New crystal structure of molecular complex 1-piperidine carboxylate-piperidinium-H<Subscript>2</Subscript>O studied by X-ray single crystal diffraction

Piperidine absorbs CO2 and H2O in air to form a molecular complex： piperidium-l-piperidinecarboxylate-H2O. The structure of the complex was characterized by X-ray single crystal diffraction. The crystal structure was determined to be triclinic, space group P1^-with a=0.648 6（8） nm, b=0.809 200） nm, c= 1.357 1（16） nm, a=96.96706）°, β =102.506（15）°,γ=104.202 05）°, Z=2. The complex is stabilized via five hydrogen bonds between the three components, N-O electrostatic interaction and O-O interaction （electron transfer） betweenl-piperidinecarboxylate and H2O. Due to electron transference of carbamate ion, the oxygen atom in water molecule is strongly negatively charged and the O-H bond is considerably shorter than that of the free molecule of water. The formation of the molecular complex is a reversible process and will decompose upon heating. The mechanism of formation and stabilization is further investigated herein.     

An Adaptive Model and Algorithm for an Electrohydraulic Position Servo System in Auto Gauge Control for Aluminum Hot Tandem Mill

The electrohydraulic servo position control system (HPC) is the core of an auto gap control for a modern fourhigh continuous hot strip mill. The actuators are loaded with considerable external disturbances, rolling forces, and the system stiffness and position accuracy will become hypersensitive to the leakage and the compressibility of the oil. Many efforts have being made to increase the position accuracies. The conventional resources are proportion integral differential (PID) controller. But the PID controller is faint for a considerable external disturbance. In this paper, by introducing the adaptive control strategy of model reference the reciprocities of the system structure with the loads were analyzed. With the Lyapunov energy function, an adaptive control algorithm applied to improve the system accuracy was formulated. The system simulations and the selection of parameters of the model were also discussed. The simulations show the static state errors at 0.02%. Finally, the industrial experimental result was given.     

交互式语音地球仪照明结构研究

简述了交互式语音地球仪结构原理;研究了地球仪上首都的无歧义显示、发光二极管的布置以及首 都显示分辨率;制成了交互式语音地球仪。     

基于人的信息处理模型分析操作人员视觉信息处理过程

报告了由知觉、思维、运动３个处理器和短期记忆、工作记忆和长期记忆构成的研究用计算机实现 人的信息处理模型;把人的信息处理模型安装在一台PC机上,模拟生产操作人员监视锅炉厂模拟机计算机屏幕 的过程表明,视觉信息处理过程取决于画面因素、人的身心状态和知觉处理器参数等与实际生产操作人员的行 为特征相符。此模型可以用来分析工业生产中人为操作失误的发生机制,以预防和减少事故发生。     

伐昔洛韦联合微米光治疗28例带状疱疹的临床观察

目的:观察伐昔洛韦(valacyclovir)联合微米光治疗28例带状疱疹的临床疗效.方法:将54例带状疱疹患者随机分为两组,试验组28例口服伐昔洛韦(商品名:维德思)1 000 mg,每日3次,共服7d后改为每次500 mg,每日3次,继续服用7d.同时皮肤照射微米光每日一次,共照射14 d.对照组26例口服阿昔洛韦,200 mg,每日5次,同样每日照射微米光,与试验组一致,共14 d.观察记录第1、3、5、7、10、14天时止疱、结痂、疼痛及不良反应,第14天根据评分表评定总疗效.结果:试验组痊愈率为82.1％,对照组为46.2％,差异有统计学意义(P＜0.01),试验组有效率为96.4％,对照组为73.1％ (P ＜0.05).全部患者无严重不良反应发生,疗程结束后查肝肾功能无明显改变.结论:伐昔洛韦(维德思)联合微米光能明显缩短带状疱疹病程、加快水疱干枯结痂、促进皮损愈合、减少神经痛的程度及持续时间,降低后遗神经痛的发生率.     

可吸入颗粒污染物在下呼吸道运动和沉积规律的数值模拟

为研究受慢性阻塞性肺病影响的呼吸道内气固流动特性,建立了基于Weibel模型的5～8级三维肺部模型.气相采用标准k-ε湍流模型,颗粒相采用离散颗粒模型.三级呼吸道内模拟的气固流动特性与实验结果进行了对比验证.在呼吸强度为30,60和90 L/min条件下,模拟了稳态、非稳态吸气时第7级内侧呼吸道受慢性阻塞性肺病影响收缩...     

昆翅在飞行中的动态形变

通过理论模化途径研究昆翅在飞行中的动态形变机制.设计翅气动力试验平台,验证翅准静态形变影响气动力的"柔性楔形效应"理论解释.探讨昆翅的变刚度特性表明,弦向刚度分布规律符合二项式函数时具有优越性和现实性,进而指出昆姻结构的变刚度特性是产生高升力的基本条件.建立了柔性翅的简化力学模型,通过坐标变换法求解在气动力和惯性力共同...     

适于全断面岩石掘进机的围岩分类方法

为了研究影响全断面岩石掘进机(TBM)掘进速率的地质因素,利用三维离散元程序3DEC建立TBM滚刀破岩三维仿真模型,分析不同的地质条件对TBM掘进速率的影响,根据TBM在围岩中的可钻性对南水北调西线工程中的围岩进行分类。分析结果表明:TBM掘进速率与岩石物理力学性质及岩体中的节理条件密切相关,在一定范围内,围岩强度越低,节理分布越密集,TBM掘进速率越高;而围岩强度越高,节理间距越大,使得TBM掘进速率大大降低。     

Evaluating the reliability of microsatellite genotyping from low-quality DNA templates with a polynomial distribution model

Molecular studies using trace DNA, such as from museum specimens, ancient or forensic samples and samples obtained noninvasively, often have a common problem of low quality of DNA templates. Amplification errors, such as allelic dropout and false allele, may arise during polymerase chain reaction (PCR) using such samples. A mathematical model which treats homozygotes and heterozygotes discriminately has been developed to measure sample quality and compute the confidence level of using multipletube approaches. We use plucked hair samples collected from 26 individual Sichuan snub-nosed monkeys (Rhinopithecus roxel- lana) to test the model. In this case, a confidence level of 99% can be achieved by three positive PCRs. If the sample quality is very poor and requires many PCR replicates, an alternative multiplestep genotyping method is recommended. This model enables researchers to optimize experimental protocols through pilot studies and obtain reliable genetic information using noninvasive sampling method.     

库存积压风险对回购激励的影响及其对策

针对决策过程中决策者在考察期望收益的同时通常也会考虑获得该期望收益的不确定性这一实际情况,基于"效用"的角度考虑了供应链回购激励机制的目标函数,提出用库存积压风险规避因子来描述决策者的风险偏好,建立了相应的基于Stackelberg主从博弈的回购激励模型,并通过对比风险中性情形的决策过程得出了关于零售商库存积压风险规避态度影响的定量结论:对于库存积压风险规避的零售商,供应商将需要给出更大的激励力度,即零售商将得到风险溢金.设计了基于批发价的目标回购激励机制作为应对策略,并证明了其有效性.