Thermal performance and reduction kinetic analysis of cold-bonded pellets with CO and H_2 mixtures

Cold-bonded pellets, to which a new type of inorganic binder was applied, were reduced by H2–CO mixtures with different H2/CO molar ratios(1:0, 5:2, 1:1, 2:5, and 0:1) under various temperatures(1023, 1123, 1223, 1323, and 1423 K) in a thermogravimetric analysis apparatus. The effects of gas composition, temperature, and binder ratio on the reduction process were studied, and the microstructure of reduced pellets was observed by scanning electron microscopy–energy-dispersive spectrometry(SEM-EDS). The SEM-EDS images show that binder particles exist in pellets in two forms, and the form that binder particles completely surround ore particles has a more significant hinder effect on the reduction. The reduction equilibrium constant, effective diffusion coefficient, and the reaction rate constant were calculated on the basis of the unreacted core model, and the promotion effect of temperature on reduction was further analyzed. The results show that no sintering phenomenon occurred at low temperatures and that the increasing reaction rate constant and high gas diffusion coefficient could maintain the promotion effect of temperature; however, when the sintering phenomenon occurs at high temperatures, gas diffusion is hindered and the promotion effect is diminished. The contribution of the overall equilibrium constant to the promotion effect depends on the gas composition.     

Experimental investigation and thermodynamic assessment of the yttriumhydrogen binary system

A coupled experimental investigation and thermodynamic study of the yttrium-hydrogen(Y-H) binary system were carried out to provide more comprehensive and quantitative insights into the key thermodynamic properties of this system. Y-H system in the full range of H/Y = 0–3.0 was investigated by accurate pressure composition isotherm(PCI) measurement to provide credible phase equilibria information and thermodynamic data.The phase boundaries obtained were in agreement with previous experimental data but with improved accuracy.With the guide of the crystal structures, all the solid phases were modelled using the three sublattice model. The Y-H phase diagram and thermodynamic parameters were calculated and assessed with the CALPHAD technique.The obtained results are in very good agreement with our experimental data and the published data reported in literature. The obtained thermodynamic database of Y-H system can be used to predict the hydrogenation behavior and decomposition temperatures of hydrides.     

同步荧光法测定蔬菜中维生素E含量

探讨了同步荧光测定蔬菜中维生素E的实验条件的优化选择,结果表明,用石油醚(30～60 ℃)作萃取剂,当Δλ=30 nm时,在激发波长为295 nm处测定维生素E,石油醚和维生素E的荧光光谱能够很好地分离.在0.01～10 mg/L内,荧光强度和维生素E质量浓度呈良好的线性关系,I=16.17ρ+1.123 5,其相关系数r=0.999 5,平均回收率为101.37%,相对标准偏差(RSD)为1.78%.该法操作简便,快速,准确性高,重复性好.     

环介导等温扩增技术检测乳粉中肺炎克雷伯菌

以荚膜脂多糖(capsular polysaccharide,CPS)合成调控子resA为靶基因片段,设计了肺炎克雷伯菌特异性引物,建立了环介导恒温扩增技术(Loop-Mediated lsothermal Amplification,LAMP)检测方法.结果表明,3对LAMP引物对肺炎克雷伯菌不仅有菌种专一性,而且,具有相当高的灵敏度(2 CFU/100 g).因此,该方法有利于更快更准确的鉴定食品中肺炎克雷伯氏菌.     

硅上液晶微型显示器发展史综述

分析集成硅上液晶（LCoS)模型显示器的两门先进技术，即半导体技术和LCD技术的发展历史。认为LCoS是集半导体技术和LCD技术而成的高新技术。LCoS的出现有赖于这两项技术的发展。反过来LCoS又促进这两项技术的发展，LCoS在微显示器系统中有巨大的应用前景，具有相当大的潜在市场。     

一种新型的无搜索求解策略

提出一种基于模糊逻辑和神经网络的专家系统，它是一种集信息表达，生成与求解为一体的新型求解系。本系统的核心－学习推理网，网络的知识表达是分布的，可实现并行推理，不需要进行搜索和匹配。     

2-取代芳基苯并咪唑-Cu(Ⅱ)络合物的研究

合成了3种2-取代芳基苯并咪唑- Cu(Ⅱ)络合物,通过苯并咪唑与Cu(Ⅱ)反应前后红外光谱解析,表明二者发生了络合反应;采用摩尔比法测定了该络合反应的配位数、X射线衍射测定了络合物的结构,确定了该络合物中心原子Cu(Ⅱ)和配体苯并咪唑分子的空间构型.     

一种使用遗传算法生成模糊控制器的方法

提出一种使用遗传算法生成模糊控制器的方法．设计人员只需设置性能指数或适值函数,而模糊规则的数目、隶属函数的参数以及模糊控制器的规则都可通过遗传算法自动生成．描述了一种具有局部优化机制的遗传算法,给出的应用实例表明该算法具有良好的适用性     

高校"助理班主任"模式的利弊分析

在高校中实行“助理班主任”制度,有利于高校学生管理工作的进行,有利于学生能力的提高,但这一模式还存在一定的问题,这就需要我们进一步探索。     

光活性苄亚胺环钯配合物的合成

在无水乙醇溶液中实现了４－甲氧基苯甲醛与Ｌ－丙胺酸甲酯的亲核加成反应,制得了光活性的Ｎ－（２＇－丙胺酸甲酯）苄亚胺。后者与乙酸钯、卤化锂或碘化钾作用,可分别制得由卤原子桥连而成的苄亚胺环钯化合物二聚体,它们可与三苯基膦或吡啶生成相应的苄亚胺环钯配合物。其产物结构分别经比旋光度、元素分析和ＮＭＲ谱测定。