The v-v energy transfer of highly vibrationally excited states (II)

The vibrational energy transfer from highly vibrationally excited CO to H₂O molecules is studied by time-resolved Fourier transform infrared emission spectroscopy (TR FTIR). Following the 193 nm laser photolysis of CHBr₃ and O₂ the secondary reactions generate CO(v). The infrared emission of CO(v → v−1) is detected by TR FTIR. The excitation of H₂O molecules is not observed. By the method of the spectral simulation and the differential technique, 8 rate constants for CO(v)/H₂O system are obtained: (1.7 ±0.1), (3.4 ±0.2), (6.2 ±0.4), (8.0 ±1.0), (9.0 ±2.0), (12 ±3), (16 ±4) and (18 ±7) (10¹³cm³ · molecule^-1· s^-1). At least two reasons lead to the efficient energy transfer. One is the contributions of the rotational energy to the vibational energy defect and the other is the result of the complex collision. With the SSH andab initio calculations, the quenching mechanism of CO(v) by H₂O is suggested.     

Shear-wave splitting and anisotropy in crust of Dabieshan orogenic belt

The shear-wave splitting was analyzed on the deep seismic sounding profile crossing the Dabieshan area. The direction difference between Sg and SmS fast wave polarization indicates that the modem regional tectonic stress field in the Dabieshan area exists only in uppcr crust, while the crack alignment caused by the Triassic collision between the North China and the Yangtze blocks had been preserved in mid-lower curst.     

Identification and classification of subspecies of Asian cultivated rice and their hybrids

Having reviewed the major classification systems proposed by various scholars across the world, it is found thatindica andjaponica underO. sativa L. are two major directions thoroughly differentiated from the Asian cultivated rice, forming the framework of the classification structure. A system withindica andjaponica as the only two subspecies is therefore reiterated. There are various ways to determine the indica-japonica identity of hybrid rice, but the “combined morphological trait index” (CMT index) method is more efficient and easier to handle, although the isozyme analysis, molecular marker analysis and grain quality assay methods are also feasible.     

单向耦合映象格子的时空混沌同步

用主动－被动分拆方法实现了单向耦合映象格子系统的时空混沌同步,从理论上给出步范围,并从数值实验上得到验证。该法具有高度保密性,且信号可以完全恢复,特别适用于混沌保密通讯 。     

用^1H—NMR测定纤维素的摩尔取代度

用＾１Ｈ－ＮＭＲ测定羟丙基纤维素的摩尔取代度,根据纤维素在ＤＣｌ中水解后的＾１Ｈ－ＮＭＲ谱峰面积来计算ＭＳ值。同时还应用铬酸氧化蒸馏法测定了羟丙基纤维素的ＭＳ值,以及利用ＭＳ与羟丙基含量的关系得到ＭＳ值,可以发现ＮＭＲ的方法是可行的。     

氧化铝超细粉体的表面吸附改性

本文选用十二烷基苯磺酸钠（SDBS）,氯化十四烷基吡啶为改性剂,探讨其在Al2O3／H2O的固液界面上的吸附等温线,同时测定了Zeta电位与粒子平均孔径讨论其吸附机理;为考察改性效果测定了样品的红外光谱、粉末接触角、悬浮体的稳定性,粒子平均大小等物化性质．     

激光照射对金鱼受精卵生物效应的研究

本文采用He－Ne632．8um激光照射金鱼受精卵,实验结果表明不同剂量的激光照射对金鱼的受精率、孵化时间和孵化率等的影响是不同的,存在一个最佳照射剂量,在此剂量下各生物性能指标均有较大的提高．跟踪观察发现经激光照射而孵化出的金鱼有较大的变异。     

非线性机电系统数学建模的联结方法

由于传统建模方法缺乏通用性,发展通用建模方法已成为必要．在总结了传统的机电系统数学建模优缺点、引入位移联结、速度联结和加速度联结概念的基础上,提出了适用于非线性机电系统数学建模的通用方法——联结方法．将联结理论从线性系统拓宽于非线性系统,拓展了联结理论．将联结方法与传统的拉格朗日法进行对比,说明了联结方法可避免建模过程中严重偏微分运算的优越性,并从理论上证明了研究结果的可靠性．     

1673K下BaO-BaF_2-Cr_2O_3渣系的热力学性质

１６７３Ｋ下,采用－ＭｏＣｒ＋Ｃｒ２Ｏ３ＺｒＯ２（ＭｇＯ）｛Ｃｕ＋Ｃｒ｝ａｌｏｙ＋（Ｃｒ２Ｏ３）ｓｌａｇＭｏ＋固体电解质电池测定了ＢａＯＢａＦ２Ｃｒ２Ｏ３渣系中Ｃｒ２Ｏ３的活度．研究结果表明,Ｃｒ２Ｏ３的活度随其浓度升高而升高,随ＸＢａＯ／ＸＢａＦ２升高而降低．根据实验及Ｘ射线衍射结果推测了该渣系的等温相图,并作出了该渣系中Ｃｒ２Ｏ３的等活度图．