Nanoengineering of amino - functionalized mesoporous silica nanospheres as nanoreactors

Selective functionalization of mesoporous silica nanospheres (MSNs) is crucial for nanoengineering of MSNs. Herein, we have combined “surface-protected etching strategy” and “cationic surfactant assisted etching strategy” to prepare functionalized MSNs with externally attached amino groups. The externally attached NH2 groups endow the catalysts with excellent catalytic performance for nitroaldol reaction between nitromethane and benzaldehyde. In addition, those NH2-MSNs can also be used to support gold nanoparticles, which display very good catalytic performance for reduction of 4-nitrophenol. It can be envisioned that the synthesis protocol developed in this work could also be extended to nanoengineered MSNs, which provides opportunities for nanoreactors design.     

Experimental validation of inter-subspecific genetic diversity in rice represented by the differences between the DNA sequences of ‘Nipponbare’ and ‘93-11’

The pedigrees of three sequenced rice cultivars were analyzed to show that a majority of the genetic composition of 'Nipponbare' originates from japonica cultivars while the minority originates from indica cultivars. In contrast, '93-11' is derived mainly from indica cultivars with a smaller contribution from japonica cultivars. All ancestors of 'Guang lu ai 4' appeared to be indica lines. A set of molecular markers (46 InDels and 53 SSRs) polymorphic between 'Nipponbare' and '93-11' were examined in 46 typical indica and 47 typical japonica cultivars selected from 443 accessions according to Cheng's index. All cultivars were divided into indica and japonica groups without overlapping when clustered by Cheng's index, InDels and SSRs. Much higher InDel and SSR diversity between groups than within groups implies that the marker polymorphisms between 'Nipponbare' and '93-11' represent a large proportion of inter-subspecific diversity. About 85% of indica cultivars and more than 90% of japonica cultivars were confirmed to have the same PCR banding patterns as '93-11' and 'Nipponbare', respectively. Some polymorphic loci between 'Nipponbare' and '93-11' cannot be validated in other indica and japonica cultivars, either as subspecies-specific but not predominant alleles, or alleles not specific between the two groups. It was concluded that molecular markers developed from sequence polymorphism between 'Nipponbare' and '93-11' often represent inter-subspecific diversity, although some exceptions were sensitive to either particular marker loci or particular cultivars.     

变数据窗阻抗算法的频域分析方法研究

分析典型变数据窗阻抗算法的估计原理和特点 ,提出了一种适用于不同阻抗估计算法的新型频率响应计算方法 ,为不同算法的频域特性分析和比较提供了共同的基础 .该方法也可用于对算法抑制非周期分量的性能进行分析研究     

美国对付外星人的武器

美国国家航空航天局发布消息说,1977年发射的"旅行者1号"探测器已抵达太阳系边缘,这意味着"人类第一个星际使者"有望不久后首次脱离太阳系,进入星际空间。那让我们天马行空地想象一下,假如"人类星际使者"遭遇外星人怎么办?或者,更糟糕的情况,如果将并不友善的外星人引到地球,向人类发起袭击又该怎么办?人类在抵御外星人入侵时,是否已掌握合适的     

Preparation and characterization of doubly substituted microwave absorbing material by sol-gel technique for super high frequency applications

Rare earth Dy~(3+)and divalent Mn~(2+)elements substituting W-type hexagonal ferrites Ba_(1-x)Dy_xZn_2Fe_(16-y)Mn_yO_(27)(x=0,0.02,0.06,0.1 and y=0,0.1,0.3,0.5)were prepared by sol-gel method.The thermo-gravimetric analysis(TGA)and differential scanning calorimetry(DSC)was carried out to find the temperature at which single phase can be obtained.XRD patterns indicate the presence of the single phase for all the synthesized samples with the absence of any extra peak due to unreacted material and secondary phases.The occurrence of absorption bands at low wave numbers(563 and 446 cm~(-1)),can be assigned to the stretching vibration of metal and oxygen ions in FTIR spectra,which also confirms the single hexagonal phase for prepared material.The grains are of platelet like structure,which enhances the microwave absorption properties of hexagonal ferrites.The synthesized material exhibits the minimum reflection loss of-20.9 dB at 11.8 GHz frequency,which reflects the applications of this material in super high frequency devices.The microwave conductivity of the material increases with frequency.     

基于Unity3D平台的三维可视化校园系统开发研究

虚拟现实技术和三维建模技术是虚拟校园建设的主要技术. 以内蒙古师范大学赛罕校区为研究区域,利用GIS、遥感、三维建模技术、图像处理等技术进行了三维建模,全面、详细、生动地描绘出了校园的三维场景. 结果表明,Unity3D平台开发出的系统具备较好的开发接口,体现较强的直观性和跨平台性等特点,为用户提供了优越的体验和视觉效果.     

结晶条件对聚丙烯-聚异丁烯共混物形态和性能的影响

通过WAXS,SAXS和拉伸试验对聚丙烯-聚异丁烯共混物进行了表征,讨论了结晶条件和共混物的组成对其形态和拉伸行为的影响,与室温淬火试样相比,等温结晶试样具有较高的结晶度、较厚的晶片、较高的拉伸模量及强度、较差的韧性,PIB的存在导致iPP结晶度降低,力学性能变差。     

Effect of Electromagnetic Fields and Explosions on Seismicity and Geodynamic Consequences

The change in seismicity of the Garm region in Tajikistan after an irradiation of its crust with high energy electromagnetic pulses (EP) and after the Semipalatinsk nuclear explosions (NE) is considered. It’s shown that the influence of EP, as well as NE, causes a statistically significant increase in the seismic activity and speed up the seismic energy release. Two areas of anomalous increase in seismic energy after irradiation and explosions adjoined to active faults were identified within the region. Both have a complex configuration in the form of two “petals” located in different sides of those faults. In both cases, one of the “petals” appears after EP, and the second after NE. It is shown that each of these “butterflies” constitutes as a whole anomalous area in which there are high tectonic stresses. The impact of NE has also been studied before beginning and after completion of these experiments. In both cases, those anomalous areas were not observed. Moreover after those experiments were completed, on distances of 50~70 km from the EP source no high stresses areas were observed at all. Consequently, the irradiation of the crust caused their relaxation on the area of about 3 500 km2. However,judging by the appreciable rise in seismicity caused by NE on the southwestern and southeastern margins, stresses had been increasing on periphery of the irradiated area.     

某些交错群和对称群的刻划

设G为群,π_e(G)为G中元的阶之集.在文献中作者证明了G(?)A_n当且仅当(1)π_e(G)=π_e(A_n),(2)|G|=|A_n|.对某些交错群,如A_5,A_7,A_8可以仅用上述条件(1)加以刻划.在文献中作者证明了对所有的对称群S_n,n≥2,可用上述条件(1)和(2)加以刻划.然而,对群S_i,i=2,3,…,6均不能由条件(1)单独确定.     

新疆高校足球选项课教学的现状及时对策研究

采用问卷调查法、文献资料法、访谈法．逻辑分析法对当前新疆高校开设足球选项课教学的现状进行分析,提出了应转变足球教学的指导思想改革现有的足球教学模式、建足球健身教学体系、丰富教学内容和教学形式、完善教学考核评价制度等对策与建议,以尽快解决当前高校足球教学中的问题,使之在素质教育中发挥更大的作用。