper and zinc porphyrins

The photophysics of Zn（tetraphenylporphyrin,TPP）, Zn（tetra-2,4,6-trimethylphenyl porphyrin, TMP）, Zn （tetra-（o-dichlorophenyl） porphyrin, TPPCI8）, Cu（tetraphenylporphyrin,TPP）, Cu（tetra-2,4,6-trimethyl- phenyl porphyrin,TMP）, and Cu（tetra-（o-dichlorophenyl） porphyrin, TPPCIE, TPPCI8） in several solvents have been investigated on steady state and time-resolved spectroscopy. The Cu（TPPCI8 ） is normal and shows no evidence of CT transition in the visible or near UV regions in nonpolar solvent. However, Cu（TPPCI8）shows a blue shift in the absorption spectrum and intramolecular CT bands at absorption spectra in polar solvent, which shows a fluorescence maximum emission at 650 nm and 8.4 ns lifetime. The reason can be attributed to two points. Firstly, the increase of solvent polarity can enlarge outer reorganisational energy, which is favorable to reduce the activation free energy of charger-transfer transition based on Marcus theory of electron transfer. Moreover, the internal heavy-atom effect on Cu（TPPCIE） is encouraging to stabilize the 2T1 state also, which increases the possibility of population to CT band from 2T1 state. This result is in accord with an earlier estimate of a 10 ns lifetime and CT absorption at 640 nm bands for the CT state of Cu （11） octethylporphyrins. Other possible reasons arousing unusual fluorescence like H-bonding, axial ligands, molecular aggregation are excluded.     

Relationship between the atmospheric heat source over Tibetan Plateau and the heat source and general circulation over East Asia

On the basis of NCEP/NCAR version I daily reanalysis data from 1971 to 2000 and by the methods of inverse calculation, correlation analysis and comparative analysis, the influences of atmospheric heat source （AHS） over the Tibetan Plateau on the large-scale AHS and the general circulation in summer are studied in this paper. The results show that AHS over the plateau in summer may trigger a heat source wavetrain propagating northeastward along the coast from the East Asian continent and West Pacific to Bering Strait-Arctic or even North America. In addition, if AHS over the eastern plateau is intense, South Asian High moves to southeast and West Pacific subtropical high moves to southwest; on the contrary, if AHS over the eastern plateau is weak, South Asian High moves to northwest and West Pacific subtropical high moves to northeast. Therefore, South Asian High and West Pacific subtropical high move in the horizontally-opposite directions in terms of interannual variation, for which AHS over the eastern plateau seems to be thermodynamically responsible.     

Analysis of biomarkers for the cross-linkage of formaldehyde with bovine serum albumin peptides

Formaldehyde, a well-known environmental toxic hazard, has been found to produce endogenously via semicarbazide-sensitive amine oxidase-catalyzed oxidative deamination of methylamine. In diabetes, the activity of SSAO has been found to increase with a subsequent increase in endogenous formaldehyde production. It has been postulated that SSAO-induced production of formaldehyde may be involved in the alteration of protein structure, which may subsequently cause protein deposition associated with chronic pathological disorders. Formaldehyde has also been found to react （cross-link） with amino group of the N-terminal amino acid residue and with the side-chains of arginine, cysteine, histidine and lysine residues. Therefore, formaldehyde may be responsible, at least in part, for protein cross-linkage, oxidative stress and cytotoxicity. The cross-linking of formaldehyde with bovine serum albumin was studied using LC-MS and Mascot database. The peptides sequence for control BSA （untreated） digested with trypsin was matched in the online database search query by exporting the MS/MS data to online MASCOT database. In this way, a total of twenty-seven peptides were matched in the database search query. These twenty-seven peptides were then searched manually in all of the tryptic BSA samples treated with different concentrations of FA that were incubated in different time intervals. Six formaldehyde-treated BSA peptides （FKDLGEEHFK, HLVDEPQNLIK, KVPQVSTPTLVEVSR, RPCFSALTPDETYVPK, LVNELTEFAK, DAFLGSFLYEYSR） were found to be the possible markers for formaldehyde-protein/peptides adducts.     

Bio-replicated forming of the biomimetic drag-reducing surfaces in large area based on shark skin

On the investigation of biomimetic drag-reducing surface, direct replication of the firm scarfskins on low-resistance creatures to form biomimetic drag-reducing surfaces with relatively vivid morphology relative to the living prototype is a new attempt of the bio-replicated forming technology. Taking shark skin as the bio-replication template, the hot embossing method was applied to the micro-replication of its outward morphology. Furthermore, the skins were jointed together to form the drag-reducing surface in large area. The results of the resistance measurements in a water tunnel according to the flat-plate sample pieces have shown that the biomimetic shark-skin coating fabricated by the bio-replicated forming method has significant drag reduction effect, and that the drag reduction efficiency reached 8.25% in the test conditions.     

Trace determination of zirconium using anodic adsorptive voltammetry at a carbon paste electrode modified with multi-walled carbon nanotubes

A carbon paste electrode modified with multi-walled carbon nanotubes （MWCNT） was prepared and the determination of ultra trace amount of zirconium based on the anodic adsorptive voltammetry of the zirconium-calcium-alizarin red S mix-polynuclear complex is described in this paper for the first time. The results showed that the sensitivity and the selectivity of the method are excellent. The second derivative linear scan voltammograms of the complex were recorded by polarographic analyzer from 200 to 1200 mV （vs. SCE） and it was found that the complex can be adsorbed on the surface of the electrode, yielding a peak at about 840 mV, corresponding to the oxidation of ARS in the complex. The peak current increases linearly with Zr （IV） concentration in the range of 6.0×10^-12--6.0×10^-11 mol. L^-1 （accumulation time 120 s）, 6.0×10^-11--2.0×10^-9 mol. L-1 （accumulation time 90 s） and 2.0×10^-9--1.0×10^-7 mol. L^-1 （accumulation time 60 s） and the detection limit （S/N = 3） is 2.0×10^-12 mol. L^-1 （accumulation time 180 s）. The procedure has been successfully applied to the determination of zirconium in the ore samples.