Recognition and sensing of anions through synergistic effects using simple benzimidazolium-urea receptors

Benzimidazolium-based receptors 1-3 were designed and synthesized. On the basis of fluorescence, UV-Vis, and 1H NMR spectroscopic studies, and X-ray single crystal structure analysis, it was confirmed that the receptor 1 displays strong (C-H)+···X, N-H···X hydrogen bonds and charge-charge interactions with anions. More importantly, these investigations demonstrated that the charged (C-H)+ benzimidazolium and urea moieties play a synergistic role in anion recognition.     

互通区跨线桥邻近路基墩柱偏移事故分析

结合工程实例分析了跨线桥墩柱偏移的原因,提出了偏移墩柱的处治措施.首先,通过现场实测揭示了邻近路基墩柱的变位性状,采用低应变动测评测了桥墩桩身损伤情况,并基于场区地基软土性状分析,指出邻近路基堆载是引起墩柱偏移的根本原因.然后,基于应变楔分析模型,提出了一种以桩顶位移为计算控制条件的桩身受力分析方法,并通过工程实例验证了该方法的合理性.最后,根据各桥墩支座偏位量情况,结合桩身受力验算与Bozozuk分析评价标准,对支座位移不大于50 mm的墩柱采用平衡堆载的处治方法;对支座位移大于50 mm的墩柱采用桩基顶推联合墩柱牵引的纠偏处治措施.结果表明,处治后墩柱支座偏移量分别降低了10.7%～43.7%和79.7%～100%,处治效果良好,对类似工程具有借鉴意义.     

Synthesis process of Ba-ferrites from α-FeOOH and γ-FeOOH and investigation of magnetic properties

The claviform BaFe₁₂O₁₉ crystals were synthesized by the precipitation-toptactic reaction method using α-FeOOH and γ-FeOOH as raw materials respectively. The synthesis processes of BaFe₁₂O₁₉, studied by XRD, SEM, EDS, FT-IR, and TG-DTA techniques, included preparations of precursor γ and precursor α, formations of α-Fe₂O₃ and BaFe₂O₄, and production of rod-like BaFe₁₂O₁₉ through dehydroxylation of pod-like FeOOH, followed by reactions of α-Fe₂O₃ with BaCO₃ and BaFe₂O₄. The crystallinity of α-Fe₂O₃ and BaCO₃ from precursor α was better than from precursor γ due to the direct dehydroxylation of α-FeOOH, resulting in a lower nucleation rate and better crystallinity of BaFe₂O₄. BaFe₁₂O₁₉ prepared from precursor α showed lower crystallinity and purity with a higher length-diameter ratio than from precursor γ. The VSM results proved that the appearance of final products had an important influence on magnetic properties.     

Radon-Nikodym theorem in signed Loeb space

This paper gives the Radon-Nikodym theorem in signed Loeb space under 1-saturated nonstandard model. First,the nonstandard characterization of absolute continuity is discussed,on which Radon-Nikodym theorem in signed Loeb space is obtained. Then,some facts about a finite signed Loeb measure and its variation are shown.     

Effect of intermittent aeration on the treatment performance in a submerged membrane bioreactor

In order to improve removal for nitrogen in a pilot-scale submerged membrane bioreactor (SMBR), intermittent aeration was conducted, and the effect on the treatment performance under four kinds of operation condition (run 1, continuous aeration; run 2, 60/60 min aeration on/off time; run 3, 60/90 min aeration on/off time; run 4, 60/75 min aeration on/off time) was evaluated. The results showed that depending on the specific on/off of the aeration time ratio, removal efficiency of nitrogen could be improved significantly, and the removal rates of total nitrogen (TN) under different operation conditions were 28.0%, 59.5%, 66.8% and 70.7%, respectively. There were no obvious differences for removal rates for COD_Cr and ammonia among different operation conditions. In general, intermittent aeration could be used as a feasible way to improve treatment performance for nitrogen in the SMBR.     

Vegetation effects on mean daily maximum and minimum surface air temperatures over China

Changes in the daily maximum (Tmax) and minimum (Tmin) surface air temperatures and the associated temperature extremes have severe consequences on human society and the natural environment. In this study, we assess vegetation effects on mean Tmax and Tmin over China by computing a vegetation feedback parameter using the satellite-sensed Normalized Difference Vegetation Index (NDVI) and observed temperatures for the period 1982–2002. In all seasons, vegetation exerts a much stronger forcing on Tmax than on Tmin, and thus has a substantial effect on the diurnal temperature range (DTR) over China. Significant positive feedbacks on Tmax and the DTR occupy many areas of China with the feedback parameters exceeding 1°C (0.1 NDVI)–1, while significant negative effects only appear over the summertime climatic and ecological transition zone of northern China and some other isolated areas. Also, the vegetation feedbacks are found to vary with season. In areas where significant feedbacks occur, vegetation contributes to typically 10%–30% of the total variances in Tmax, Tmin, and the DTR. These findings suggest that vegetation memory offers the potential for improving monthly-to-seasonal forecasting of Tmax and Tmin, and the associated temperature extremes over China. Meanwhile, the limitations and uncertainties of the study should be recognized.     

A security patch for a three-party key exchange protocol

The CLC protocol (proposed by Tzung-Her Chen, Wei-Bin Lee and Hsing-Bai Chen, CLC, for short) is a new three-party password-authenticated key exchange (3PAKE) protocol. This CLC protocol provides a superior round efficiency (only three rounds), and its resources required for computation are relatively few. However, we find that the leakage of values A _V and B _V in the CLC protocol will make a man-in-the-middle attack feasible in practice, where A _V and B _V are the authentication information chosen by the server for the participants A and B. In this paper, we describe our attack on the CLC protocol and further present a modified 3PAKE protocol, which is essentially an improved CLC protocol. Our protocol can resist attacks available, including man-in-the-middle attack we mount on the initial CLC protocol. Meanwhile, we allow that the participants choose their own passwords by themselves, thus avoiding the danger that the server is controlled in the initialization phase. Also, the computational cost of our protocol is lower than that of the CLC protocol.     

Dynamic domain decomposition method and its application on nonlinear problem

In this paper,domain decomposition method(DDM) for numerical solutions of mathematical physics equations is improved into dynamic domain decomposition method(DDDM) . The main feature of the DDDM is that the number,shape and volume of the sub-domains are all flexibly changeable during the iterations,so it suits well to be implemented on a reconfigurable parallel computing system. Convergence analysis of the DDDM is given,while an application approach to a weak nonlinear elliptic boundary value problem and a ...     

Regularization strategy for the Cauchy problem of Laplace’s equation from the viewpoint of regularization theory

Within the framework of the regularization theory, a spectral regularization method is introduced and analyzed. The convergence estimate under an appropriate choice of regularization parameter is obtained. A numerical implementation is described. Numerical examples show that the proposed method is effective and stable.     

Accurate localization and excision of genomic islands in four strains of <Emphasis Type="Italic">Pseudomonas aeruginosa</Emphasis> and <Emphasis Type="Italic">Pseudomonas fluorescens</Emphasis>

Mobile genomic islands (GIs) can be excised from the chromosome, then form a circular intermediate and be reintegrated into the chromosome by the GI internal integrase. Some mobile GIs can also be transferred into a new receptor cell by transformation, conjugation, or transduction. The action sites of the integrase are usually flanked direct repeats (DRs) of the GIs. Accurate localization of the flanking sequences is a precondition for determining the mobility of the GI. Mobile GIs are generally associated with transfer RNAs (tRNAs). Based on the correlation between flanking sequences and tRNA sequences, the flanking sequences of 11 putative mobile GIs in Pseudomonas aeruginosa PAO1, P. aeruginosa PA14, P. fluorescens Pf-5 and P. fluorescens Pf0-1 were identified. Among the 11 GIs, Pf0-1GI-1 is responsible for benzoate degradation. PAO1GI-1, Pf5GI-2, Pf5GI-3, and Pf5GI-4 were confirmed experimentally to be excised from a chromosome to form a circular intermediate. The action sites of the integrases are these GIs direct repeats. Due to distinct DRs, cutting sites for the internal integrase of PAO1GI-1, Pf5GI-2, Pf5GI-3 and Pf5GI-4 were determined outside the T-loop of the tRNA^Gly gene, outside the anticodon loop of the tRNA^Ser gene and tRNA^Lys gene, and at the asymmetric 3′-end of the tRNA^Leu gene, respectively. PAO1GI-1 and other mobile GIs may be transferred into many different strains that belong to different phyla because of the clear flanking sequences. This study describes basic information about the action sites of the integrases, assesses the mobility of GIs, and can help design and transfer mobile GIs to candidate strains.