Metabolism of 3β-hydroxycholest-5-en-26-oic acid in hamsters

Summary Metabolism of 26-hydroxycholesterol to 3-hydroxychol-5-en-24-oic acid and other C24-bile acids has been expected to occur by way of 3-hydroxycholest-5-en-26-oic acid in studies in vitro. 3-Hydroxycholest-5-en-26-oic acid was infused intravenously into bile fistula hamsters and the following C24-bile acids were identified: 3-hydroxychol-5-en-24-oic acid, lithocholic acid, chenodeoxycholic acid, and a small amount of cholic acid.     

外加电磁场对火焰结构及燃料燃烧特性的影响

燃料在电、磁场作用下的燃烧是一个新的跨学科性质的研究课题.它涉及磁流体发电、空间技术中电磁燃烧技术的应用以及能源与动力工程中能量转换与效率.本文从实验和理论两个方面,扼要地报导了碳氢燃料在外加磁场、电场影响下的火焰结构及其燃烧特性.把近年来我研究小组的主要研究结果汇总发表.     

Occurrence of 3-epi-22-deoxy-20-hydroxyecdysone and its phosphoric ester in diapause eggs of the silkworm,Bombyx mori

Ecdysteroids in diapause eggs of the silkworm,Bombyx mori, were analyzed using high-performance liquid chromatography (HPLC) combined with radioimmunoassay (RIA). A relatively large amount of an unidentified free ecdysteroid and its phosphoric ester (conjugated form) were detected. These two compounds were isolated by a combination of column chromatography on silicic acid, thin-layer chromatography (TLC), and HPLC using a reverse-phase (RP) column. The purified compounds were identified as 3-epi-22-deoxy-20-hydroxyecdysone (22d20E) and 3-epi-22-deoxy-20-hydroxyecdysone 2-phosphate (22d20E2P) by means of mass spectrometry and nuclear magnetic resonance spectroscopy. to our knowledge, this is the first report of 22d20E and 22d20E2P.     

反胶束溶液和血红蛋白水溶液相平衡的研究

研究了十六烷基三甲基溴化铵－正庚烷反胶束溶液和牛血红蛋白水溶液的相平衡,探讨了有机相助表面活性剂种类和浓度、水相ｐＨ值、水相离子种类和强度、表面活性剂浓度的影响,适宜条件下,牛血红蛋白的萃取率可达９５％以上。对实验结果从表面活性剂极性头与蛋白质分子间的相互作用和反胶团包溶蛋白质时的空间阻碍作用上进行了解释。     

16MnR钢夹杂物的行为

系统地调查研究了１６ＭｎＲ钢在整个生产过程中钢中夹杂物的演变规律和清洁度水平,重点考察了钢锭中大型氧化物夹杂的类型,数量,分布,来源的形成,结果表明：钢锭中夹杂物主要是块状Ａｌ２Ｏ３,钢锭中大颗粒夹杂物主要来源于复合渣卷渣。     

含磷FCC催化剂的酸性研究

利用磷酸对高岭土进行处理,制取不同含磷量的活性基质,然后与分子筛、填充物等组合成ＦＣＣ催化剂。在用ＦＴＩＲ技术和ＭＡＴ试验等催化剂表征手段对其表征之后,发现酸性,酸密度和强度等与催化剂的裂化性能有很大关系;所制５种不同含磷量催化剂的酸性特征随含磷量的变化而较有规律地变化。     

三自由度耦合非线性振动的同步混沌

讨论了一个三自由度耦合非线性振动的混沌响应。利用非线性振动的模态分析方法,将这一高维非线性性系统降维到一维子流形上来研究,对降维解耦后的模态振动方程采用平面Ｍｅｌｎｉｋｏｖ方法,得到了系统发生同步混沌的临界条件,并进行了数值计算,从中得到了一些有益的结论。     

高阶模态对弹性屈曲梁混沌运动的影响

为了讨论高阶模态对混沌运动的影响,建立了横向载荷作用下弹性屈曲简支梁的非线性动力方程,将其化为常微分方程或方程组。对梁的单模态模型采用Ｍｅｌｎｉｋｏｖ函数法给出了发生混沌运动的门槛值,对梁的单模态模型和双模态模型利用时程曲线、相平面轨迹,Ｐｏｉｎｃａｒｅ映射判断是否发生混沌运动,理论和数值分析表明高阶模态对混沌运动具有很大的影响。