Self-assembling Characteristics of Amphiphilic Star Block Copolymers with a Polyelectrolyte Shell

1 Results Amphiphilic block copolymers are capable of forming supramolecular assemblies resembling those observed in nature,such as spherical micelles,worm micelles,and vesicles.Changing the solvent composition,ionic strength or pH of the polymer solution may induce the self-assembly of block copolymers or trigger the transition between the geometries of noncovalent assemblies.In the current work,we have synthesised starlike amphiphilic block copolymers having hydrophobic poly(methyl methacrylate),PMMA,core,and hydrophilic poly(acrylic acid),PAA,shell.The self-assembling characteristics of these polymers have been investigated in aqueous solutions by light scattering and direct visualisation by cryo-transmission electron microscopy (cryoTEM)[1]. Computer simulations along with the theoretical predictions made for the star-like system based on mean-field theory have been used to support the experimental observations[2]. The association of the starlike macromolecules resembles that of charged biopolymers,such as actin,since a balance between attractive and repulsive forces is required for the formation of cylindrical assemblies and can be manipulated by changing the pH or the ionic strength of the solvent[3].     

新型降血脂药用化合物——山梨酸衍生物的研究

采用酰氯法合成了一种山梨酸衍生物--N-异丁基山梨酰胺.降血脂药效实验发现,N-异丁基山梨酰胺在预防性高血脂症动物实验中,表现出降低血清TC值(P=0.0858)和显著降低血清LDL-C(P=0.0116)的功效,具有良好的降血脂作用.     

浅析体育专业民族学生汉语交际能力的培养

文章通过体育教育专业少数民族学生汉语交际能力的观察,对怎样在体育教学中更好地利用专业汉语课程提高少数民族学生交际能力,对体育专业汉语课程教材、课堂组织、教学方法,交际活动等四个方面进行了分析,对教学中的一些常见的做法作出了初步的探讨。     

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