二苯并四氧二氮环醚及其稀土配合物合成与荧光性质研究

合成了二十员大环双氮杂冠醚：2，3，l6，l7—二苯—l，8，ll，18—四氧—5，14—二氮杂环二十烷及其7个与稀土硝酸盐(RE^3 ＝La^3 ，Sm^3 ，Eu^3 ，Gd^3 ，Tb^3 ，Dy^3 。Yb^3 )所形成的1：2(M：L)型固体配合物，并经过红外光谱、元素分析、摩尔电导及热分析等方法对配合物进行了表征．结果表明，配位是通过配体中的C—O-C进行的，而Ar—O-C未参与配位，同时含2分子配位水．对Sm(Ⅲ)，Eu(Ⅲ)，Tb(Ⅲ)，Dy(Ⅲ)的配合物进行了荧光光谱测定，所有配合物均有较强的荧光强度，其中Tb(Ⅲ)的配合物荧光强度最高，表明该新双氮杂冠醚配体三重态的能量与Tb(Ⅲ)的振动能级最为匹配．     

BP网络应用于黄河水质的预测研究

利用黄河兰州段水质指标浓度时间序列作为学习样本，选取了DO、COD、氨氮、重金属离子等l0项指标作为输出参数，运用人工神经网络BP模型中的Levenberg—Marguardt优化算法对学习样本优化建模，将优化好的网络的预测结果与实测结果进行了比较，表明BP网络可以很好地用于黄河水质指标值及水质类别的预测。     

连续事件的语义数据模型

语义抽象概念aggregation和generalization不仅对不包含时间概念的复杂情况的数据模型的建立很有用，而且还可以成功地用于连续事件的建模。建立了两种情况并存的语义数据模型：or—dering(次序)和sequencing(先后顺序)，并且可以在任何程序环境下实现。     

豫西早二叠世掌蕨Chiropteris Kurr和髻籽羊齿Nystroemia Halle有机连接标本的发现

基于河南登封早二叠世肾掌蕨Chiropteris reniformis Kawasaki和髻籽羊齿Nystroemia pectiniformis Halle有机连接的标本, 确立了肾髻籽羊齿(新组合)Nystroemia reniformis (Kawasaki) comb.nov.营养叶具长柄, 肾形, 基部心形, 全缘或具细齿; 叶脉细, 多次二歧分叉并结为多边形或菱形细网.生殖枝在苞片腋部着生.苞片与营养叶同形.胚珠器官在叶性器官腋部着生或两者分别不规则地着生于生殖枝的轴上.极多的具翼双角籽倒圆锥形, 呈两列状排列, 珠孔朝上.该植物代表了一种新的已灭绝的裸子植物.     

CHARACTERIZATION OF SOL-GEL-DERIVED ZrO2 FILM BY PHOTOTHERMAL RADIOMETRY

In modern industry,thin film on the substratc has much important role to decide the properties of product, especially for electrical, optical and wear-resistant etc, production. There are some technical methods to prepare thin film,including plasma spray,physical vapor deposition (PVD),chemical vapor deposition (CVD) and sol-gel,etc. Among of them,sol-gel method has been developed a popular tech nique for preparing thin films.     

生态遗传算法在模糊系统辨识中的应用

给出一类模糊系统的模糊神经网络模型 .提出一种实用的生态算子 ,构建的生态遗传新算法有效解决了基本遗传算法的“早熟”问题 .采用新算法实现模糊神经网络模型的辨识 ,提高了辨识精度 .实例仿真结果验证了新算法在模糊系统辨识中的有效性     

带有油膜轴承的裂纹轴转子系统故障特征分析

通过大量仿真计算，对于带有油膜轴承的裂纹轴转子系统的故障特征进行了较为全面的论证．这些特征是通过三维频谱、转速-振幅特性和周期分岔特性来表达的．除了分析裂纹轴转子系统的基本故障特征外，还重点分析了作为故障特征的一个重要方面的非线性行为．为诊断转子系统裂纹故障提供了理论依据．     

描述石灰石分解的分数维收缩核模型及模拟

基于分形理论中颗粒表面积与颗粒当量半径以及表面积与体积之间的关系式，考虑固体颗粒表面形貌的不规则性，建立了化学反应起控制作用的固体颗粒分解的分数维收缩核模型，并将其用来模拟石灰石颗粒的缎烧分解过程，取得了较为满意的模拟结果．同时，将其模拟结果与收缩核模型的模拟结果进行了比较．     

Endogenous oscillatory activity and TTX-sensitive spikes of the heart muscle in early juveniles of the isopod crustaceanLigia exotica

The heart beat of early juveniles of the littoral isopodLigia exotica occurred at a frequency of 250 to 350/min, associated with rhythmic activity of the heart muscle. Each burst was composed of a slow depolarizing potential with superimposed spike potentials. The spike potential was eliminated by perfusion with TTX-containing or Na⁺-free saline. In TTX-saline, the slow potential was unchanged in frequency and amplitude. By current injection into the heart muscle, the rhythm of the slow potential was phase-shifted and its frequency was changed in a membrane potential-dependent manner. These results show that the heart ofLigia early juveniles acts as an endogenous muscle oscillator generating oscillatory slow potentials and Na⁺-dependent spikes.     

Antioxidant survey to assess antagonism to redox stress using a prokaryotic and an eukaryotic system

Using a prokaryote (Escherichia coli) and a metazoa-resembling eukaryote (Ochromonas danica), we surveyed antioxidants which might overcome redox stress imposed by menadione sodium bisulphite (MD) and buthionine sulphoximine (BSO). BSO oxidant stress was evident only inO. danica; MD oxidant stress was evident in both organisms. Glutathione, its precursors, e.g. cysteine, homocysteine, and 2-oxo-4-thiazolidine carboxylic acid, and red blood cells, emerged as prime antioxidants for relieving BSO and MD oxidant stress. BSO and MD oxidant activity and antioxidant-annulling effect inO. danica were judged comparable to those found in animal cells whereas the resultsE. coli were not entirely equivalent. TheO. danica system emerged as a practical, rapid, and useful system for pinpointing oxidant stressors and antioxidants, and shows promise for studies with mammalian systems.