Experimental investigation of incremental reactivity of di-tert-butyl peroxide

Large quantities of di-tert-butyl peroxide (DTBP) have been emitted into the troposphere due to human activities. Its role in the atmospheric photochemical reaction has not been understood. This study presents the results of the photochemical reactions of DTBP and NOx, which have been simulated in a self-made smog chamber under the temperature of (29±1)℃. Both the wall decays of ozone and NO2 could be neglected, compared to the results in simulative experiments. The effective intensity of UV light used in the experiments was 1.28×10-3 s-1, which was expressed by the rate constant of NO2 photolysis in purified air. The reaction mechanism was proposed according to our results and reports of other researchers. The maximum values of incremental reactivity (IR) in the three simulative ex- periments were 9.53×10-2, 5.23×10-2 and 3.78×10-2, respectively. The incremental reactivity decreased with the increase of initial concentrations of DTBP. The IR value of DTBP obtained in this study was comparable to that of acetylene reported in our previous research.     

Reconstruction of linkage maps in the distorted segregation populations of backcross, doubled haploid and recombinant inbred lines

Non-Mendelian segregation of markers, known as distorted segregation, is a common biological phenomenon. Although segregation distortion affects the estimation of map distances and the results of quantitative trait loci (QTL) mapping, the effects of distorted markers are often ignored in the construction of linkage maps and in QTL mapping. Recently, we have developed a multipoint method via a Hidden Markov chain method to reconstruct linkage maps in an F2 population that corrects for bias of map distances between distorted markers. In this article, the method is extended to cover backcross, doubled haploid and recombinant inbred line (RIL) populations. The results from simulated experiments show that: (1) the degree that two linked segregation distortion loci (SDL) affect the estimation of map distances increases as SDL heritability and interval length between adjacent markers increase, whereas sample size has little effect on the bias; (2) two linked SDL result in the underesti- mation of linkage distances for most cases, overestimation for an additive model with opposite additive effects, and unbiased estimation for an epistatic model with negative additive-by-additive effects; (3) the proposed method can obtain the unbiased estimation of linkage distance. This new method was applied to a rice RIL population with severely distorted segregation to reconstruct the linkage maps, and a bootstrap method was used to obtain 95% confidence intervals of map distances. The results from real data analysis further demonstrate the utility of our method, which provides a foundation for the inheritance analysis of quantitative and viability traits.     

面向学生的个性化智能型教学平台的构成和应用

本文结合“电大在线”教学平台和作者开发的个性化智能学习服务系统,依据现代教学设计理论和学习理论建立了面向学生的个性化智能教学平台的组成模块,分析了各模块的特点,并设计教学平台,支持面向学生的个性化教学。     

Plasma sheet stretching accompanied by field aligned energetic ion fluxes observed by the NUADU instrument aboard TC-2

The NUADU (NeUtral Atom Detector Unit) instrument aboard TC-2 recorded 4л solid angle images of charged particles (E >180 keV) spiraling around the magnetic field lines in the near-Earth plasma sheet (at ~ -7 RE, equatorial dawn-to-night side) during a geomagnetic storm (Dst =-219 nT) on August 24, 2005. Energetic ion beam events characterized by symmetrical, ring-like, solid angle distributions around ambient magnetic field lines were observed during a 34-minute traversal of the plasma sheet by the TC-2 spacecraft. Also, observations during these multiple crossings of the plasma sheet were monitored by the magnetometer experiment (FGM) aboard the same spacecraft. During each crossing, a whistler-mode chorus enhancement was observed in the anisotropic area by the TC-2 low frequency electromagnetic wave detector (LFEW/TC-2) at a frequency just above that of the local lower hybrid wave. A comparison of the ion pitch angle distribution (PAD) map with the ambient magnetic field shows that an enhancement in the field aligned energetic ion flux was accompanied by tailward stretching of the magnetic field lines in the plasma sheet. In contrast, the perpendicular ion-flux enhancement was accompanied by a signature indicating the corresponding shrinkage of the magnetic field lines in the plasma sheet. Since both parallel ion-flux and perpendicular ion-flux enhancements occurred intermittently, the data were interpreted to imply a dynamical, oscillatory process of the magnetic field line (stretching and shrinking) in the near-Earth plasma sheet, which might have acted to help establish an interaction region in this area which would support continuous aurora-substorm triggering during the ongoing magnetic storm. The whistler-mode chorus may have been produced due to ion gyro-resonance during particle pitch angle diffusion after the plasma sheet compression.     

污水处理过程的模糊参数自校正控制器设计

针对城市污水生物处理过程存在的本质的非线性特性,采用了基于神经网络的模糊自校正方法的控制策略,同时为了提高控制的精度,比较了各种不同的隶属度函数对控制误差的影响。仿真实验结果表明,通过本方法设计的控制器可以获得满意的控制效果。     

可数基-中紧空间

文章引入了可数基-中紧空间，并且获得了如下主要结果：1）设f：X→Y为完备映射，Y为可数基-中紧空间，则X是可数基-中紧空间.2）设X是可数基-中紧空间，Y是紧空间，则X×Y是可数基-中紧空间.3）设X是可数基-中紧空间，Y是局部紧的可数基-中紧空间，则X×Y是可数基-中紧空间.     

双模压缩光场作用下电子干涉器件中电子密度的关联

通过对双模压缩态光场和两个电子干涉器件相互作用的研究，得到了两个电子干涉器件中电子密度的关联，并采用归一化关联函数来描述这种关联，发现通过选择合适的初始相位差，量子关联可以很好地从双模压缩态光场转移到电子。     

基于Hamaker假设的黏着接触弹性模型

为研究微纳米系统中的黏着接触问题，基于Hamaker假设和Lennard-Jones的势能定律，通过积分方法得到了球体与平面间的黏着力，同时结合经典弹性理论建立了一种新型的球体与平面黏着接触的弹性模型．该模型可以同时得到平面轮廓随间距的变形过程及黏着力和平面变形量随间距的变化规律，当球体半径较大时，所建模型与基于Derjaguin近似的黏着模型给出的结果基本一致，随着球体半径的逐渐减小，2种模型的差异逐渐增大，这是由于Derjaguin近似的误差随球体半径的减小而增大引起的．因此，当球体的半径趋近纳米级时，基于Hamaker假设的黏着接触模型消除了Derjaguin近似所带来的误差，可以更加准确地给出黏着力和平面变形量随间距的变化规律．     

基态氢原子的光电离截面

考虑末态电子与靶离子间的相互作用，作库仑波近似，导出了氢原子光电效应散射截面的解析形式。得出在低能特别是接近阈值时，末态相互作用对光电离截面起决定作用的结论。