全文获取类型
收费全文 | 1842篇 |
免费 | 67篇 |
国内免费 | 87篇 |
专业分类
系统科学 | 69篇 |
丛书文集 | 41篇 |
教育与普及 | 106篇 |
理论与方法论 | 7篇 |
现状及发展 | 13篇 |
综合类 | 1760篇 |
出版年
2024年 | 7篇 |
2023年 | 35篇 |
2022年 | 53篇 |
2021年 | 67篇 |
2020年 | 37篇 |
2019年 | 28篇 |
2018年 | 38篇 |
2017年 | 41篇 |
2016年 | 44篇 |
2015年 | 67篇 |
2014年 | 89篇 |
2013年 | 77篇 |
2012年 | 59篇 |
2011年 | 88篇 |
2010年 | 80篇 |
2009年 | 98篇 |
2008年 | 99篇 |
2007年 | 85篇 |
2006年 | 61篇 |
2005年 | 66篇 |
2004年 | 50篇 |
2003年 | 47篇 |
2002年 | 39篇 |
2001年 | 59篇 |
2000年 | 55篇 |
1999年 | 75篇 |
1998年 | 69篇 |
1997年 | 65篇 |
1996年 | 57篇 |
1995年 | 59篇 |
1994年 | 37篇 |
1993年 | 34篇 |
1992年 | 27篇 |
1991年 | 25篇 |
1990年 | 21篇 |
1989年 | 15篇 |
1988年 | 16篇 |
1987年 | 9篇 |
1986年 | 15篇 |
1985年 | 3篇 |
排序方式: 共有1996条查询结果,搜索用时 31 毫秒
131.
合成了一个新的配合物[Mg(H2O)6](p-OPA)2.2H2O(p-OPA-=4-氧-1(4H)-吡啶乙酸根),并对其进行了元素分析和单晶X射线的表征。配合物晶体属单斜晶系,空间群为P 21/c,晶胞参数为a=1.2561(3)nm,b=1.2947(3)nm,c=0.67885(14)nm,β=99.32(3)°,V=1.0895(4)nm3,Z=2,Mr=472.69,Dc=1.441g/cm3,μ=0.154mm-1,F(000)=500,最终R=0.0525,wR=0.1398。Mg(Ⅱ)原子与六个水分子配位形成八面体构型,4-氧-1(4H)-吡啶乙酸根作为抗衡离子,配阳离子与阴离子之间通过静电吸引和氢键作用形成了三维氢键超分子网络结构。 相似文献
132.
利用雕刻技术,以有机玻璃为原材料,加工制作了一种可双向工作的单振子双腔体压电薄膜泵,并对该结构压电泵的工作原理进行了阐述.通过对单振子双腔体压电薄膜泵的输出流量和压力的测试,得出在输入100V正弦交流信号时,它的最佳工作频率为20Hz,输出流量为785mL/min,输出压力为14kPa,表明单振子双腔体压电泵在低频工作时,其输出流量优于单振子单腔体压电泵,而且能够提高机械转化效率,工作过程无脉动现象. 相似文献
133.
希尔伯特黄变换在齿轮故障诊断中的应用 总被引:2,自引:1,他引:2
希尔伯特黄变换是先把一列时间序列数据通过经验模态分解,然后经过希尔伯特变换获得时频谱的信号处理新方法。介绍了希尔伯特黄变换算法的原理及流程,利用由希尔伯特谱反映出的丰富的物理信息来对齿轮进行故障诊断。结果表明,希尔伯特谱较好地实现了齿轮故障的诊断,希尔伯特黄变换为齿轮故障提供了有力的工具。 相似文献
134.
宣钢单喷镁铁水脱硫技术应用与实践 总被引:1,自引:0,他引:1
介绍了宣钢炼钢厂采用单喷颗粒镁铁水脱硫工艺,改善了转炉冶炼原料铁水条件,同时对镁在铁水中的脱硫机理作了简要的叙述.该工艺在生产实践中不断优化,使铁水经过预处理后终点硫均达到0.010%(质量分数)以下,最低终点硫含量达到0.003%,满足了炼钢铁水要求. 相似文献
135.
Wolf spiders are predators in large quantities in the fields. How wolf spiders keep their dominant species status under long-period pesticide force? To answer this question, eight geographical populations of Pardosa pseudoannulata were used as materials to test the influence of geographical habitats on their genomic DNA polymorphism. The RAPD pattern showed polymorphic variations among and within different populations. Total 84 bands amplified by 10 random primers, of which 62 (73.81%) are polymorphic, were generated from 55 individuals of eight geographical populations. Meanwhile, Shannon’s index (Ho= 0.5177) showed a rich genetic diversity of P. pseudoannulata, and most of the genetic variation (64.24%) was found within populations. Multiple regression analysis suggested that it is the climatic variation (such as annual average temperature etc.) that results in adaptive eco-geographic differentiation, and it is the long-period pesticide force that speeds up the genetic differentiation of P. pseudoannulata which changed the genetic diversity of the population. 相似文献
136.
Determination of the optical thickness and effective particle radius of clouds from transmitted solar radiation measurements 总被引:1,自引:0,他引:1
A method is presented for determining the optical thickness (τc) and effective particle radius (re) of stratiform cloud layers from transmitted solar radiation measurements. A detailed study shows that the cloud optical thickness and effective particle radius of water clouds can be determined from transmission function measurements at 0.75 and 2.13 μm, provided that the scaled optical thickness τ′0.75>1 and re>5 μm. The wavelengths adopted by our study are similar to the channels of the moderate resolution imaging spectrometer (MODIS). The proposed method is invalid for optically thin clouds since transmission at 2.13 μm is less sensitive to re. The retrieval errors of τ′0.75 and re monotonically decrease with increasing τc. For clouds having τ′0.75≥2, the retrieval errors of τ′0.75 and re are below 10% and 20%, respectively. Transmissions at 0.75 and 1.65 μm can also be used to retrieve τc and re. 相似文献
137.
XUE Shuang ZHAO QingLiang WEI LiangLiang WANG LiNa LIU ZhiGang 《科学通报(英文版)》2007,52(18):2496-2505
The reduction of mass and trihalomethane formation potential (THMFP) of dissolved organic matter (DOM) and its fractions from secondary effluent during laboratory-scale soil-aquifer treatment (SAT) soil columns were studied. Reduction in dissolved organic carbon (DOC), absorbance of ultraviolet light at 254 nm (UV-254), biodegradable dissolved organic carbon (BDOC) and nonbiodegradable dis- solved organic carbon (NBDOC) for the bulk DOM averaged 72.35%, 53.98%, 97.49% and 35.33% across the soil columns, respectively. Using XAD-8 and XAD-4 resins, DOM was fractionated into 3 fractions: hydrophobic acid (HPO-A), transphilic acid (TPI-A) and hydrophilic fraction (HPI). HPO-A was removed by 61.06%, TPI-A by 54.86% and HPI by 74.95% as DOC as a consequence of the laboratory-scale SAT, respectively. The reduction of THMFP from HPO-A, TPI-A and HPI was 27.24%, 26.24% and 36.08%, respectively. Proton nuclear magnetic resonance (1H-NMR) spectra revealed that the HPO-A isolated from the secondary effluent contained more aromatic functional groups than the corresponding TPI-A. Fourier-transform infrared (FT-IR) spectrum analysis illustrated that TPI-A had decreased hydrocarbon and increased aromatics content in the SAT columns. Specific ultraviolet light absorbance (SUVA) and specific THMFP for each DOM fraction increased across the soil columns and HPI exhibited greater increase in both than HPO-A and TPI-A. The most problematic THM precursor was found to be HPO-A with its high quantity present in recharged water and high chlorine reactivity. 相似文献
138.
139.
用DFT方法对NiB,Ni2B,Ni3B二重态和四重态两种多重度的各种可能构型进行高水平的量子化学计算,结果发现Ni,B原子所带电荷的正负与原子簇的组成和结构有关,存在较强Ni,B的相互作用,Ni-B键对NiB,Ni2B,Ni3B分子的稳定性有很大贡献 相似文献
140.
三氟乙烷的气相音速测量与热力学性质研究 总被引:1,自引:0,他引:1
采用球型腔体声学共振法测量了新型制冷剂三氟乙烷(HFC143a)的气相音速,得到了压力在200~800kPa范围内,温度分别为293.61、302.96、313.19和323.18K时的4条等温线共28个音速数据.根据实验数据,由热力学关系式得到了HFC143a的理想气体比定压热容和第二音速维里系数等热力学性质,同时根据现有的高精度实验数据拟合了HFC143a的理想气体比热方程.温度、压力和气体音速测量的不确定度分别为±14mK、2.0kPa和±0.0037%. 相似文献