纳米TIO2光催化剂的制备及降解活性红研究

采用溶胶-凝胶法,以钛酸四丁酯为前驱体合成TIO2溶胶,在不同温度下焙烧得到三种不同晶粒大小的纳米TIO2光催化剂。采用X射线衍射和电子扫描电镜（SEM）对样品的结构和形貌进行表征,考察了不同焙烧温度对TIO2纳米粒子粒径的影响。在500W汞灯照射下对活性红进行紫外光催化降解实验,考察了不同光照时间和焙烧温度对活性红催化降解活性的影响。结果表明,550℃焙烧温度下所得的TIO2光催化剂在紫外光照射下对活性红降解效果最好,30min光照后降解率可达97.9%。     

非饱和绢云母片岩残积土动力特性试验分析

以广泛分布于大临铁路沿线的绢云母片岩残积土为研究对象,开展非饱和状态下绢云母片岩残积土的共振柱试验,研究了动剪应变γd在小应变范围内(10-6<γd<10-4)不同含水率、干密度及固结围压对动剪切模量Gd与阻尼比D的影响.试验结果表明,含水率对动剪切模量与阻尼比的影响较大,对干密度及固结围压的影响较小.Gd及D随含水率...     

利用顶点预测方法实现三维网格的保形简化

针对产品的三维表面用三角网格来表示时,三角形数量巨大的问题,提出了一种基于顶点预测的三角形折叠简化方法。首先根据网格模型的每一个顶点与其周边元素之间的几何拓扑关系,运用投影预测方法来预测三角形折叠的折叠点坐标,然后运用线性插值算子对折叠点坐标进行调整。为进一步保证简化后模型的质量,在采用距离误差控制的同时,引入了角度误差控制方法。实验结果表明,该简化算法在减少模型的三角形数量的同时,有效地保持模型特征,保证了模型表面的光顺。     

Synthesis and characterization of bifunctional terbium complex-based nanoparticles

Novel bifunctional terbium complex-based nanoparticles were developed using a modified Stber method and a layer-by-layer assembly process. A magnetic core of Fe3O4 nanoparticles was coated with a silica shell to form the first layer. Then a ternary Tb3+ complex (TESPPA-Tb), which acted as a luminescent marker, was covalently bound to the silica surface by stable Si-O-Si bonds. The TESPPA monomer was synthesized by binding pyridine 2,6-dicarboxylic acid to 3-aminopropyltriethoxysilane, which was used as a ligand for coordination with the Tb3+ ions. An outer shell of silica was applied to the nanoparticles to allow for versatility with surface functionalization. The nanoparticles were characterized by X-ray powder diffraction, transmission electron microscopy, Fourier transform infrared spectroscopy, ultravioletvisible spectroscopy, vibration sample magnetometer, and photoluminescence spectroscopy. The bifunctional nanoparticles exhibited favorable superparamagnetic behavior and photoluminescence properties of Tb3+. These nanoparticles have potential applications in biolabeling, bioseparation, immunoassays, and pathogenic diagnosis.     

Redox modulated hydrogelation of a self-assembling short peptide amphiphile

Hydrogels resulting from the self-assembly of small peptides are smart nanobiomaterials as their nanostructuring can be readily tuned by environmental stimuli such as pH,ionic strength and temperature,thereby favoring their practical applications.This work reports experimental observations of formation of peptide hydrogels in response to the redox environment.Ac-I 3 K-NH 2 is a short peptide amphiphile that readily self-assembles into long nanofibers and its gel formation occurs at concentrations of about 10 mmol/L.Introduction of a Cys residue into the hydrophilic region leads to a new molecule,Ac-I 3 CGK-NH 2,that enables the formation of disulfide bonds between self-assembled nanofibers,thus favoring cross-linking and promoting hydrogel formation.Under oxidative environment,Ac-I 3 CGK-NH 2 formed hydrogels at much lower concentrations(even at 0.5 mmol/L).Furthermore,the strength of the hydrogels could be easily tuned by switching between oxidative and reductive conditions and time.However,AFM,TEM,and CD measurements revealed little morphological and structural changes at molecular and nano dimensions,showing no apparent influence arising from the disulfide bond formation.     

Spatial prisoner’s dilemma games with increasing size of the interaction neighborhood on regular lattices

We studied the evolution of cooperation in the prisoner’s dilemma game on a square lattice where the size of the interaction neighborhood is considered. Firstly, the effects of noise and the cost-to-benefit ratio on the maintenance of cooperation were investigated. The results indicate that the cooperation frequency depends on the noise and cost-to-benefit ratio: cooperation reaches a climax as noise increases, but it monotonously decreases and even vanishes with the ratio increasing. Furthermore, we investigated how the size of the interaction neighborhood affects the emergence of cooperation in detail. Our study demonstrates that cooperation is remarkably enhanced by an increase in the size of the interaction neighborhood. However, cooperation died out when the size of the interaction neighborhood became too large since the system was similar to the mean-field system. On this basis, a cluster-forming mechanism acting among cooperators was also explored, and it showed that the moderate range of the neighborhood size is beneficial for forming larger cooperative clusters. Finally, large-scale Monte Carlo simulations were carried out to visualize and interpret these phenomena explicitly.     

黑社会组织形成及其社会控制方式——基于成本-效益的“袍哥文化”分析

“袍哥文化”是我国长江中上游地区特有的社会文化,其初期组织形式以反清复明的民间组织为主．但由于人们对其文化内涵认识产生偏差以及对利益的盲目追求,导致“袍哥文化”下形成危害社会的黑社会组织。本文从文化视角分析“袍哥文化”对黑社会组织形成的作用,并建立成本一效益经济模型,探讨其社会控制方式。     

斜Hurwitz级数环的PP性质

研究了斜Hurwitz级数环的PP性质,证明了当R是σ-刚性环,且R关于加法做成的群是挠自由群时,R上的斜Hurwitz级数环是PP-环当且仅当R是PP-环,且R的每个由幂等元组成的可数集在R的全体幂等元组成的集合B(R)中有上确界.还证明了若R是交换的σ-刚性环,且R关于加法做成的群是挠自由群时,R上的斜Hurwitz级数环是弱PP-环当且仅当R是弱PP-环.     

一个自选子密钥的可验证理性多秘密共享方案

给出在适当模型下的一个自选子密钥的可验证理性多秘密共享方案.     

基于随机矩阵理论和改进粒子群优化-深度置信网络的无功优化

配电网无功优化是使电网能安全稳定运行的重要问题,本文将深度学习应用于配电网无功优化上,提出基于改进的粒子群优化 (Particle swarm optimization, PSO)深度置信网络（Deep Belief Networks,DBN）模型的配电网无功优化方法。首先,利用随机矩阵理论将配电网运行过程中产生的环境以及电气数据构造五种随机矩阵,每种矩阵构建8种特征指标,共提取40种特征指标;其次,以随机矩阵理论所提取的各特征指标为输入,以变压器分接头档位和节点的无功补偿容量作为输出,利用改进的PSO优化DBN网络的初始权重,建立PSO-DBN模型,学习各特征指标输入与变压器分接头档位以及节点无功补偿这两种控制策略之间的关系,得出相应的无功优化策略。最后,以改进的IEEE33节点系统作为算例仿真对象,验证了所提方法可降低网损和减少电压波动。