结构混凝土抗压强度预测RBF-ANN模型

为了达到对C20~C40范围内的结构混凝土抗压强度快速准确预测的目的,基于RBF-ANN模型基本原理及应用特点,在钻芯法、回弹法、超声波法及回弹-超声波综合法等大量室内和现场无损检测试验基础上,进一步应用Matlab2012b神经网络工具箱,建立了混凝土抗压强度RBF-ANN预测模型。该模型经充分训练后,应用于山西省重点建设工程项目的结构混凝土质量控制。工程实践表明,构建的RBF-ANN模型预测精度为4.4%,满足工程实际需要,具有较好的便捷性、经济性和准确性。     

柔性双段腿的SLIP模型参数敏感性分析

为了反映腿部多段串联的多参数耦合特性,以SLIP(spring loaded inverted pendulum)模型为基础,建立了小腿含有串联线性伸缩弹簧的机器人柔性双段腿动力学模型。通过仿真分析其运动,获得柔性双段腿弹簧刚度、触地角度、虚拟腿长、膝关节角度、质量分布等参数的稳定域。通过对各个参数稳定域进行归一化处理和曲线拟合,获得参数稳定域变化曲线及参数敏感度排序。最后基于ADAMS与MATLAB联合仿真验证了柔性双段腿模型中参数敏感度排序的正确性。     

3-(4-硝基苯基)氨基-1H-吲哚-4(5H)-酮的简便合成及结构表征

以对甲氧基乙二醛一水合物、3-苯氨基-5,5-二甲基-2-环己烯-1-酮和4-硝基苯胺为原料,对甲苯磺酸为催化剂,在乙醇溶剂中,微波辐射下多组分一步法合成标题化合物C29H27N3O4.其结构通过单晶X射线衍射法确定,晶体属三斜晶系,空间群P1,Mr=481.54,晶胞参数:a=0.617 80(5)nm,b=1.291 04(11)nm,c=1.606 78(13)nm,V=1.237 45(18)nm3,Z=2,Dc=1.292 Mg·m-3,μ=0.087mm-1,F(000)=508.晶体结构用直接法解出,经全矩阵最小二乘法对原子参数进行修正,最终的偏离因子R=0.059 3,Rw=0.134 8.在晶体结构中新形成的吡咯环为芳构化的共平面结构.     

Effect of Ce addition on hot tearing behavior of AZ91 alloy

A small amount of cerium (below 1.0 wt%) addition to AZ91 alloy have been investigated on the hot tearing susceptibility (HTS) at a cooling rate of 1.5Ks^?1. The HTS increased to a maximum value with a cerium addition of 0.6 wt% and then decreased to a stable status as cerium was gradually added. Due to high chemical activity, cerium into the melts can react with aluminum to form an Al₁₁Ce₃ intermetallic compound. X–ray diffraction results also confirmed the existence of Al₁₁Ce₃. The Al₁₁Ce₃ increased with the presence of the needle-like and block morphology. As cerium levels increased, the amount of Mg₁₇Al₁₂ decreased. The variations between Mg₁₇Al₁₂ and Al₁₁Ce₃ resulted in a similar normal distribution of the HTS in AZ91 alloy. The findings were further verified through the microstructure evolution and the surface morphology of fracture.     

Template/surfactant free and UV light irradiation assisted fabrication of Mn-Co oxides composite nanorings: Structure and synthesis mechanism

A facile, green, cost effective, and template or surfactant free strategy via a two-step route i.e. UV irradiation followed by dissolution-growth for the controlled synthesis of Mn-Co composite nanorings at room temperature was proposed. The nanorings structures and the process were systematically studied via TEM, HRTEM, EDX and XRD. Bir-MnO_2 nanosheets first formed through the direct photolysis of KMnO_4 under UV light irradiation. This was followed by a dissolution-growth process via the dissolution of Bir-MnO_2 nanosheets by the generated H~+ from the redox reaction between the added Co(NO_3)_2 and residual KMnO_4, as well as the accompanied formation of CoOOH, and Mn-Co composite nanorings. It was found that a balance between the dissolution and growth rate was needed. Suitable pH, KMnO_4 presence and the starting nanosheets like Bir-MnO_2 were the key factors for the formation of nanorings. The obtained Mn-Co nanorings/TiO_2 showed enhanced efficiency for the catalytic oxidation of HCHO. Based on the above understandings, it is believed that the developed dissolution-growth method can be adopted for the designing and preparation of other Mn-Co composite nanostructures which can be further applied for environmental pollution remediation.     

略论江西红色文化与高校学生党建工作

江西红色文化是中国共产党领导新民主主义革命在江西区域留下的丰硕成果,在物质和非物质两个层面展示出中华文明璀灿的光辉。高校是培养建成社会主义全面小康社会人才和接班人的重要阵地,学生党建工作更是事关实现中华民族伟大复兴。本文比较全面和深刻地分析了江西红色文化的载体、内涵和特征,就新时期高校学生党建工作面临挑战条件下,如何运用这一宝贵文化资源,创新学生党建的质量和水平,提出了理念思路和方式方法。     

High-performance flexural fatigue of carbon nanotube yarns

Carbon nanotube yarns （CNTY） possess good specific strength and specific conductivity. As such, their potential for commercial applications is significant. Fatigue performance is a significant consideration in yarn/wire applications. In this study, the flexural fatigue performance of CNTY spun from super-aligned carbon nanotube arrays was investigated using a reversed bending test. The results showed that CNTY exhibited excellent resistance to pure flexural fatigue, significantly outperforming stainless steel wire; CNTY failed where a combination of flexural fatigue and tension-tension fatigue had special hollow fracture morphology, and CNTY resistance remained fundamentally unchanged in the combination fatigue process.     

Privacy Quantification Model Based on the Bayes Conditional Risk in Location-Based Services

The widespread use of Location-Based Services(LBSs),which allows untrusted service providers to collect large quantities of information regarding users’locations,has raised serious privacy concerns.In response to these issues,a variety of LBS Privacy Protection Mechanisms(LPPMs)have been recently proposed.However,evaluating these LPPMs remains problematic because of the absence of a generic adversarial model for most existing privacy metrics.In particular,the relationships between these metrics have not been examined in depth under a common adversarial model,leading to a possible selection of the inappropriate metric,which runs the risk of wrongly evaluating LPPMs.In this paper,we address these issues by proposing a privacy quantification model,which is based on Bayes conditional privacy,to specify a general adversarial model.This model employs a general definition of conditional privacy regarding the adversary’s estimation error to compare the different LBS privacy metrics.Moreover,we present a theoretical analysis for specifying how to connect our metric with other popular LBS privacy metrics.We show that our privacy quantification model permits interpretation and comparison of various popular LBS privacy metrics under a common perspective.Our results contribute to a better understanding of how privacy properties can be measured,as well as to the better selection of the most appropriate metric for any given LBS application.     

金红石TiO2(011)表面的理论研究进展

基于密度泛函理论 (DFT) 的第一性原理 (First-principles) 计算方法，就金红石TiO₂(011)表面在理论方面的研究进展做了介绍.首先，通过阐述研究金红石TiO₂(011)表面的必要性和实验在其结构方面的研究进展，介绍了金红石TiO₂(011)表面的电子结构和光学性质，指出并验证了该表面对可见光有较强的响应能力.随后，介绍了金红石TiO₂(011)表面的缺陷和杂质，指出吸附H原子和形成O缺陷后还能显著增强其在红外区的红外吸收.在此基础上，不仅从理论上提供了一些传统实验所无法提及的数据资料，还弥补了相关实验在微观领域研究中的不足.最后，就目前金红石TiO₂(011)表面研究中存在的问题做了展望，指出金红石TiO₂(011)表面各种表面现象的微观本质是未来研究的重点内容.