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811.
XIEWenwei GUOYanchuan GANChangsheng YANTiantang PANZhongxiao PENGBixian 《科学通报(英文版)》2003,48(5):424-429
A series of 1,8,15,22-tetra(2,4-ditertbutylphen-oxy) phthalocyanines [α-(oAr)4PcM,M1=(H)2,M2=Pd,M3=Cu,M4=Zn,M5=Pb] were synthesized in this study.Each compound was bromized in two kinds of solvent.One is the solvent mixture of 1,1,2-trichloroethane and water,the other is 1,1,2-trichloroethane alone.The effects of solvent,bromine excess added and reaction duration on the bromization reaction were studied.The shift of maximum absorbance wave-length both is solution and in solid thin film was investigated comparatively,discovering that both were bathochromism but the former was more.TG data showed that the temperature of thermal decomposition decreased continuously with the increase of numbers of bromine.Finally,the fragments produced during the bromization of (OAr)4PcPb in 1,1,2-trichloroethane were characterized by GC/MS.Based on the electronic structure,the possible mechanism of decomposition of these compounds was presented and discussed. 相似文献
812.
浅谈公路黄土边坡坡面防护 总被引:1,自引:0,他引:1
Jia Yunjie 《科学之友》2007,(8)
在前人进行边坡优化设计的基础上充分考虑了坡面的不稳定因素,对边坡的坡角和坡高等进行设计,并总结了黄土地区边坡坡面的防治措施。 相似文献
813.
This study evaluates performance of information criteria used to separate latent classes. In the evaluations, various numbers
of latent classes, sample sizes, parameter structures and latent-class complexities were designed to simulate datasets. The
average accuracy rates of information criteria in selecting the designed numbers of latent classes were the core results in
this experiment. The study revealed that widely used information criteria, e.g., AIC, BIC, CAIC, could perform poorly under
some circumstances. By including a sample size adjustment (Rissanen, 1978), the unsatis-factory performances could be improved
considerably. The sample size adjustment provides a plausible solution for separating latent classes. Guidelines are provided
to help achieve optimum use of the model fit indices. 相似文献
814.
利用网络中未使用IP地址构建扫描检测平台能够有效提高检测准确率,降低虚警率.在扫描检测平台实际构建之前,需要对可控部署地址资源的预计检测效用进行评估,以确定地址资源可达的检测目标以及明确平台构建的必要性.为此,提出一种基于网络分类的扫描检测模型,依据此模型可对扫描检测平台对于随机扫描源和本地优先扫描源的检测效用进行评估,为扫描检测平台部署构建提供理论指导.以法国电信Leurre’com Honeynet Project实际分布式检测平台作为效用评估样例.评估结果表明该检测平台能够有效检测类似Slammer蠕虫的高速随机扫描源和每秒至少发出2个扫描连接的本地优先扫描源,对低速扫描源检测效用低下.实际数据统计结果与仿真实验验证了评估结果的准确性. 相似文献
815.
816.
In the era of e-businesses, the traditional business services are greatly challenged by the ever-increasing demands from customers with various backgrounds and personalities. Large numbers of new e-businesses are driven by the needs of customers. The existing dynamics inherent in the customer needs require the corresponding dynamic management of services. Attempting to respond to customers in a rapid and intelligent way, this paper proposes a situation calculus based approach for dynamically managing e-Business services in the ubiquitous environment. By employing the formalism of the situation calculus to enable intelligence and automation, the approach can implement. the functions of service automatic composition and model verification. These functions will improve the degree of customer-orientation and enable fast responsiveness in the emerging e-service systems. 相似文献
817.
Conflict analysis approaches for investigating attitudes and misperceptions in the War of 1812 总被引:1,自引:0,他引:1
Formal systems engineering approaches to modeling misperceptions and attitudes are employed within the framework of the graph model for conflict resolution to systematically study the War of 1812 between the United States of America and Great Britain in order to provide enhanced insights into the causes of the war. More specifically, relational definitions for preferences, movements and stability concepts are defined for describing the attitudes and associated behavior of decision makers involved in a conflict. To capture misperceptions of decision makers in the War of 1812, attitudes are studied within the structure of a hypergame. Combining attitudes and misperceptions within the paradigm of the graph model furnishes the flexible analytical tool which demonstrates that misunderstanding of attitudes by Great Britain and the United States may have contributed to the outbreak of this nasty war. 相似文献
818.
Jinwang LIU Dongmei LI Xiaosong CHEN 《系统科学与复杂性》2007,20(4):610-613
Polynomial composition is the operation of replacing variables in a polynomial with other polynomials. λ-Grgbner basis is an especial Grobner basis. The main problem in the paper is: when does composition commute with λ-Grobner basis computation? We shall answer better the above question. This has a natural application in the computation of λ-Grobner bases. 相似文献
819.
Daniel S. Yeung Wing W. Y. Ng Aki P. F. Chan Patrick P. K. Chan Michael Firth Eric C. C. Tsang 《系统科学与系统工程学报(英文版)》2007,16(2):166-180
Company bankruptcies cost billions of dollars in losses to banks each year. Thus credit risk prediction is a critical part of a bank's loan approval decision process. Traditional financial models for credit risk prediction are no longer adequate for describing today's complex relationship between the financial health and potential bankruptcy of a company. In this work, a multiple classifier system (embedded in a multiple intelligent agent system) is proposed to predict the financial health of a company. In our model, each individual agent (classifier) makes a prediction on the likelihood of credit risk based on only partial information of the company. Each of the agents is an expert, but has limited knowledge (represented by features) about the company. The decisions of all agents are combined together to form a final credit risk prediction. Experiments show that our model out-performs other existing methods using the benchmarking Compustat American Corporations dataset. 相似文献
820.
Penny Singh 《Systemic Practice and Action Research》2007,20(4):293-304
This study started with problems that my colleagues (and I) were experiencing with interaction and intercultural communication
among students in our diverse classrooms. Educators were also experiencing difficulties in motivating students to work effectively
in groups. The purpose of this paper was to seek solutions to these problems by exploring variations of the group oral assessment
structure in a multilingual and multicultural context. Four phases of assessments were conducted at two tertiary institutions
in South Africa using a combination of action research and a participatory approach. Not only did this study succeed in addressing
the problems but it also revealed the added benefits of using an action research methodology. 相似文献