生物酶法合成L-茶氨酸和聚谷氨酸的高效同步分离纯化

利用γ-谷氨酰转肽酶(γ-glutamyl transpeptidase,γ-GGT,EC 2.3.2.2)催化,以谷氨酰胺和乙胺为底物进行酶反应.反应后主要成分为L-茶氨酸和聚谷氨酸(poly γ-glutamic acid,PGA),杂质有氯离子、乙胺以及少量谷氨酰胺和谷氨酸.通过弱酸性阳离子树脂和弱碱性阴离子树脂...     

Acylation of nitriles to β-ketonitriles catalyzed by a heterometallic alkoxide cluster of neodymium and sodium： NdNa8（O^tBu）10（OH）

Catalytic acylation of nitriles with esters in the presence of 10 mol% NdNa8(OtBu)10(OH) is developed.The procedure is suitable for both enolizable and nonenolizable esters and affords β-ketonitriles in moderate to high yields.The heterometallic alkoxide cluster NdNa8(OtBu)10(OH) is structurally characterized by X-ray diffraction,and a mechanism for the production of β-ketonitriles using the cluster is proposed and verified.     

Rapid reductive degradation of azo dyes by a unique structure of amorphous alloys

An Fe-based amorphous alloy was found to significantly enhance the reductive degradation of an azo dye in aqueous solution. The surface-area normalized rate constant was up to 2.0 L m-2 min-1 at room temperature,an order of magnitude larger than any previously reported value. The activation energy of the degradation process was calculated according to the Arrhenius equation,and a much lower value than those previously reported was obtained. Valence band measurement indicated that a depressed valence band maximum and a widened empty band were established in the amorphous ribbon. The unique structure of the amorphous alloy is important-it may reduce the activation energy of the degradation process and enhance the activity of the electrons,thus accelerating the degradation process.     

Power law and small world properties in a comparison of traffic city networks

We analyze the statistical properties of the urban public bus networks of two cities (Beijing and Chengdu) in China. To this end, we present a comprehensive survey of the degree distribution, average path length, and clustering of both networks. It is shown that both networks exhibit small world behavior and are hierarchically organized. We also discuss the differences between the statistical properties displayed by the two networks. In addition, we propose a weight distribution approach to study the passenger flow through the public bus networks we considered. A hierarchical structure is observed here also.     

化学实验教学中培养中学生自我效能感的有效策略

自我效能感是指个体对自己是否能够成功地进行某一成就行为的主观判断。学生的自我效能感主要表现在其学习活动中,它是指学生在学习活动中对自己是否有能力完成学习任务和进行具体学习活动的能力的预测和估计,它体现了学生对自身学习的一种自信和期望。化学实验教学是化学教学的重要内容之一,它既受学生已有自我效能感的影响,又对于提高其自我效能感有重要作用。在化学实验教学中有效培养学生的自我效能感应该遵循若的干教学策略。     

三流异型连铸中间包结构优化的数值模拟

根据西宁特殊钢股份有限公司三流异型连铸中间包的结构和操作参数,提出中间包结构的优化方案,应用ANSYS CFX数值模拟软件计算不同控流装置下中间包内的流场和温度场分布,并建立物理模型对数值模拟的结果进行验证,确定最佳的优化方案。结果表明,原型中间包内流场和温度场分布不均匀,3个水口最大温差达3.11K,导致各水口处铸坯质量存在差异;使用U形挡墙后,中间包内钢液的流动特性得以改善,其成分和温度分布更为均匀,3个水口的最大温差仅为0.20K。     

界面剂对新旧混凝土界面粘结性能影响的试验研究

为研究界面剂对新旧混凝土界面粘结强度的影响及其粘结机理,进行未涂刷界面剂与涂刷水泥净浆、掺10%粉煤灰水泥浆、掺10%U型膨胀剂水泥浆、掺10%丁苯乳液水泥浆等5组Z形试件的直剪试验,测定各试件新旧混凝土界面的剪切强度;同时,采用显微硬度仪与扫描电子显微镜,分析界面过渡区的显微硬度值分布规律、微观结构形貌以及水化产物种类与分布特征.试验结果表明,新旧混凝土界面为薄弱区域,涂刷合适的界面剂可优化孔结构,改善界面密实度,增大新旧混凝土在微观层面上的机械咬合作用.此外,常用的4种界面剂中,水泥净浆和掺U型膨胀剂水泥浆的性价比相对较高.     

Carbon isotopic record of foraminifers in surface sediments from the South China Sea and its significance

Since the 1990s, the papers and data involved withthe South China Sea (SCS) have been emerging in largenumbers in the world as people pay more attention to thepaleoceanography of the SCS. There have been more than100 cores mentioned in papers containing p…     

发泡剂 ADC 生成过程传质与动力学分析

在间歇搅拌反应器中进行了发泡剂ADC生产过程传质与动力学研究 .考察了搅拌速度、氯气流量、辅助空气流量、固体联二脲浓度、粒度及反应温度对过程速率的影响 .分析了影响过程速率的主要因素 .研究结果表明 ,发泡剂ADC生产过程涉及极其复杂的气液固多相传递与反应过程 ,其中气相反应物氯气的溶解传质过程是影响整个过程速率的主要控制步骤     

苦瓜的营养成分研究

用自动定氮仪、氨基酸自动分析仪分析测定苦瓜 (Momordica charantia L .) 5个品种 (当地栽培苦瓜、长白苦瓜、长白 1号苦瓜、 89- 1苦瓜、 92 - 2苦瓜 )的干物质含量、维生维 C含量、可溶性糖含量、蛋白质和氨基酸、矿物质含量及其种子的蛋白质含量。结果表明 ,苦瓜果实含干物质 6 %～ 7% ,品种间的差异不显著 (P>0 .0 5 ) ;每 10 0 g嫩苦瓜中含维生素 C6 0～ 80 mg,可溶性糖 1.0 8～ 1.5 5 mg,品种间的差异都不显著 (P >0 .0 5 ) ;苦瓜果实的蛋白质含量为 1.3%～ 1.8%、总氨基酸含量为 1.3%～ 1.5 % ,种子蛋白质含量高达 39%～4 5 % ,各种成分相对含量有显著性差异 (P <0 .0 1) ,不同品种之间存在蛋白质多态性变化。苦瓜种子的营养价值很高。