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氧化钒簿膜电极在锂充电电池中的应用(英文)   总被引:1,自引:0,他引:1  
鉴于氧化钒是应用于锂充电电池的最有希望的电极材料之一,采用等离子体增强化学气相沉积法(PECVD)和激光溅射沉积法(PLD),制备了不同的氧化钒薄膜,并研究了它们的电化学性质。这些薄膜具备较高的充放电容量和优良的充放电稳定性。晶体和非晶体的V2O5薄膜都可以用PLD方法在200℃和不同的气氛下制备。这些薄膜的充电容量可达380mA·h/g。所制备的最稳定的薄膜是用PECVD方法得到的。这些薄膜的O/V比很接近V6O13(厚度约为0.5um)。它们的放电容量可达408mA.h/g或1265mAh/cm3,其能量密度可达960.3W.h/kg。即使经过4400次的充放电后,这些薄膜的放电容量仍基本不变。因此,PECVD方法及其用它所制备的氧化钒薄膜将是锂充电电池工业很有希望的一种选择。  相似文献   
13.
In digital fingerprinting, preventing piracy of images by colluders is an important and tedious issue. Each image will be embedded with a unique User IDentification (UID) code that is the fingerprint for tracking the authorized user. The proposed hiding scheme makes use of a random number generator to scramble two copies of a UID, which will then be hidden in the randomly selected medium frequency coefficients of the host image. The linear support vector machine (SVM) will be used to train classifications by calculating the normalized correlation (NC) for the 2class UID codes. The trained classifications will be the models used for identifying unreadable UID codes. Experimental results showed that the success of predicting the unreadable UID codes can be increased by applying SVM. The proposed scheme can be used to provide protections to intellectual property rights of digital images aad to keep track of users to prevent collaborative piracies.  相似文献   
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Severe behavioural deficits in psychiatric diseases such as autism and schizophrenia have been hypothesized to arise from elevations in the cellular balance of excitation and inhibition (E/I balance) within neural microcircuitry. This hypothesis could unify diverse streams of pathophysiological and genetic evidence, but has not been susceptible to direct testing. Here we design and use several novel optogenetic tools to causally investigate the cellular E/I balance hypothesis in freely moving mammals, and explore the associated circuit physiology. Elevation, but not reduction, of cellular E/I balance within the mouse medial prefrontal cortex was found to elicit a profound impairment in cellular information processing, associated with specific behavioural impairments and increased high-frequency power in the 30-80?Hz range, which have both been observed in clinical conditions in humans. Consistent with the E/I balance hypothesis, compensatory elevation of inhibitory cell excitability partially rescued social deficits caused by E/I balance elevation. These results provide support for the elevated cellular E/I balance hypothesis of severe neuropsychiatric disease-related symptoms.  相似文献   
15.
Overexpression of sirtuins (NAD(+)-dependent protein deacetylases) has been reported to increase lifespan in budding yeast (Saccharomyces cerevisiae), Caenorhabditis elegans and Drosophila melanogaster. Studies of the effects of genes on ageing are vulnerable to confounding effects of genetic background. Here we re-examined the reported effects of sirtuin overexpression on ageing and found that standardization of genetic background and the use of appropriate controls abolished the apparent effects in both C. elegans and Drosophila. In C. elegans, outcrossing of a line with high-level sir-2.1 overexpression abrogated the longevity increase, but did not abrogate sir-2.1 overexpression. Instead, longevity co-segregated with a second-site mutation affecting sensory neurons. Outcrossing of a line with low-copy-number sir-2.1 overexpression also abrogated longevity. A Drosophila strain with ubiquitous overexpression of dSir2 using the UAS-GAL4 system was long-lived relative to wild-type controls, as previously reported, but was not long-lived relative to the appropriate transgenic controls, and nor was a new line with stronger overexpression of dSir2. These findings underscore the importance of controlling for genetic background and for the mutagenic effects of transgene insertions in studies of genetic effects on lifespan. The life-extending effect of dietary restriction on ageing in Drosophila has also been reported to be dSir2 dependent. We found that dietary restriction increased fly lifespan independently of dSir2. Our findings do not rule out a role for sirtuins in determination of metazoan lifespan, but they do cast doubt on the robustness of the previously reported effects of sirtuins on lifespan in C. elegans and Drosophila.  相似文献   
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Disturbance in riparian areas of semiarid ecosystems involves complex interactions of pulsed hydrologic flows, herbivory, fire, climatic effects, and anthropogenic influences. We resampled riparian vegetation within ten 10-m × 100-m plots that were initially sampled in 1992 in 4 watersheds of the Snake Range, east central Nevada. Our finding of significantly lower coverage of grasses, forbs, and shrubs within plots in 2001 compared with 1992 was not consistent with the management decision to remove livestock grazing from the watersheds in 1999. Change over time in cover of life-forms or bare ground was not predicted by scat counts within plots in 2001. Cover results were also not well explained by variability between the 2 sampling periods in either density of native herbivores or annual precipitation. In contrast, Engelmann spruce ( Picea engelmannii ) exhibited reduced abundance at all but the highest-elevation plot in which it occurred in 1992, and the magnitude of change in abundance was strongly predicted by plot elevation. Abundance of white fir ( Abies concolor ) individuals increased while aspen ( Populus tremuloides ) individuals decreased at 4 of 5 sites where they were sympatric, and changes in abundance in the 2 species were negatively correlated across those sites. Utility of monitoring data to detect change over time and contribute to adaptive management will vary with sample size, observer bias, use of repeatable or published methods, and precision of measurements, among other factors.  相似文献   
17.
Hanging gardens of the Narrows, Zion National Park, Utah, are plant communities growing at permanent seeps on the canyon walls. The gardens are isolated from each other and from other plant communities by vertical expanses of sandstone. Gardens consist mostly of herbaceous species less than 1 m tall. Though not individually species-rich, the hanging gardens are diverse as a group, and very dissimilar. This study considers two explanations of the heterogeneous distribution of species in hanging gardens. The assemblages of dispersal types in gardens of different spatial attributes and disturbance frequencies are examined. The G H statistic, a log likelihood ratio test, analyzes the incidence of dispersal types among classes of three spatial and two disturbance variables. The disturbance variables of expected flood frequency and soil depth segregate dispersal types; and the spatial variables of area, distance to possible seed sources, and relative isolation do not. Ferns and mosses, dispersing through spores, dominate a heterogeneous fugitive guild in the flood-prone gardens. Infrequently flooded gardens support more large-seeded species.  相似文献   
18.
On 29 May 1770 Joseph Banks described a spectacular swarming of ‘milions’ [sic] ‘of one sort’ of butterfly at Thirsty Sound, near what is now Rockhampton, Queensland, comparing it to a species from China that had been named by Linnaeus. Discovery of what appears to be an Endeavour voyage specimen of this Australian butterfly in the Hunterian Zoology Museum, Glasgow, allows us to confirm its long-suspected identity as Tirumala hamata hamata (Macleay) – a species unnamed and unknown at the time of Cook’s first voyage. Investigations into several collections that include eighteenth-century Australian Lepidoptera and associated literature have not positively identified any further specimens taken from the swarm, although a pair in the Oxford University Museum of Natural History could be from the same source. Taxonomic confusion due to mimicry, convergence and/or non-divergence affecting blue tiger patterned butterflies is most likely the principal reason such a specimen has previously gone undetected.  相似文献   
19.
Hirschsprung disease (HSCR), the most common hereditary cause of intestinal obstruction, shows considerable variation and complex inheritance. Coding sequence mutations in RET, GDNF, EDNRB, EDN3 and SOX10 lead to long-segment (L-HSCR) and syndromic HSCR but fail to explain the transmission of the much more common short-segment form (S-HSCR). We conducted a genome scan in families with S-HSCR and identified susceptibility loci at 3p21, 10q11 and 19q12 that seem to be necessary and sufficient to explain recurrence risk and population incidence. The gene at 10q11 is probably RET, supporting its crucial role in all forms of HSCR; however, coding sequence mutations are present in only 40% of linked families, suggesting the importance of noncoding variation. Here we show oligogenic inheritance of S-HSCR, the 3p21 and 19q12 loci as RET-dependent modifiers, and a parent-of-origin effect at RET. This study demonstrates by a complete genetic dissection why the inheritance pattern of S-HSCR is nonmendelian.  相似文献   
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