复杂轮廓曲线的样条插补与速度规划方法

针对复杂轮廓曲线数控加工高速高精度控制要求,基于B样条曲线理论,提出了3次B样条曲线插补算法,通过预判加工速度,采用3次B样条曲线不同段间连接点的切矢量求解,建立以时间为参数的样条曲线方程,同步完成插补轨迹规划和速度规划.经过仿真分析表明,该算法的计算效率高,可满足加工精度与速度平滑要求.     

新型全自动抓斗卸船系统

针对抓斗卸船机司机劳动强度大、安全性低、机械可靠性无法保证等一系列难题,首创性地提出了一套全自动化卸船作业方案。对该方案做出了详细阐述,包括系统运行模式、作业流程和几种策略优化方法,并与传统卸船工艺做了综合详尽的对比分析。该全自动抓斗卸船机在上海港罗泾矿石码头实施后,经过轻重载调试目前已投入正式生产。对装备性能的全面测试结果证明,与传统作业方式相比,该系统作业效率显著提高,人员劳动强度大幅降低,同时为机械运行可靠性和安全性提供了有力保障。     

Effects of -NO2 and -NH2 functional groups in mixed-linker Zr-based MOFs on gas adsorption of CO2 and CH4

This study was undertaken to evaluate the effects of mixing BDC-NO_2 and BDC-NH_2 linkers in the synthesis of Zrbased metal organic frameworks(Zr-MOFs) on their adsorption and separation of CO_2 and CH_4. Ui O-66 with single or binary-NO_2 and-NH2 samples were synthesized under solvothermal conditions and activated by solvent exchanging using methanol. Structural analyses of the materials were conducted using FTIR, XRD, TGA,SEM,1 HNMR and N2 adsorption/desorption techniques and adsorption of CO_2 and CH_4 at high pressures and different temperatures(273 and 298 K) was investigated. It was found that Ui O-66-NH2 exhibited higher CO_2 and CH_4 adsorption capacities than those of Ui O-66-NO_2. Addition of-NH_2 functional group in Ui O-66-NO_2 could enhance CO_2 and CH_4 adsorption due to the extra CO_2 adsorption sites of-NH_2 functional groups. Addition of-NO_2 functional group to Ui O-66-NH2 at a low loading could also increase CO_2 and CH_4 adsorption, however,a high loading of NO_2 functional group to Ui O-66-NH2 would result in decreased adsorption.     

挤压工艺对可生物降解 Mg–5Zn–1.5Y 镁合金显微组织及力学性能和腐蚀性能的影响

本研究分析了挤压温度和挤压比对 Mg–5Zn–1.5Y 合金的显微组织、硬度、压缩和腐蚀行为的影响。显微组织观察表明，铸造合金由α-Mg晶粒和Mg₃Zn₆Y和Mg₃Zn₃Y₂金属间化合物组成，主要位于α-Mg晶界上。较高温度下的挤压合金显示出较粗的晶粒微观结构，而以较高比率挤压的合金含有较细的微观结构，尽管在两种条件下都测量到具有较低金属间化合物的更多动态再结晶晶粒。较低温度 (340°C) 和较高比率 (1:11.5) 的组合条件提供了较高的抗压强度。然而，没有实现显着的硬度改善。挤压工艺可以降低铸造合金在模拟体液中的腐蚀率超过 80%，这主要是由于细化了微观结构。与挤压比相比，挤压温度对耐腐蚀性能的影响更为显着，挤压温度越高，耐腐蚀性能越高。