Dynamic fracture by large extraterrestrial impacts as the origin of shatter cones

A large impact by a comet or meteorite releases an enormous amount of energy, which evaporates, melts and fractures the surrounding rocks. Distinctive features of such impacts are 'shatter cones', deformed rocks characterized by hierarchical striated features. Although such features have been used for decades as unequivocal fingerprints of large-body impacts, the process by which shatter cones form has remained enigmatic. Here we show that the distinctive shatter-cone striations naturally result from nonlinear waves (front waves) that propagate along a fracture front. This explains the observed systematic increase of striation angles with the distance from the impact. Shatter-cone networks, typically spanning many scales, can be understood as hierarchical bifurcations of the fracture front, which is generated by the immense energy flux carried by the initial, impact-generated, shock waves. Our quantitative predictions based on this theory are supported by field measurements at the Kentland and Vredefort impact sites. These measurements indicate that shatter cones near to the impact site were formed by fractures propagating at nearly the Rayleigh wave speed of the host rocks, whereas the furthest shatter cones observed (about 40 km from the impact site) were formed by fronts moving more slowly. These results provide insight into impact dynamics as well as dissipative mechanisms in solids subjected to sudden, extremely intense fluxes of energy.     

An intense stratospheric jet on Jupiter

The Earth's equatorial stratosphere shows oscillations in which the east-west winds reverse direction and the temperatures change cyclically with a period of about two years. This phenomenon, called the quasi-biennial oscillation, also affects the dynamics of the mid- and high-latitude stratosphere and weather in the lower atmosphere. Ground-based observations have suggested that similar temperature oscillations (with a 4-5-yr cycle) occur on Jupiter, but these data suffer from poor vertical resolution and Jupiter's stratospheric wind velocities have not yet been determined. Here we report maps of temperatures and winds with high spatial resolution, obtained from spacecraft measurements of infrared spectra of Jupiter's stratosphere. We find an intense, high-altitude equatorial jet with a speed of approximately 140 m s(-1), whose spatial structure resembles that of a quasi-quadrennial oscillation. Wave activity in the stratosphere also appears analogous to that occurring on Earth. A strong interaction between Jupiter and its plasma environment produces hot spots in its upper atmosphere and stratosphere near its poles, and the temperature maps define the penetration of the hot spots into the stratosphere.     

The remarkable metal-catalysed olefin metathesis reaction

Catalytic olefin metathesis--through which pairs of C = C bonds are reorganized--transforms simple molecules to those that are complex and precious. This class of reactions has noticeably enriched chemical synthesis, which is the art of preparing scarce molecules with highly desirable properties (for example, medicinal agents or polymeric materials). Research in the past two decades has yielded structurally well-defined catalysts for olefin metathesis that are used to synthesize an array of molecules with unprecedented efficiency. Nonetheless, the full potential of olefin metathesis will be realized only when additional catalysts are discovered that are truly practical and afford exceptional selectivity for a significantly broader range of reactions.     

On Indivisibles and Infinitesimals: A Response to David Sherry, “The Jesuits and the Method of Indivisibles”

In “The Jesuits and the Method of Indivisibles” David Sherry criticizes a central thesis of my book Infinitesimal: that in the seventeenth century the Jesuits sought to suppress the method of indivisibles because it undermined their efforts to establish a perfect rational and hierarchical order in the world, modeled on Euclidean Geometry. Sherry accepts that the Jesuits did indeed suppress the method, but offers two objections. First, that the book does not distinguish between indivisibles and infinitesimals, and that whereas the Jesuits might have reason to object to the first, the second posed no problem for them. Second, seeking an alternative explanation for the Jesuits’ hostility to the method, he proposes that its implicit atomism conflicted with the Catholic doctrine of the sacrament of the Eucharist, and was therefore heretical. In response to Sherry’s first criticism I point out that the Jesuits objected to all forms of the method of indivisibles, and that the distinction between indivisibles and infinitesimals consequently cannot explain the fight over the method in the seventeenth century. With regards to the Eucharist, I agree with Sherry that the Jesuits were indeed concerned about the method’s affinity to atomism and materialism, though for a different reason: these doctrines were antithetical to their efforts to impose divine hierarchy and order on the world. In as much as the technical details of the miracle of the Eucharist mattered, they provided no grounds for objecting to a mathematical (rather than physical) doctrine.     

Suitable energy platform significantly improves charge separation of g-C_3N_4 for CO_2 reduction and pollutant oxidation under visible-light

The photocatalytic activities of g-C_3N_4 can be significantly improved by increasing life time of the photogenerated charges. Here, in this work we introduced TiO_2 as proper energy platform to accept the photogenerated electrons from g-C_3N_4 during photocatalysis. The nanophotocatalysts formed from the combination of a suitable amount of TiO_2 nanoparticles and g-C_3N_4 nanosheets showed 8.75 and 4.22% enhancement in photocatalytic activities for CO_2 reduction and 2-chlorophenol(2-CP) degradation under visible light illumination as compared to bare g-C_3N_4. Based on the surface photovoltage spectra, photoluminescence spectra and examination of formed hydroxyl radicals, it was confirmed that these enhanced photoactivities were attributed to the much-improved charge separation via the electron transfer from g-C_3N_4 to TiO_2. From trapping experiments,it was found that hydroxyl radicals were the major species involved in the photocatalytic degradation of 2-CP.This study is helpful to synthesize efficient photocatalysts to cope with energy and environmental issues.     

Effects of the deep rolling process on the surface roughness and properties of an Al-3vol%SiC nanoparticle nanocomposite fabricated by mechanical milling and hot extrusion

Deep rolling is one of the most widely used surface mechanical treatments among several methods used to generate compressive residual stress. This process is usually used for axisymmetric components and can lead to improvements of the surface quality, dimensional accuracy, and mechanical properties. In this study, we deduced the appropriate deep rolling parameters for Al-3vol%SiC nanocomposite samples using roughness and microhardness measurements. The nanocomposite samples were fabricated using a combination of mechanical milling, cold pressing, and hot extrusion techniques. Density measurements indicated acceptable densification of the samples, with no porosity. The results of tensile tests showed that the samples are sufficiently strong for the deep rolling process and also indicated near 50% improvement of tensile strength after incorporating SiC nanoparticle reinforcements. The effects of some important rolling parameters, including the penetration depth, rotation speed, feed rate, and the number of passes, on the surface quality and microhardness were also investigated. The results demonstrated that decreasing the feed rate and increasing the number of passes can lead to greater surface hardness and lower surface roughness.     

How to Make Iranian Banks Customer Oriented with Use of Customer Relationship Management Concepts? Methodology and Comprehensive Architecture

This paper focuses on finding solutions to two important questions regarding making Iranian banks customer-oriented with the use of customer relationship management (CRM) concepts: What is a practical architecture for the CRM of a bank that can bring about benefits of CRM to the organization, and what is the method to achieve such architecture? This research uses an Action Research (AR) approach in one of the largest Iranian banks to achieve answers to the aforementioned questions. In brief, it concentrates on the AR cycle and its reflexes. In the plan stage, extended literature review, pioneer banks studies, and benchmarking provide a preliminary plan. Later, in the act stage this plan can be confirmed, extended, or customized based on more precise examination of the organization, managers and employees’ interviews, and customer opinion surveys. In the check stage, university and bank experts will review the plans and in the last stage of the cycle, reflected results, lessons, and experiences that help system design in the second bank will be discussed. The efficient method of achieving the CRM architecture (which in the beginning we had only general knowledge about) as well as the improvements that can be done based on experts’ opinions in order to receive more applicable results, are among the issues that will be discussed in this paper.     

Catalytic Z-selective olefin cross-metathesis for natural product synthesis

Alkenes are found in many biologically active molecules, and there are a large number of chemical transformations in which alkenes act as the reactants or products (or both) of the reaction. Many alkenes exist as either the E or the higher-energy Z stereoisomer. Catalytic procedures for the stereoselective formation of alkenes are valuable, yet methods enabling the synthesis of 1,2-disubstituted Z alkenes are scarce. Here we report catalytic Z-selective cross-metathesis reactions of terminal enol ethers, which have not been reported previously, and of allylic amides, used until now only in E-selective processes. The corresponding disubstituted alkenes are formed in up to >98% Z selectivity and 97% yield. These transformations, promoted by catalysts that contain the highly abundant and inexpensive metal molybdenum, are amenable to gram-scale operations. Use of reduced pressure is introduced as a simple and effective strategy for achieving high stereoselectivity. The utility of this method is demonstrated by its use in syntheses of an anti-oxidant plasmalogen phospholipid, found in electrically active tissues and implicated in Alzheimer's disease, and the potent immunostimulant KRN7000.     

Predictive power and unbiasedness of implied forward charter rates

This paper examines the efficiency and predictive power of implied forward shipping charter rates. In particular, we examine whether implied forward 6‐month time‐charter rates, which are derived through the difference between time‐charters with different maturities based on the term structure model, are efficient and unbiased predictors of actual future time‐charter rates. Using a dataset for the period January 1989 to June 2003, results of different statistical tests, including the cointegration approach, suggest that implied forward rates are in fact unbiased predictors of future time‐charter rates in the dry bulk freight market. In addition, it is found that implied forward rates yield superior forecasts compared to alternative univariate and multivariate time series models. However, while the unbiasedness hypothesis is found to hold, on average, we find that chartering strategies based on simple trend‐following trading rules in this cyclical market are able to generate economic profits even out‐of‐sample. This highlights how standard tests for unbiasedness do not always capture cyclical predictable components in the market behaviour. Copyright © 2007 John Wiley & Sons, Ltd.     

Sodium azide,an efficient inhibitor of protein diazotization

Résumé L'azide de sodium est un inhibiteur très efficace de la réaction de diazotation. Il réagit avec l'ion de diazonium à des molarités approximativement égales.