WO3 nanoflakes decorated with CuO clusters for enhanced photoelectrochemical water splitting

The low quantum efficiency arising from poor charges transfer and insufficient light absorption is one of the critical challenges toward achieving highly efficient water splitting in photoelectrochemical cells. Three dimensions(3D) structures and heterojunctions have received intensive research interests recent years due to their excellent ability to separate photo-generated charges as well as the enhanced light harvesting property. Herein,3 D Cu O/WO_3 structure was fabricated through a facile solvothermal method followed by chemical bath deposition. The loading of Cu O clusters on WO_3 nanoflake arrays results in a much improved photocurrent density compared with that of pristine WO_3 nanoflake arrays, which reaches 1.8 m A/cm2 at 1.23 V vs. the reversible hydrogen electrode. The electrochemical impedance spectroscopy measurement demonstrates that the improved performance of Cu O/WO_3 electrode is attributed to the accelerated charge transfer kinetics as a result of the desirable band alignment in Cu O/WO_3 heterojunction. This work demonstrates a facile strategy to construct superior WO_3 electrode, which will ultimately allow for efficient storage of solar energy into hydrogen.     

偶氮样品折射率变化的测量与计算

测量了偶氮染料甲基红掺杂PMM A薄膜的反射光谱,并对测量结果进行了修正.利用修正后的反射光谱进行了k-k变换,获得了样品的折射率分布.对样品进行了不同状态下吸收光谱的测量,利用k-k变换获得了样品在不同状态下折射率的变化分布.     

关于距离图着色问题一个结果的新证明

利用数论的方法,重新确定了距离图G（Z,D）的圆色数Xc（D）和分式色数Xf（D）,其中D={a,b,a＋b,2（a＋b）}是一个特殊的四元素距离集．     

Error analysis and distribution of the driving mechanism for large spherical radio telescope active reflector

In order to reduce the cost, 3-PRS mechanism is introduced into the application of supporting the active reflector unit of large radio telescope. The kinematic model of 3-PRS mechanism with rotational joint errors is derived to solve the error problem in actual engineering application. Then based on the error model, inverse and forward kinematics are analyzed. Because the solutions can not be analytically expressed, a numerical method is applied. Afterwards, the parasitic motion errors are analyzed using search method and empirical formulas of the maximum parasitic motion error are put forward. Finally, the tolerance is distributed using empirical formulas to avoid interference between adjacent reflector units. The analyses provide a theoretical basis for the design and installation of large radio telescope active reflector.     

基于视频编码流的视频传输端到端失真度估算

研究了基于信源量化、信道错误和差错隐藏的视频传输端到端失真问题.提出了一种基于视频编码流结构的端到端失真度估算方法.采用帧间递归,以宏块为单位根据信道平均误比特率和视频编码信息在编码器端实时估算端到端失真.仿真结果表明,对于绝大部分视频测试序列,在不同信道误比特率下,该方法模型估算的平均相对偏差小于8%,平均绝对偏差控制在0.9 dB以内,准确度高,为基于率失真或联合功率率失真优化中的失真估算提供一个有力的工具.     

沥青路面常见问题分析及处理

文章分析了沥青路面的常见问题,以提出相应的处理措施.     

Interlayer engineering of molybdenum disulfide toward efficient electrocatalytic hydrogenation

Electrocatalytic hydrogenation (ECH) enables the sustainable production of chemicals under ambient condition;however,suffers from serious competition with hydro...     

颗粒增强聚合物复合材料损伤模型

研究了颗粒增强聚合物复合材料的力学行为,研究得知:材料屈服、裂纹形核、扩展与贯通直至最终断裂是一逐渐劣化过程,而损伤理论正是这一劣化过程的良好描述.通过假设自由能和耗散势函数,导出了损伤演化规律,与实验比较,模型和试验结果基本符合.进一步采用改进的Dugdale模型,重点研究损伤对GB/PPO复合材料宏观裂纹起裂的影响,通过建立损伤模型来描述材料的劣化行为和裂纹扩展,结果表明,损伤区域严重影响裂尖的性能,材料损伤对宏观裂纹起裂影响不可忽略.     

茁霉多糖发酵工艺条件研究

以出芽短梗霉为生产菌株，蔗糖为碳源进行发酵生产茁霉多糖．通过摇瓶实验，确定了该菌株的发酵条件，并对发酵条件进行了优化，在此条件下，获得了较高的多糖产量．实验表明，摇瓶转速和发酵初始pH值是多糖发酵的重要影响因素，它们与多糖的合成密切相关．     

高层短肢剪力墙结构变形能力分析优化

短肢剪力墙结构以剪力墙为基础,并吸取框架的优点,已广泛应用于工程实践中.应用ANSYS软件对高层T形短肢剪力墙结构的变形能力进行了仿真试验,分析了楼层层数、连梁跨高比、墙肢截面高厚比和轴压比等因素对变形能力的影响,并对结果进行了分析优化,为工程中的T形短肢剪力墙结构设计提供理论和试验依据.