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41.
Metallic materials are the most used materials as orthopedic or dental implants due totheir excellent mechanical properties. However they are not able to create a natural bonding withthe mineralized bone and occasionally suffer localized corrosion. This work describes theelectrochemical behavior of a hybrid sol–gel thin film with the addition of green inhibitor. Thesefilms enhance the ability of the implant to make a union with the existing bone and improve itsresistance to aggressive environment. An ethanol solution of the polymerized vinyltrimethoxysilane(PVTMS) was mixed with an aqueous solution of henna extract (Lawsonia inermis) and refluxed togive homogeneous sols. Nanostructure hybrid PVTMS/henna thin films were deposited on thestainless steel 316L by spin-coating. The morphology, composition and adhesion of hybrid sol–gelcoatings have been examined by SEM, EDX and pull-off test, respectively. Addition of highadditive concentrations (0.1%) did not disorganize the sol–gel network. Direct pull-off testrecorded a mean coating-substrate bonding strength larger than 20.6 MPa for the hybrid sol–gelcoating. The effect of henna extract, with various added concentrations from 0.012% to 0.1%, onthe anticorrosion properties of sol–gel films have been characterized by electrochemical impedancespectroscopy (EIS) and potentiodynamic polarization tests in simulated body fluid (SBF) solutionand has been compared to the bare metal. Henna extract additions (0.05%) have significantlyincreased the corrosion protection of the sol–gel thin film to higher than 90%. The in vitrobioactivity of prepared films indicates that hydroxyapatite nuclei can form and grow on the surfaceof the doped sol–gel thin films. The present study shows that due to their excellent anticorrosion properties, bioactivity and bonding strength to substrate, doped sol–gel thin films are practicalhybrid films in biomedical applications. 相似文献
42.
Ali Rasooli Mehdi Divandari Hamid Reza Shahverdi Mohammad Ali Boutorabi 《矿物冶金与材料学报》2012,19(2):165-172
Based on the measurement of the released hydrogen gas pressure (PH2), the reaction kinetics between TiH2 powder and pure aluminum melt was studied at various temperatures. After cooling the samples, the interface of TiH2 powder and aluminum melt was studied. The results show that the 2 H PH2-time curves have three regions; in the first and second regions, the rate of reaction conforms zero and one order, respectively; in the third region, the hydrogen gas pressure remains constant and the rate of reaction reaches zero. The main factors that control the rate of reaction in the first and second regions are the penetration of hydrogen atoms in the titanium lattice and the chemical reaction between molten aluminum and titanium, respectively. According to the main factors that control the rate of reaction, three temperature ranges are considered for the reaction mechanism:(a) 700-750℃, (b) 750-800℃, and (c) 800-1000℃. In the first temperature range, the reaction is mostly under the control of chemical reaction; at the temperature range of 750 to 800℃, the reaction is controlled by the diffusion and chemical reaction; at the third temperature range (800-1000℃), the dominant controlling mechanism is diffusion. 相似文献
43.
基于网格追踪的临近预报外推(pixel-based nowcasting, PBN)算法能够预报降雨的平移、旋转和变形。为了评价该算法在长江三峡地区的应用效果, 该文利用三峡万县S波段雷达2010年汛期观测到的11场典型降雨过程, 采用相关系数、探测率、误报率、临界成功指数等4种评价指标对PBN算法进行验证。结果显示: 对于全部11场降雨, 该算法1小时预报结果与实际观测的相关系数接近0.6, 整体预报效果较好。在针对4场典型降雨的分析中所有4个指标均表明: PBN算法对独立且相对稳定的大面积层状降雨预报效果最好, 对包含多个对流型雨团生成与消亡的降雨预报效果最差。 相似文献
44.
Davila S Furu L Gharavi AG Tian X Onoe T Qian Q Li A Cai Y Kamath PS King BF Azurmendi PJ Tahvanainen P Kääriäinen H Höckerstedt K Devuyst O Pirson Y Martin RS Lifton RP Tahvanainen E Torres VE Somlo S 《Nature genetics》2004,36(6):575-577
Mutations in PRKCSH, encoding the beta-subunit of glucosidase II, an N-linked glycan-processing enzyme in the endoplasmic reticulum (ER), cause autosomal dominant polycystic liver disease. We found that mutations in SEC63, encoding a component of the protein translocation machinery in the ER, also cause this disease. These findings are suggestive of a role for cotranslational protein-processing pathways in maintaining epithelial luminal structure and implicate noncilial ER proteins in human polycystic disease. 相似文献
45.
46.
This study investigated the effect of Zn foil layers on the microstructure and corrosion characteristics of friction stir welded aluminum alloy 5754. Samples of various joints were prepared by applying different rotational and welding speeds, and their microstructures were evaluated via a metallographic technique and scanning electron microscopy equipped with energy-dispersive X-ray spectroscopy elemental analysis. The anticorrosion behavior of joints in the absence and presence of a Zn interlayer was studied by cyclic potentiodynamic polarization test in 3.5wt% NaCl aqueous solution, and sound welds were obtained in the presence of the Zn interlayer foil. The results revealed that the joint made at a rotational speed of 800 r/min and traveling speed of 15 mm/min achieved a chemical composition identical to that of aluminum alloy 7xxx series, and as such, it showed the best resistance to corrosion. 相似文献
47.
Mechanical activation(MA) of malachite was carried out by dry planetary grinding(DPG) and wet Isa grinding(WIG) methods. When the rotational speed was increased to 400 r/min in DPG, the specific surface area of malachite reached the maximum and the particle size reached the minimum of 0.7–100 μm. Agglomeration occurred between mineral particles when the rotational speed was increased to 580 r/min in DPG.However, no agglomeration was observed among particles with sizes 0.4–3 μm in WIG. X-ray diffraction analysis showed that, at a 580 r/min rotational speed in DPG, the amorphization degree of malachite was 53.12%, whereas that in WIG was 71.40%, indicating that MA led to amorphization and distortion of crystal structures. In addition, in the Fourier transform infrared(FT-IR) spectra of activated malachite, the bands associated with –OH, CO_32-and metal lattice vibrations of Cu–O and Cu–OH were weakened, and a new H–O–H bending mode and peaks of gaseous CO_2 appeared, indicating that MA decreased the band energy, enhanced dihydroxylation, and increased the chemical reactivity of the malachite.Furthermore, the leaching behavior of copper ore was greatly improved by MA. 相似文献
48.
Pairing of electrons in conventional superconductors occurs at the superconducting transition temperature T(c), creating an energy gap Delta in the electronic density of states (DOS). In the high-T(c) superconductors, a partial gap in the DOS exists for a range of temperatures above T(c) (ref. 2). A key question is whether the gap in the DOS above T(c) is associated with pairing, and what determines the temperature at which incoherent pairs form. Here we report the first spatially resolved measurements of gap formation in a high-T(c) superconductor, measured on Bi2Sr2CaCu2O8+delta samples with different T(c) values (hole concentration of 0.12 to 0.22) using scanning tunnelling microscopy. Over a wide range of doping from 0.16 to 0.22 we find that pairing gaps nucleate in nanoscale regions above T(c). These regions proliferate as the temperature is lowered, resulting in a spatial distribution of gap sizes in the superconducting state. Despite the inhomogeneity, we find that every pairing gap develops locally at a temperature T(p), following the relation 2Delta/k(B)T(p) = 7.9 +/- 0.5. At very low doping (< or =0.14), systematic changes in the DOS indicate the presence of another phenomenon, which is unrelated and perhaps competes with electron pairing. Our observation of nanometre-sized pairing regions provides the missing microscopic basis for understanding recent reports of fluctuating superconducting response above T(c) in hole-doped high-T(c) copper oxide superconductors. 相似文献
49.
Güler AD Ecker JL Lall GS Haq S Altimus CM Liao HW Barnard AR Cahill H Badea TC Zhao H Hankins MW Berson DM Lucas RJ Yau KW Hattar S 《Nature》2008,453(7191):102-105
Rod and cone photoreceptors detect light and relay this information through a multisynaptic pathway to the brain by means of retinal ganglion cells (RGCs). These retinal outputs support not only pattern vision but also non-image-forming (NIF) functions, which include circadian photoentrainment and pupillary light reflex (PLR). In mammals, NIF functions are mediated by rods, cones and the melanopsin-containing intrinsically photosensitive retinal ganglion cells (ipRGCs). Rod-cone photoreceptors and ipRGCs are complementary in signalling light intensity for NIF functions. The ipRGCs, in addition to being directly photosensitive, also receive synaptic input from rod-cone networks. To determine how the ipRGCs relay rod-cone light information for both image-forming and non-image-forming functions, we genetically ablated ipRGCs in mice. Here we show that animals lacking ipRGCs retain pattern vision but have deficits in both PLR and circadian photoentrainment that are more extensive than those observed in melanopsin knockouts. The defects in PLR and photoentrainment resemble those observed in animals that lack phototransduction in all three photoreceptor classes. These results indicate that light signals for irradiance detection are dissociated from pattern vision at the retinal ganglion cell level, and animals that cannot detect light for NIF functions are still capable of image formation. 相似文献
50.
A common feature of the single-walled carbon-nanotube field-effect transistors fabricated to date has been the presence of a Schottky barrier at the nanotube--metal junctions. These energy barriers severely limit transistor conductance in the 'ON' state, and reduce the current delivery capability--a key determinant of device performance. Here we show that contacting semiconducting single-walled nanotubes by palladium, a noble metal with high work function and good wetting interactions with nanotubes, greatly reduces or eliminates the barriers for transport through the valence band of nanotubes. In situ modification of the electrode work function by hydrogen is carried out to shed light on the nature of the contacts. With Pd contacts, the 'ON' states of semiconducting nanotubes can behave like ohmically contacted ballistic metallic tubes, exhibiting room-temperature conductance near the ballistic transport limit of 4e(2)/h (refs 4-6), high current-carrying capability (approximately 25 micro A per tube), and Fabry-Perot interferences at low temperatures. Under high voltage operation, the current saturation appears to be set by backscattering of the charge carriers by optical phonons. High-performance ballistic nanotube field-effect transistors with zero or slightly negative Schottky barriers are thus realized. 相似文献