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791.
Tert-butylhydroquinone-decorated graphene nanosheets and their enhanced capacitive behaviors 总被引:1,自引:0,他引:1
In the present work,tert-butylhydroquinone(TBHQ) was used to decorate graphene nanosheets to obtain a novel and environmentally friendly electrode material for supercapacitors.The fast redox reactions between hydroquinone and quinone generate pseudocapacitance.Graphene layers which have adsorbed TBHQ interact with each other to construct a three-dimensional network.Through this network,electrolyte ions can easily access the surface of graphene to generate electric double-layer capacitance.Electrochemical measurements have shown that using TBHQ as a redox modifier of graphene can obtain a maximum value of 302 F g-1 and provide a 51% enhancement in specific capacitance.Furthermore,excellent rate capability and cycling ability are achieved using the TBHQ-decorated graphene nanosheet electrode. 相似文献
792.
Coalbed methane (CBM) accumulation models include continuous gas accumulation and staged gas accumulation.However,studied on the geochemical characteristics and indices to evaluate staged accumulation CBM are lacking.This study for the first time obtained the carbon and hydrogen isotopic compositions of methane and ethane generated at different evolution stages using thermal simulation of samples prepared by treating an herbaceous swamp peat at different temperatures.The results showed that the carbon isotopic compositions of methane and ethane were obviously affected by the thermal evolution level of the starting sample,while the hydrogen isotopic compositions were closely related to the maturity of gases.The carbon and hydrogen isotopic compositions of gases generated by coal-forming organic matter with Ro values from 1.2%,1.7%,2.4%,3.2% and 3.7% to 5.2% were determinated.The relationship between Ro values and the carbon and hydrogen isotopic compositions of gases generated by coal-forming organic matter at different evolution stages as well as the carbon or hydrogen isotopic relationships between methane and ethane were established.The results provide a scientific basis for studying the genesis of CBM generated at different maturity intervals and understanding the geochemical characteristics of staged accumulation CBM.These results were applied to a case study on CBM from the southern Qinshui basin,and it was found that the CBM accumulated after the Middle Jurassic and was characteristic of staged gas accumulation.This is consistent with the result of geological studies,and further showed that the results of thermal simulation experiments are very important for evaluating the genesis of natural CBM. 相似文献
793.
TAO ChunHui LI HuaiMing HUANG Wei HAN XiQiu WU GuangHai SU Xin ZHOU Ning LIN Jian HE YongHua ZHOU JianPing 《科学通报(英文版)》2011,56(26):2828-2838
During January–May in 2007,the Chinese research cruise DY115-19 discovered an active hydrothermal field at 49°39′E/37°47′S on the ultraslow spreading Southwest Indian Ridge (SWIR).This was also the first active hydrothermal field found along an ultraslow-spreading ridge.We analyzed mineralogical,textural and geochemical compositions of the sulfide chimneys obtained from the 49°39′E field.Chimney samples show a concentric mineral zone around the fluid channel.The mineral assemblages of the interiors consist ... 相似文献
794.
The engineering design of a Cable-In-Conduit Conductor (CICC) is complicated. A model for the optimal design of a CICC based on conductor stability, AC loss and strain is proposed. The model considers the critical current density as a function of applied strain. A mathematical programming method that minimizes the AC loss of the CICC is established to yield an optimal design for the CICC structure. The optimized structure and related performance agree well with the engineering design values used for the KSTAR project. 相似文献
795.
XinMiao Lü LiPing Zhu Mitsugu Nishimura Yoshimune Morita Takahiro Watanabe Toshio Nakamura Yong Wang 《科学通报(英文版)》2011,56(27):2931-2940
A 380-cm-long sediment core was acquired from the deep water area of Pumoyum Co, southern Tibet. Twenty-five plant residue
samples were selected, and organic carbon stable isotopes were obtained using the AMS 14C chronological method. The 14C age and carbon reservoir effect were calibrated with surface sedimentation rate measurements using 210Pb dating. Results showed that the core sediment deposited over 19 cal ka BP. Based on a multi-proxy analysis of TOC and IC
contents, grain size and pollen assemblage data, the palaeoclimatic evolution of Pumoyum Co was reconstructed since the last
glacial. Pumoyum Co was a shallow lake prior to 16.2 cal ka BP; although the glacier around the lake began to melt due to
increasing temperatures, climate was still cold and dry. In the interval of 16.2–11.8 cal ka BP, the sedimentary environment
fluctuated drastically and frequently. Two cold-events occurred at 14.2 and 11.8 cal ka BP, and these may correspond to the
Older Dryas and the Younger Dryas events, respectively. After 11.8 cal ka BP, Pumoyun Co developed into the deep lake as it
is now. The lake water temperature was relatively lower at that time because of influx of cold water from glacial meltwater
entering the lake. As a result, the multi-proxy indicators showed no sign of warm conditions. Comparisons between the sedimentary
record of Pumoyum Co with that of other lakes of the same age in southern Tibet indicate a warmer climate following the last
deglaciation influenced the southeastern Tibetan Plateau. These results imply that the southwest Asian monsoon gradually became
stronger since the deglaciation during its expansion to the inner plateau. The glacial-supplied water of the lake responded
sensitively to cold-events. The entire southern Tibet region was dominantly influenced climatically by the southwest Asian
monsoon during the Holocene. 相似文献
796.
797.
PMSM矢量控制下逆变器母线电流频谱分析 总被引:1,自引:0,他引:1
逆变器直流母线电流频谱的准确解析是对电磁干扰进行分析及母线电容选取的重要理论基础。针对永磁同步(PMSM)作为负载时逆变器直流母线电流频谱的数学表达和理论求解方法分析了相电压基波和高次谐波对应的等效阻抗。分析得出:非凸极PMSM各次谐波对应的视在电感相等并且恒定;凸极式PMSM的基波电流可以在直轴和交轴上进行相量分解,其对应电感为直轴和交轴电感,高次谐波对应的电感随着转子的位置变化。理论计算时可以通过忽略高次谐波或取平均电感的方法来进行近似。给出了母线电流频谱计算的方法与过程。仿真和实验都证明了本文给出的计算方法及公式的正确性和有效性。 相似文献
798.
利用京津冀地区耕地面积统计资料为基础,采用耕地资源变化率计算方法和灰色预测法,分析和预测了该地区耕地的变化及趋势.研究结果表明:1985-2007年京津冀地区耕地总面积呈波动下降趋势,总共减少924.3 k hm2,多年平均变化率为-0.59%.耕地的三种类型之中,旱地和水田面积几乎年年减少,多年平均变化率分别为-3.57%和-0.73%,而水浇地的面积在大部分年份都有所增加,多年平均变化率为0.85%.2020年,京津冀地区的耕地总量将从2007年的6 531.61 k hm2减小至6 164.4 k hm2,耕地总面积平均每年减少0.44%,即28.7 k hm2.旱地和水田将继续保持较高的减少率,平均每年分别减少2.57%和0.84%.而水浇地的预测结果为2007年至2020年间每年稍增0.17%.在未来的十几年中,尽管耕地减少的速率减缓,但是京津冀地区耕地保护的压力依然很大. 相似文献
799.
低温胁迫下,对鄂尔多斯高原碱湖的钝顶节旋藻(A1)、非洲Chad湖的钝顶节旋藻(A2)和墨西哥Texcoco湖的极大节旋藻(A3)的质膜伤害进行比较研究,以了解来自中纬度与低纬度不同节旋藻对低温的反应,探讨其对低温的适应性及与原产地的关系.结果表明,无论直接低温处理还是经低温锻炼后再低温处理,随温度的降低3个样品细胞外渗液中可溶性蛋白和游离氨基酸的含量均增加,且胁迫的温度越低、时间越长,细胞外渗液中两种物质的含量也越高.经低温锻炼可减弱低温胁迫对节旋藻质膜的伤害,相比之下,对A1作用更明显.在相同的处理条件下,外渗液中蛋白质和游离氨基酸的含量均是A1相似文献
800.
吉林濒危植物天女木兰种群分布格局与生态位研究 总被引:1,自引:0,他引:1
以吉林省通化和集安为研究地点,对两地天女木兰种群的分布格局与生态位进行了研究。结果表明:天女木兰多呈聚集分布的特征,种群变小的趋势明显,生态位明显低于分布广的建群树种,在群落中属非建群树种,对群落环境和外貌影响不大,对环境适应能力较低。天女木兰与多数树种的生态位重叠主要集中在0.1以下,相对较低,与其他树种生态位重叠较少,分布范围狭小,在群落中居次要地位;在群落中其他大多数乔木树种天女栏其种间关联均为低度而且不显著。 相似文献