二元未知参数酸碱体系的一种图解计算法

根据Ivaska直线交点处理法的思想,提出一种能剔除电位滴定较差数据点,含有二元未知参数酸碱体系的计算方法。由于采用统计原理取舍数据,计算机进行全过程运算,不仅减少了原手工作图、目测判断的误差,而且大大提高了计算速度和精度。并且将此法推广应用于任意多元酸的二元混合物体系,同时编制了“IVASKA—PLOT(CO—PK)”计算机程序。     

SiH3+O2(3∑g)反应路径的理论研究

采用密度泛函B3LYP／6—311G^＊＊和高级电子相关耦合簇CCSD（T）／6-311G^＊＊。方法计算并研究了SiH3与O2（^3∑g）反应的机理，全参数优化了反应势能面上各驻点的几何构型，并用频率分析方法和内禀反应坐标（IRC）进行了计算，对过渡态进行了验证．结果表明：SiH3＋O2（^3∑g）反应可经多条路径和多个步骤，经缔合、氢转移和离解得到SiH3O2，SiH2O2＋H，SiH2O＋OH，SiH3O＋O，SiHO2＋H2等产物．     

云南兰坪-思茅盆地大平掌铜多金属矿床同位素地球化学与成矿年代学

大平掌铜多金属矿床是近年来在兰坪 -思茅盆地新发现的一个重要矿床 .该矿床产出于火山岩中 ,其构造背景及矿床地质特征均比较复杂 ,整个矿床由上部层状或透镜状的块状硫化物矿体和下部脉状及浸染状的矿体组成 .该矿床脉状矿体中石英流体包裹体Rb_Sr等时线年龄为 ( 1 1 8± 1 2 )Ma ,初始锶同位素组成为 ( 0 .70 80 0 7± 0 .0 0 0 0 3 7) ;流体包裹体研究表明成矿流体具有中低盐度 ( 2 .0～ 8.0wt %NaCl)和中低温度 ( 90～ 2 0 0℃ ) ;矿床中主要硫化物矿物的δ34S值在 - 0 .9‰～ 3 .5‰之间 ,集中在零值附近 .结合对以往的氢 -氧同位素和铅同位素研究结果的综合分析可以看出 ,大平掌矿床与区域内的脉状铜矿具有相似的地球化学特征 .因此认为大平掌铜多金属矿床为形成于燕山期的热液矿床 ,而不是前人认为的海底喷流沉积形成的块状硫化物矿床     

杂多核氰根桥联配合物的研究进展

随着超分子配位化学和材料科学的发展，分子磁体的设计合成与研究成为近来最引人注目的课题。氰基桥联配合物以其独特的光化学和物理性质，使得它在该领域占有尤为重要的地位。20世纪80年代以来，具有良好铁磁性的氰基桥联配合物的不断出现，大大促进了氰基桥配合物磁性分子的合成与研究工作。     

音乐分析学的学科发展概况

在音乐学科发展过程中,作为研究音乐作品宏观结构的曲式学,因其研究视野狭窄以及高度程式化的研究方法,其重要地位有所削减或正在逐步被音乐分析学所取代。在我国,音乐分析学作为一门独立的学科只是近十几年来的事情,但在西方,该学科的独立却要早得多。通过介绍音乐分析学重要的学术专著以及主要音乐分析方法,梳理国内外音乐分析学发展的历史轨迹,并对我国音乐分析学的学科建设提出自己的看法。     

对现代足球比赛进球策略分析

通过对第12届欧洲杯、第18届世界杯足球赛的224个进球的发动方式、进球成功率、进球前传球次数的分析,证实抢断球、任意球、点球、角球、界外球、球门球是现代足球进球的主要发动方式,进一步验证了查理.休斯的进球前传球次数越少,进球机率就越大的理论,并对“直接打法”提出新的观点和看法.     

A heat-driven thermoacoustic cryocooler capable of reaching below liquid hydrogen temperature

A "double-gas acoustic amplifier" is introduced to couple a thermoacoustic heat engine and a two-stage pulse tube cooler in this paper. Compared with previous acoustic amplifiers, this new acoustic amplifier maintains the function of amplification for pressure amplitude. In particular, the novel acoustic amplifier with a reservoir makes it possible to install an acoustic transparent but gas blocking elastic membrane between the engine and the cooler. Thus, the engine can use nitrogen as the working gas to work at low frequency; and meanwhile, the cooler can still use helium as the working gas to maintain its high performance. With this new amplifier, the cooling temperature of a two-stage pulse tube cooler driven by an energy-focused thermoacoustic engine reached 18.7 K.     

试论国外施工风险管理及对策

在集团公司“走出去”战略的指导下，施工企业积极开拓国外市场，承揽了多个施工项目。如何在复杂多变的国际市场中防范和控制工程施工风险是每个施工企业非常关注的问题。文章重点就国外施工的常见风险及应对策略做了概述。     

Morphology and contact mechanics influence adhesive characteristics of Dung Beetle’s bristle and Gecko’s setae

Geckos (Gekko gecko) use their hairy setae to adhere on various solid surfaces and dung beetles (Copris ochus Motschulsky) use their hairy bristles to anti-adhere in sticky environments. We study why two hairy systems express a conflict in functions by using SEM, histological approaches and functional experiments. Adhesion models and various parameters were collected and analyzed. Based on the morphological data and functional experimental results carried out by natural and denatured gecko setae and beetle bristles, we first demonstrated that the stiffness along the hair is 1000 to 30000 times that perpendicular to the hair. This stiffness difference is the key factor leading to the two hairy systems’ functional differences. Slope of gecko setae reduces contact stiffness, increases contact points and real contact area that results in amazing adhesive abilities. On the other hand, stiff bristles in a beetle have higher contact stiffness, which reduces the real contact area and decreases the adhesion between two contact surfaces. Deformation of gecko setae destroys the hierarchical structure, increases the contact stiffness and results in a decrease of adhesion forces. Similarly, deformation of beetle bristles destroys the erect structure of the hair, interconnects the separated bristles and thus decreases the anti-adhesive functions. These observations inspire us in designing anti-adhesive and adhesive biomimetic systems.     

Water-vapor source shift of Xinjiang region during the recent twenty years

The aim of this paper is to investigate the climate water-vapor sources of Xinjiang region and their shifts during the past 20 years. First, the principle and steps are roughly regulated to seek the water-vapor sources. Second, the climate stationary water-vapor transport in troposphere is calculated to distinguish where the water vapor comes from by ERA-40 reanalysis. In addition, the collocation between the transport and the atmospheric column water vapor content is analyzed. The results show that the major vapor comes from the west side of Xinjiang for mid-month of seasons, apart from July while the water vapor comes from the north or northwest direction. The water vapor sources are different for different seasons, for example, the Caspian Sea and Mediterranean are the sources in January and April, the North Atlantic and the Arctic sea in July, and the Black Sea and Caspian Sea in October, respectively. In recent ten years more water vapor above Xinjiang comes from the high latitudes and the Arctic sea with global warming, and less from Mediterranean in comparison with the case of 1973—1986. In fact, the air over subtropics becomes dry and the anomalous water vapor transport direction turns to west or southwest during 1987—2000. By contrast, the air over middle and high latitudes is warmer and wetter than 14 years ago.