Suitable energy platform significantly improves charge separation of g-C_3N_4 for CO_2 reduction and pollutant oxidation under visible-light

The photocatalytic activities of g-C_3N_4 can be significantly improved by increasing life time of the photogenerated charges. Here, in this work we introduced TiO_2 as proper energy platform to accept the photogenerated electrons from g-C_3N_4 during photocatalysis. The nanophotocatalysts formed from the combination of a suitable amount of TiO_2 nanoparticles and g-C_3N_4 nanosheets showed 8.75 and 4.22% enhancement in photocatalytic activities for CO_2 reduction and 2-chlorophenol(2-CP) degradation under visible light illumination as compared to bare g-C_3N_4. Based on the surface photovoltage spectra, photoluminescence spectra and examination of formed hydroxyl radicals, it was confirmed that these enhanced photoactivities were attributed to the much-improved charge separation via the electron transfer from g-C_3N_4 to TiO_2. From trapping experiments,it was found that hydroxyl radicals were the major species involved in the photocatalytic degradation of 2-CP.This study is helpful to synthesize efficient photocatalysts to cope with energy and environmental issues.     

Effect of Co substitution on the structural, electrical, and magnetic properties of Bi0.9La0.1FeO3 by sol-gel synthesis

Cobalt (Co)-doped Bi_0.9La_0.1FeO₃ multiferroics were synthesized by a sol-gel method based on the autocombustion technique. As-synthesized powder was examined using various characterization techniques to explore the effect of Co substitution on the properties of Bi_0.9La_0.1FeO₃. X-ray diffraction reveals that Co-doped Bi_0.9La_0.1FeO₃ preserves the perovskite-type rhombohedral structure of BiFeO₃, and the composition without Co preserves the original structure of the phase; however, a second-phase Bi₂Fe₄O₉ has been identified in all other compositions. Surface morphological studies were performed by scanning electron microscopy. Temperature-dependent resistivity of the samples reveals the characteristic insulating behavior of the multiferroic material. The resistivity is found to decrease with the increase both in temperature and Co content. Room temperature frequency-dependent dielectric measurements were also reported. Magnetic measurements show the enhancement in magnetization with the increase in Co content.     

考虑震损的混凝土框架结构改进建模方法

为准确描述震后结构损伤的影响,提出了损伤构件的定量分析方法及震损结构的改进建模方法.首先,从骨架曲线退化及滞回规则退化两方面定义了损伤构件的性能退化指数;然后,基于Park-Ang模型与Kunnath模型,采用统计回归分析方法提出了损伤构件恢复力模型,并对其准确性进行了验证;最后,应用该恢复力模型对震损框架结构进行弹塑性分析.结果 表明:采用Park-Ang模型和Kunnath模型得到的损伤构件恢复力模型均具有较高的准确性;对于所研究的2种构件,滞回曲线力峰值的理论值和试验值误差均小于10％;向完好结构输入组合地震波,向震损结构输入单一地震波,各层位移时程曲线吻合良好,说明采用该恢复力模型进行震损结构建模能够准确分析震损程度及分布对结构抗震性能的影响.     

Impact of gamma radiation and salinity on growth and K+/Na+balance in two populations of Medicago sativa(L.)cultivar Gabès

The perennial Medicago sativa cv.Gabès is widely grown on saline soils in Tunisian oases.Morphological and physiological analyses of two populations(Mareth and Gannouch)were conducted in order to study the effect of salinity and gamma radiation(350 Gy)inter-action on two populations of this species.It has been shown that the two irradiated populations of Medicago sativa are fairly tolerant to salt at growth phase compared to the non-irradiated.Exposure to gamma irradiation(350 Gy),alone or in combination with salt stress,increased significantly (p<0.00 1)shoot number,stem height and chlorophyll b pigment especially for the Gannouch population,while no change occurred for the Mareth population.The presence of salt to 9 g/1 affected significantly the root biomass and induced a reduc-tion of shoot development of both control and irradiated alfalfa populations.For all treatments,plants of two populations remained able to produce and to allocate dry matter to the different organs.The survey of Na+/K+ratio showed that the growth of the aerial organs of two non-irradiated populations was at least determined by a selectivity in favour of the K+ions r2=0.97 and r2=0.59 for Mareth and Gannouch non-irradiated populations,respectively).However,the rather weak correlation detected for the irradiated populations,par-ticularly for the irradiated Gannouch.seems to be the consequence of the effect of irradiation that improved potassium availability.essential element for growth and development.Results also showed that the two irradiated populations,especially the Mareth,accumu-lated Na+ions in its photosynthetic organs.This accumulation was associated with an improvement of foliar water content at a level of salinity around 5 g/1.Such a mechanism reflects probably an inclusive behaviour of the plants and a good aptitude to use the dominant ions(Na+)for the osmotic adjustment.However,the non-irradiated populations are unable to adjust their internal osmotic potential.Consequently,irradiated plants have probably adapted to the osmotic stress by either closing their stomata or increasing the osmotic pressure of the leaf cells.     

一种克服机械共振的功率放大电路

许多驱动机械装置的马达的功放电路，由于受到机械共振频率的限制，不能高速运行．本电路采用陷波器，对于机械共振频率进行限制，保证驱动系统在高速运行时的稳定性．     

Isolation of alkaloids fromAthrotaxis selaginoides

Summary A novel series of alkaloids has been obtained from the Tasmanian plantAthrotaxis selaginoides, the first to be isolated from the plant family Taxodiaceae.     

Degradation of phenylalanine in the presence of hydrogen peroxide.

UV-irradiation of phenylalanine by 253.7 nm light in the presence of hydrogen peroxide formed 5 ninhydrin reactive products and ammonia. Four of them were identified as aspartic acid, serine, alanine and lysine.