Synthesis and Characterization of Poly[ 2, 2- （m-phenylene） -5, 5-bibenzimidazole ] in 1-butyl-3-methylimidazolium Chloride

Poly[2,2-(m-phenylene)-5,5-bibenzimidazole](mPBI)were synthesized by mixing 3,3’,4,4’-tetraaminobiphenyl and isophthalic acid in 1-butyl-3-methylimidazolium chloride([BMIM]Cl).Intrinsic viscosity of mPBI polymers was 0.67 dL/g which was measured in 96%sulfuric acid.The polymer was characterized by Fourier transform infrared spectroscopy(FTIR),nuclear magnetic resonance(1H-NMR),and thermogravimetric analysis(TGA).The effects of polymerization conditions on the intrinsic viscosity of mPBI were investigated.It showed that the molecular weight of polymer mainly depended on pre-reaction time and reaction temperature.Comparison of structure and properties of mPBI synthesized in ionic liquids(ILs)and polyphosphoric acid was also reported.It indicates that the ionic liquids are a kind of good solvents in synthesis process of mPBI and ionic liquids mainly affect molecular weight of mPBI.     

深化《分析化学实验》改革,培养农业拔尖人才

以培养农业拔尖人才为目标,对《分析化学实验》教学方式进行了改革。提出了优化课程结构,精选实验内容,改进教学方法、严格考核制度和加强师资队伍建设等改革措施。这些措施提高了实验教学效果,培养了学生的创新能力。     

时滞Belousov—Zhabotinskii系统行波解的存在性

研究时滞Belousov—Zhabotinskii系统行波解的存在性．首先利用变量代换将所研究的系统转化为常微分方程组,然后构造合适的上解和下解,得到系统行波解存在的充分条件．     

Tween-modified suspension array for sensitive biomolecular detection

Suspension arrays are attracting increasing interest for detecting and quantifying proteins, nucleic acids and other biomolecules. Among various suspension arrays, sillica-based suspension arrays which benefit from low fluorescence background and material stability have been widely used. Sillica-based suspension arrays are often manufactured with the popular aldehyde-aminosilane chemistry for the attachment of a variety of biomolecules. One drawback of this immobilization strategies is the relatively high array particles lost efficiency when washed by centrifugation. Due to this shortcoming, it is low reproductivity and limited in multiplex assay. Herein we report a novel method to fabricate Tween-coated suspension sillica particles, which could achieve good- reproductivity and the low limit of detection. Tween surfactants, each containing hydrophilic ethylene glycol head groups and a hydrophobic alkyl tail, prevent silica particles from being adsorbed onto the centrifuge tube wall and make beads resuspended well. Also, Tween with low fluorescence background could reduce non-specific protein adsorption. Also Tween surfactants are economic and facile agent. In this study, we demonstrate the preparation of the protein array to substantiate the applicability of our approach. Under the optimized experiment conditions, the limit of detection of our Tween-modified particles is as low as 50 pg/mL, which is sufficiently low for the current methods. We believe that the proposed method could provide a perspective on the improvement of self-encoded silica particle arrays.     

基于匹配度的政府服务渠道、用户与服务整合

针对网络、电话和现场三类主要的公共服务渠道,构建服务渠道、服务与用户三要素的评测指标,进一步提出三要素匹配度的概念及测算方法,最后给出进行三要素整合的方法模型,通过实例验证了方法的有效性.结果表明,该决策方法可以为政府规划服务渠道提供有益参考,优化渠道互补结构、整合渠道模式是最佳的服务传递途径.     

壳斗科栲属种子结构性防御与化学防御的权衡

植物从环境中能得到的资源有限,为了避免其种子被捕食(取食),植物进化出了多种防御方式,包括结构性防御与化学防御.作者对壳斗科栲属11个物种的种子的结构性防御以及化学防御进行了定量的测量分析,发现壳斗科栲属种子在结构性防御和化学防御之间存在权衡关系.即在栲属各个物种间,当结构性防御的投入增加时,化学防御的投入就会下降,结构性防御与化学防御之间呈现负相关关系,栲属种子的各个防御间的权衡关系是存在的;另一方面,不同的物种选择的防御对策不一样,有的物种选择结构性防御,如高山栲,有的物种选择化学防御,如藜蒴栲与苦槠.根据防御对策的差异,提出重新考虑个别物种的分类地位.     

利用局部线性嵌入的模态识别

提出了一种新的利用局部线性嵌入的模态识别方法。该方法以流形学习为理论基础,从提取结构的几何或固有特征出发,以系统结构的响应数据为分析对象,可识别出结构的模态参数。该方法的基本思想是,将结构的响应看作一个高维数据集,将系统的模态看作高维数据集的本质结构与固有特征,然后通过求解数据的低维嵌入进行模态参数识别。圆柱壳仿真结果表明:提出的利用局部线性嵌入的模态识别方法能够有效地进行模态参数识别;随着阻尼系数的增加,对于贡献量较大的模态,利用局部线性嵌入的识别效果优于基于主成分分析的识别效果。     

往复式压缩机管道系统气流脉动的数值与实验研究

通过实验和数值分析研究了两台往复式压缩机并机运行时管道系统中关键部位的气流脉动,根据计算流体动力学(CFD)方法建立了管道系统流体动力学模型,提出了合理的边界条件,分析了层流和湍流两种模型下管道系统中的气流脉动。通过实验数据对比发现,采用CFD方法中的湍流模型计算管道气流脉动比层流模型更加合理,进而研究了3种不同湍流模型下的气流脉动特性和压力不均匀度,结果表明,标准k-ε湍流模型在计算管道系统气流脉动时最为准确,并适用于研究分析不同转速的压缩机并机运行时管路间的相互影响,及各管路中气流脉动随压缩机转速变化的规律。     

小功率单相电机的单片机变频调速系统研制

针对以DSP、FPGA为主控器,采用三相逆变器变频调速单相电机存在系统较复杂、性价比较低、不利于小型化等缺点,提出以PIC单片机为核心的变频调速系统：根据双极性SPWM算法,CCP模块实现相位差为90℃的2路SPWM输出,由单边缘滞后电路扩展为具有死区时间控制的4路信号,通过隔离器件HCPL3120驱动H逆变桥,实现对单相电机从8—50Hz的变频调速．试验结果表明设计方法可行,效果理想．     

植物内生菌药用研究进展

植物内生菌能产生或生物转化出丰富的药理活性物质,因而成为新研究热点.本文综述了植物内生菌的次生代谢产物的药理活性,以及植物内生菌的生物转化研究.