西北村镇建筑冬季室内期望温度研究

对乌鲁木齐、西宁、西安、天水、银川5个典型西北地区村镇住宅建筑各主要功能房间的使用情况、采暖情况、温度、居民热需求、衣着和活动强度等进行测试与问卷调查,以得到主要功能房间间歇采暖时间段、采暖与否两种情况下居民的期望温度、室内活动强度与服装热阻对居民期望温度的影响。结果表明：采暖和非采暖情况下,卧室期望温度分别约为15～19℃和12～14℃;采暖和非采暖情况下,客厅期望温度分别约为16～19℃和11～13℃。冬季间歇采暖时间段可取为：主卧为19：00—次日8：30,次卧为20：30—次日8：00,客厅为8：30—19：00,但考虑到时差原因,采暖时段可作相应调整。     

离子交换树脂催化剂研究进展

本文介绍了近年来阳离子交换树脂催化剂的研究、开发及应用情况,着重介绍了阳离子交换树脂用作醚化及酯化反应催化剂方面的研究进展。     

含苯并咪唑八齿配体EGTB双核钴(Ⅱ)配合物的合成和表征

报导了八齿配体N,N,N′．N′四（2-苯并咪唑甲基）－1,4－H乙氨基乙二醚（EGTB）的4种从核钴（Ⅱ）配合物的合成及其红外（IR）、紫外可见（UV－Vis）光谱和电子自旋共振（ESR）谱表征．并用硝基蓝四氮唑（NBT）光照还原法证明这4种配合物均具有超氧化物歧化酶性质．与O_2反应的速率常数在10~6～10~7mol·L·s之间．     

机载雷达二维自适应处理的空时结构方法比较

在机载雷达时空二维信号处理中，通常有三种处理结构：空时级联、时空级联和空时联合域结构。尽管联合域最优处理在实际中不大可能应用，但它有极为重要的理论价值，人们已将其有用概念和方法应用于空时级联或时空级联结构中，这时“级联”一词的含意已不再是“空、时频率响应之积”，因而它们的性能将大大提高。本文对比分析了空时结构中几种自适应算法的性能，并讨论了其实际应用的可能性。     

基于SHELL单元模型的对薄壁件铣削仿真优化分析

为了实现对薄壁框架零件较高精度的铣削加工,通过基于SHELL单元所组成的有限元模型,在充分提高分析效率的基础上,分析了落刀位置、零件几何尺寸以及切削用量在加工过程中对零件变形的影响,最终对零件的不同切削参数下的变形量进行了分析.最终可以得出结论:采用基于SHELL单元的有限元模型在提高分析效率的基础上,可以对薄壁件的加工过程进行较为系统的优化最终以达到提高薄壁件加工精度和加工效率的目的.     

NPP distribution related to the terrains along the North-South Transect of Eastern China

Vegetation net primary productivity (NPP) is defined as the accumulative amount of organic matters per unit area and time, which is calculated from the difference between accumulative photosynthesis and accumulative autotrophic respiration by green plants. Since the NPP reflects the physiological and ecological characteristics of the plants and the interactive results of the environmental factors, it is an important index to evaluate a structure of ecological system, functional features and …     

K-rich lamellar exsolution in clinopyroxene： Constraint on the depth of peridotite source at Zhimafang

The oriented lamellar K-rich exsolutions within clinopyroxene host were recognized in garnet peridotite massif at Zhimafang in the Sulu ultrahigh pressure metamorphic terrane, eastern China. EMP and TEM analyses revealed that the composition and the index of electron diffraction for this exsolution are corresponding with phlogopite, and the shape is the lamellae with 1 μm in width and 5 to 30 μm in length. Moreover, the topotaxy is that the (001) of K-rich exsolution parallels to (I00) of the clinopyroxene host. The electron diffraction analyzing shows the exsolution is of a 1M polymorphism. The high-resolution lattice fringe image displays the stack features along [001], which only a layer mineral shows. We conclude that the clinopyroxene with IM and K-rich exsolution was probably derived from mantle depths over 240 km, thus resulting from decompressional exsolution in the initial stage of slab exhumation.     

复合轻型吸波涂层电磁参数及吸波性能的研究

制备了复合轻型导电导磁材料与环氧树脂吸波涂层,用3cm波导式测量线在9.2GHz测量其电磁参数及吸波性能.实验结果表明,复合导电导磁材料与环氧树脂的质量分数对吸波涂层的电磁参数及吸波性能有较大影响,当复合导电导磁材料与环氧树脂的质量分数为50%,涂层厚度为1.7mm时,吸波效果最好.其吸收峰值为34dB,大于10dB的有效带宽,达11GHz.     

土岩复合地层中深基坑开挖对邻近管线变形影响分析

为探究土岩复合地层中深基坑开挖对邻近管线变形的影响规律,开展了土岩复合地层中深基坑开挖的现场监测和数值模拟研究.以南京地铁一号线北延工程二桥公园站车站基坑为工程依托,基于现场实测数据进行了管线沉降变形分析,并使用PLAXIS 3D有限元分析软件进行数值模拟,揭示了管线与基坑间距、管线埋深等因素对管线变形的影响规律,并定...     

Special IR properties of palladium nanoparticles and their aggregations in CO molecular probe infrared spectroscopy

Dispersed Pd nanoparticles (Pdn) have been synthesized by reducing H2PdCI4 with ethanol, and stabilized using poly(vinylpyrrolidone) (PVP). The Pdn is applied to the glassy carbon substrate to form a thin film, and then the potential cyclic scanning at 50 mV.s^-1 from -0.25 to 1.25 V was carried out for about 30 min to form the aggregations of Pdn (Pdn^ag). FTIR spectroscopy of both transmission and reflection modes was employed to study CO adsorption on Pdn and Pdn^ag in both solidlliquid and solidlgas interfaces. It has been revealed that CO adsorption on Pdn film yields two IRbands near 1964 and 1906 cm-1, which are assigned to IR absorption of CO bonded on asymmetric and symmetric bridge sites, respectively. In contrast to the IR properties of CO adsorbed on Pdn, only species of CO bonded on asymmetric bridge sites was determined on Pdn^ag, and the direction of the IR band near 1963 cm^-1 is completely inverted. The full width at half-maximum (FWHM) of the COB^as band near 1964 cm^-1 is measured to be 14 cm^-1 on Pdn film, while it is 24 cm^-1 on Pdn^ag film. The results of the present study demonstrated that the inverting of the IR band direction is a general phenomenon that is closely related to the interaction between nanoparticles in aggregation of Pdn.