DFT study on nonlinear optical properties of lithium-doped corannulene

The effects of lithium doping on the nonlinear optical properties of new electrodes (lithium-doped corannulene) were investigated in detail. Nine dynamically stable geometries of Lin-C20H10 (n=1, 2) are predicted by B3LYP/6-31G(d,p). Among these nine structures, the largest first static hyperpolarizability (β0) is computed to be 15314 au, which is dramatically larger than the β0 value of 74 au for C20H10, indicating that Li doping plays an important role in elevating the first hyperpolarizability of corannulene.     

Remobilization of heavy metals during the resuspension of Liangshui River sediments using an annular flume

The release and transport of heavy metals(Ni,Cr,Cu and Pb) from Liangshui River sediments into the overlying water column during the resuspension event were determined using an annular flume with a velocity ranging from 0.15 to 0.35 m/s.It is shown that the suspended particulate matters(SPM) increased as much as nearly 25 times from 165 to 4220 mg/L as the velocity increased.Heavy metals showed an increase in dissolved phase as the velocity increased due to their desorption from the SPM.Acid-soluble heavy metals increased as the velocity increased,indicating that part of the heavy metals transformed from stable phase to labile phase during resuspension.Heavy metal concentrations in the SPM on volume normalization increased by approximately 2-6 times.However,on the mass weighted basis they decreased,approaching the bulk-sediment contents at high velocity,due to the "particle concentration effect".The distribution coefficients(K D) of heavy metals were higher at slower velocity during the sediment resuspension,which could be attributed to the decrease of fine particles(silt/clay fraction) during resuspension.     

Estimation of urbanization bias in observed surface temperature change in China from 1980 to 2009 using satellite land-use data

Since the 1980s,China has undergone rapid urbanization.Meanwhile,the climate has been warming substantially.In this paper,the urbanization effect on observed temperatures from 1980 to 2009 in China is estimated,based on analysis of urban land use from satellite observation.Urban land-use expansion(U) during 1980-2005 is applied as an urbanization index.According to these U values,stations are divided into three categories:(C1) intense urbanization around the stations;(C2) moderate urbanization around the stations;and(C3) minimal urbanization around the stations.Most C1 stations are in municipalities or provincial capitals,while C2 stations tend to be in prefecture-level cities.C3 stations are mostly in counties.The urban heat island(UHI) effect can be estimated if the urban effect on C3 is negligible.The warming of C1 or C2 relative to that of C3 represents their urbanization effects,assuming that the same larger-scale natural warming has affected each category.For C1,the local urbanization effect is 0.258°C/10 a over 1980-2009,accounting for 41% of the total warming;the trend at C2 is 0.099°C/10 a,or 21%.For all China,the urbanization effect is 0.09°C/10a,accounting for 20% of the total national warming.Winter urban warming is greater than in summer.The assumption of negligible urbanization effect on C3 is debatable,and so the true urbanization effect may equal or slightly exceed estimates.Further,the U index may have some uncertainties,for it is only one of the urbanization indices.However,it provides a new and direct estimation of environmental change,in contrast to indirect indices.     

杜洛克与梅山猪卵泡中Grb14、eIF4E和SNRPE基因的差异表达研究

为了探讨梅山与杜洛克母猪卵泡中差异表达基因对猪排卵与繁殖性状的影响,对在前期试验中通过消减杂交技术得到的EST杜大5、杜大46、杜大35进行了分析。序列分析结果表明,EST杜大5、杜大46、杜大35分别代表了Grb14、SNRPE、eIF4E基因。组织表达谱分析结果表明,这些EST在各个组织中均有不同程度的表达,其中Grb14基因只在肝脏、肾脏和卵巢、输卵管、黄体、垂体等繁殖相关器官高表达。荧光定量分析结果表明,这些基因在杜洛克猪大卵泡中的表达量均高于在梅山猪大卵泡中的表达量,其中SNRPE、eIF4E基因达到显著水平,在两猪种其他各级别卵泡中也有不同程度的表达差异,其中Grb14在杜M2中的表达量达到梅M2的2.13倍,差异显著,eIF4E基因在杜M1的表达量是梅M1的0.46倍,差异极显著。在猪种内大卵泡L、中等卵泡M2、中等卵泡M1、小卵泡S的相对表达量也有不同程度的差异。这些差异表达的基因可能影响卵泡发育和成熟,为深入了解这些基因在卵泡发育中的作用奠定了基础。     

基于脉冲耦合神经网络的结构损伤检测方法研究

机械结构的损伤发展到一定程度,会对其功能产生严重影响,所以及早检测出损伤非常必要。针对机械结构在损伤发生时其内部能量分布会发生变化的情况,对加速度计测得的结构振动信号进行短时傅立叶变换,获得可以反映能量分布的时频谱图。使用脉冲耦合神经网络提取时频谱图的熵序列特征,很好地识别了结构的损伤。使用上述方法对简支梁的损伤进行了实验研究,验证了其有效性和实用性。     

浅谈会计权益理论

本文从研究高职院校经济数学课程教育目标入手,从经济数学课程内容体系改革、教材建设改革、教学方法和考核方式改革以及数学建模活动的开展等四个方面给出经济数学课程建设和改革的实施方案。     

散体货物对敞车静侧压力的颗粒流数值模拟

以C80B敞车为研究对象,采用颗粒流程序对不同散体对敞车的静侧压力和内、外摩擦角变化时的散体侧压力沿敞车墙高的分布规律进行仿真模拟,其结果与库仑理论计算值进行比较.得出侧压力沿墙高非线性分布结果,而不是如库仑理论所计算的线性分布;侧压力的最大值位置随着内、外摩擦角的变化而上移.这种侧压力沿墙高非线性分布和侧压力最大值的位置与敞车的实际压力分布状况相符.颗粒流模拟结果指出了将离散元的方法应用于货车领域的可行性和有效性.     

基于状态空间的桥梁颤振分析

针对基于Scanlan自激力模型的桥梁颤振分析方法不能直接以风速作为参数对颤振临界风速进行自动无迭代搜索的缺陷,采用现代控制理论中对动态系统的状态空间描述方式,将结构和气流作为一个动态系统,在状态空间内对自激力进行表达,建立桥梁颤振运动方程并实现了桥梁颤振临界风速的直接求解.通过对系统状态空间中的气动状态进行优化处理,减小了系统状态空间的维数,并结合模态跟踪技术解决了基于状态空间颤振分析中关于结构固有模态根识别的问题.以具有理论解的理想平板截面的简支梁为例验证了算法的正确性,并将其应用于润扬长江大桥的颤振分析中,分析结果和风洞试验结果基本一致.     

有氧健身操对女大学生体脂成分及心肺机能的影响

本研究对持续参加一学期有氧健身操锻炼的部分女大学生锻炼前后体脂成分指标和心肺机能指标进行测试,结果显示:长期参加有氧健身操锻炼可消除体内多余脂肪、降低体脂,使女大学生体型更加健美和谐;同时有效地改善心肺功能,提高女大学生的有氧耐力,对预防心血管疾病具有重要作用。     

Controllability and Observability of Stochastic Singular Systems in Banach Spaces

Journal of Systems Science and Complexity - Exact (approximate) controllability and exact (approximate) observability of stochastic singular systems in Banach spaces are discussed. Firstly, the...