ZnO microsheet modified TiO<Subscript>2</Subscript> nanoparticle composite films for dye-sensitized solar cells

Randomly oriented ZnO microsheets were successfully self-assembled on TiO₂ nanoparticle (TN) film to act as the scattering layer via a cathodic electrodeposition process. The light scattering properties of ZnO microsheets were studied by UV-Vis spectrometer in the 400–800 nm wavelength range. It was found that ZnO microsheets exhibited excellent ability to scatter the incident light for ZnO microsheet-TiO₂ nanoparticle (ZT) composite films. The results showed that dye-sensitized solar cells (DSSCs) fabricated with ZT composite films showed higher short-circuit density (J_sc) and conversion efficiency than TN-based DSSCs, due to the light scattering properties of ZnO microsheets.     

A parallel approach to direct resolution of albuterol

A library consisting of a series of O,O′-diaryzoyl-L-(–)-tartaric acids (2) was designed and synthesized. The substituent on the aromatic ring of 2 significantly affects the diastereomeric excess and efficiency of the resolution of racemic albuterol (1). Excellent resolving reagent 2a was selected for the resolution of rac-1 via the parallel approach. However, a family of three resolving reagents failed to improve the resolution efficiency of rac-1.     

竹炭基活性炭电容去离子性能的研究

电容去离子技术可以通过施加静电场,强制离子向带有相反电荷的电极迁移,使其被电极表面产生的双电层吸附并从溶液中去除,从而达到水净化的目的.以活性炭作电极材料制备了电容去离子模拟装置,考察了该装置在通直流电的情况下的去离子性能,详细研究了处理水流速、处理水量、电极片距离与电极片对数等因素对水净化的影响及电极的反洗效果.结果表明,当流速为60mL/min,处理水量为4800mL,电极片间距为2cm,电极片对数为4对时,活性炭电极电去离子模拟装置的去离子效果最好,并表现出较好的循环利用性.对不同重金属的去除效果分别为:Pb2+Cu2+Cr3+Cd2+.此工作为活性炭型电容去离子技术提供了重要的参考价值.     

制冷陈列柜性能优化策略的应用

利用改进的双流体(MTF)模型对立式敞开型陈列柜冷风幕及其四周气体流动和传热进行数值模拟,从而确定陈列柜的漏风量.通过MTF得到的结果训练并验证针对漏风量的自适应支持向量机(ASVM)算法,建立陈列柜性能的优化函数.实验测试验证结果表明,优化后的陈列柜融霜后的凝结水质量和单位展示面积每日耗电量分别减少39.2%和19.3%,明显改善了漏风.     

BDI指数与上证综指的相关性

波罗的海干散货指数(BDI)和上海证券综合指数(上证综指)在2007—2009年的走势反映了金融危机背景下世界经济的变化趋势.选取2007—2009年BDI指数和上证综指的周均值作为实证研究的样本数据,对曲线图、散点图进行描述性分析,并进行相关性和波动趋势分析.结果显示:BDI指数与上证综指呈现正相关;上证综指一定程度上揭示了中国和世界经济的走势,确切反映了中国经济与世界航运市场的变化状况;上证综指的可借鉴性优于BDI.金融危机的爆发证明上证综指具有解释中国和世界航运市场变化的指向标的作用.     

Palaeoclimatic evolution recorded by multidicipline in sediments in gahai lake, qaidam basin since late last deglacial

Based on the analyses of Loss-on-Ignition (LOI), carbonate content and sediment characteristics, this paper reconstructs the climatic and environmental evolution of the Gahai Lake area since the late Last Deglacial Period.The results cover the late Last Deglacial Period and the Holocene.The climate was very unstable and rather arid during the late Last Deglacial Period.The Holocene can be divided into three pe-riods:the early Holocene (11360-8240 cal aB.P.), which was dry but unstable and featured rising tem-peratttres, the mid-Holocene (8240-3200 cal aB.P.), which was warm and wet and the late Holocene (since 3200 cal aBP), which was cold and dry.Results also show a warm-wet event around 1500 cal aB.P.     

定性分析和定量分析在海事风险评估中的应用

本文讨论定性分析和定量分析的定义、特点,并结合实例分析他们的优点、缺点及在海事风险评估中的实际应用.     

浅析自动气象站雷电保护

自动气象站作为一种集合了传感器、数据采集及处理、数据通信等技术的自动化电子设备,其抵御雷电兵贵损害的脆弱性是不言而喻的,因此预防雷电损害是自动气象站网可靠性设计的极其重要部分.本文从直击雷、感应雷及雷击电磁脉冲保护入手,提出了相应的解决办法,对做好自动气象站的雷击防护进行了探讨.     

无线传感器网络多轮任务调度算法

为了充分地利用网络资源,提出了一种分群结构下的无线传感器网络多轮任务调度算法(WMTSA).WMTSA以可分负载理论为基础,根据各个群的任务处理速率按多轮方案将总任务从SINK节点下发给各个群.为了去除由节点间通信干扰导致的性能下降,SINK节点相继向各个群首发送每一轮的负载.每一轮各个群执行完数据采集任务并把数据融合后,也由群首将该轮数据相继向SINK节点报告,使得任务执行和通信更好地重叠,最终减少了整个应用的响应时间且提高了网络资源利用率.实验结果表明,WMTSA可合理地将总任务分配给网络中的各个节点,从而有效地减少了完成任务的耗时耗能.随着网络规模的增大,总任务完成时间可以减少40%.     

Fe掺杂ZnS纳米线的制备及性能研究

利用水热法制备了Fe掺杂ZnS的纳米线．通过X射线衍射（XRD）、X射线能谱仪（EDS）、扫描电显微镜（SEM）和透射电子显微镜（TEM）分析了Fe掺杂对样品的结构和形貌的影响;利用紫外可见近红外分光光度计（uV-VIS）、共聚焦显微拉曼一荧光光谱仪（PL）和振动样品磁强计（VSM）对样品的光学特性进行表征．结果表明,样品为六角纤锌矿结构,Fe成功掺入ZnS晶格中,形成替位式掺杂．随着Fe掺杂浓度的增加,样品的吸收峰出现蓝移且发光强度逐渐减弱．掺杂后的样品在室温下呈现了铁磁性．