Ionic liquids containing the urea moiety for recognition of halides and complex anions

A series of novel imidazolium based ionic liquids containing the urea moiety were designed and synthesized for anion recognition. 1-Ethylurea-3-methylimidazolium acetate ([Eumim]OAc) was used as the receptor for the halides and complex anions (BF4-, PF6-, BPh4-). 1H NMR spectra showed that the urea protons and imidazolium C(2) proton of the receptor ([Eumim]OAc) moved upfield on addition of various anions. A Job plot showed that the [Eumim]OAc receptor formed a 1:1 complex with BPh4-. X-ray diffraction analysis and the molecular modeling study revealed that the conformations of [Eumim]OAc and [Eumim]BPh4 were different. The conformational change of the cation was caused by anion exchange, and may provide an alternative to current methods for recognition of anions.     

Preparation and cytocompatibility of polylactic acid/hydroxyapatite/graphene oxide nanocomposite fibrous membrane

A series of polylactic acid (PLA) based nanocomposite fibrous membranes,including neat PLA,PLA/hydroxyapatite (HA) and PLA/HA/graphene oxide (GO),were fabricated via electrospinning method.The morphology and composition were investigated by scanning electron microscopy (SEM),X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FTIR) respectively.The thermal stability was determined by thermogravimetric analysis (TGA).To estimate the cytocompatibility of asprepared PLA/HA/GO fibrous membrane,MC3T3-E1 cells were cultured,and the corresponding cell adhesion and differentiation capability were investigated by fluorescence microscopy,SEM and MTT test.The electrospun ternary PLA/HA/GO membrane exhibited three-dimensional fibrous structure with relatively rough surface morphology,which made itself ideal for cell attachment and proliferation in bone tissue regeneration.The fluorescence microscopy,SEM and MTT test confirmed that the PLA/HA/GO nanocomposite fibrous membrane created a proper environment for the seeding and proliferation of MC3T3-E1 cells.     

Deposition of bio-mimicking graphene sheets with lotus leaf-like and cell-like structures on the nickel substrate

Bio-mimicking graphene films,deposited on textured nickel substrates,were synthesized by the following method:replicating the surface textures of the lotus leaf by polymer duplication,fabricating textured nickel substrates by electroplating on the polymer coated with a Au film,preparing bio-mimicking graphene oxide films on the nickel substrates by vacuum filtration,and electrochemical reduction.By controlling the vacuum filtration,this replica method can not only replicate the lotus leaf structure by a graphene film,but also can achieve a novel cell-like graphene film.     

Preparation, characterization and photodegradation of methylene blue based on TiO2 microparticles modified with thiophene substituents

The new microparticles,2-formylthiophene(FT)/TiO2 and(E)-1,2-bis(5-formyl-2-thienyl) ethylene(EBFTE)/TiO2 were synthesized with a silane coupling agent.The prepared TiO2 composites were characterized using Ultraviolet-Vis absorption(UV-Vis),X-ray diffraction(XRD),scanning electron microscope(SEM) and thermogravimetric analyzer(TGA).Methylene blue was used as a model material to examine the photocatalytic activities of the prepared catalysts under both Ultraviolet-Vis(UV) and visible(Vis) light.The enhanced photocatalytic activities were observed in the presence of(FT)/TiO2 and EBFTE/TiO2 under Vis light.It suggests that FT or EBFTE plays a block or active role in the photodegradation mechanisms under UV and Vis light irradiation,respectively.     

基于双阀芯的挖掘机振动掘削系统仿真分析

针对传统的机械式激振实现振动掘削的结构复杂、功能单一的缺点,根据双阀芯的工作原理设计了一个基于双阀芯的挖掘机振动掘削系统,该系统能通过控制液压系统实现振动掘削的精确控制并能方便地调节振动参数.为了在设计阶段实现系统的优化,分析不同振动加载方式对系统控制性能的影响,以双阀芯系统的数学模型为基础建立了双阀芯振动掘削系统的AMESim仿真模型,运用计算流量反馈的流量控制方法和PID算法实现了阀芯的流量控制,并对矩形波、正弦波和三角波三种流量输入波形的控制精确性进行了仿真分析,得出了三角波和正弦波要比矩形波输入控制更精确的结论,对振动参数优化试验有一定的指导意义.     

论《文心雕龙》的音乐观

由于儒家思想的重要影响,《文心雕龙》标举儒家音乐观。在审美本质论上,刘勰认为音乐的本质是现实生活的反映,尤其是社会政治生活的反映,音乐的发展变迁决定于现实政治的盛衰;通过音乐可以了解一个国家国势的兴废盛衰。在美感论上,刘勰认为音乐应该具有中和之美,应该是雅正的;他提倡的中和之乐,崇＂雅＂薄＂郑＂。在审美功能上,刘勰认为音乐具有重要的教化作用,应该发挥雅正音乐的教化功能。     

供应链企业知识资源配置主要模式研究

在分析供应链企业知识资源配置内涵与属性的基础上,根据供应链特征探讨了三维共享和市场化配置两种主要模式,指出只有通过两种模式共同作用实现知识资源配置的均衡性,才能提高资源配置效率,实现供应链企业知识资源共享目标。     

一类具有种群Logistic增长的SIR传染病模型的稳定性

研究一类具有种群Logistic增长的SIR传染病模型,应用微分方程定性理论,分别得到了该系统无病平衡点、地方病平衡点全局渐近稳定的充分条件,并进行了数值模拟.     

路基边坡生态恢复的新工艺探讨

以祁浮高速公路路基边坡施工为例,对喷混植生、液力喷播、BAG植生等典型的生态防护形式的施工工艺、施工中的关键因素进行了分析,针对施工中的重点和难点问题,提出了相应的措施。     

高强钢氢致滞后断裂滞后时间的有限元预测

基于氢相关的内聚力模型,开发了顺次耦合的氢致滞后断裂有限元计算程序,预测了预含氢AISI4135高强钢圆棒缺口试样在常载荷拉伸条件下的滞后断裂时间,并考察了试样初始平均含氢水平对滞后断裂的影响.结果表明,氢相关的内聚力模型可有效预测氢致滞后断裂的断裂时间,有限元预测结果和相关报道较为一致.氢致滞后断裂存在氢临界值,当缺口尖端应力集中区聚集的氢浓度达到临界时裂纹开始形核,此临界值和结构的初始含氢量无关.