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21.
IntroductionInourdailylife ,cotton ,paperandspongearecommonlyusedtoabsorbwater.Thesematerialsabsorbonlyafewtimestheirweightofwaterandhaveratherpoorpropertieswithrespecttowaterretention .However,sometypesofpolymersandcopoly mersdofunctionashighwaterabsorb… 相似文献
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Many molecules can rotate freely around single bonds and thereby interconvert between different conformations, such as gauche and anti 1,2-disubstituted ethane, a classic example of conformational isomerism. Even though rotation occurs rapidly at room temperature, the product selectivity seen in some reactions has been explained by conformation-dependent reaction mechanisms: if reactant molecules differing only in their conformation are located at different positions on the reaction path, they may undergo different reactions. But a direct verification of this effect is difficult, because the energy barrier separating conformational isomers is so low that under ambient conditions reactants with more than one conformation will be present. But by using temperatures low enough to suppress the interconversion between different conformations, gauche-1-iodopropane ions and anti-1-iodopropane ions have been selectively generated. Here we show that the kinetic energy released during the photodissociation of 1-iodopropane ions depends strongly on the conformation of the ions. Thermodynamic arguments and ab initio calculations indicate that this difference in kinetic energy release results from differences in the reaction mechanism, with gauche-1-iodopropane ions forming 2-propyl ions and anti-1-iodopropane ions forming protonated cyclopropane ions. These findings suggest that the well-known concept of conformation selection forms the basis of a simple scheme for reaction control, thus providing in some cases an attractive alternative for more involved schemes that utilize the phase and pulse shape of laser beams to control chemical reactions. 相似文献
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利用经典力学和振动学原理建立了空间振动卸料机的力学模型和数学模型,并对其求解。在实验基础上导出阻尼系数的计算公式。 相似文献
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A new approximate scheme which is combined by the mean-field renormalization group theory (MFRG) with the discretized path-integral renormalization (DPIR) is employed in the study of the disordered tranverse Ising model (TIM). The critical properties of random-bonds Ising systems on a d-dimensional lattice are calculated with this new approximate scheme. 相似文献
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毛泽东的思想政治工作艺术其本质是对思想政治工作的一种艺术掌握方式,是目的性和工具性的统一。毛泽东丰富多彩的思想政治工作艺术在当今时代仍然具有生命力,它是新形势下思想政治工作改进和创新的重要方法借鉴。 相似文献
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Song Liuping Sun ZhongkangDept. of Electronic Eng. National Univ. of Defense Technology Changsha China 《系统工程与电子技术(英文版)》1991,(2)
The purpose of this paper is to develop a high speed detection scheme for moving and / or stationary point targets in a multitarget environment as registered in an IR image sequence. An iterative approximate 3-D line searching algorithm based upon the geometric representation of lines (for non-maneuvering targets in space) in a 3-D space is derived. The convergency of the algorithm is proved. An analysis is performed of the theoretical detection performance of the algorithm. The statistical experiment results show high effectiveness and computational efficiency of the algorithm in the case of low SNR. The idea may be employed to satisfy the real-time processing requirement of an IR system. 相似文献
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