The strong cooperativity of dioxygen binding by dicobalt (II) diporphyrin compounds in nonaqueous solution at room temperature

Thermodynamic data were determined for the reversible binding of O₂ to two compounds of dicobalt(II) di(meso-tetra-phenyl)porphyrin derivatives with different lengths of diamidoaliphatic bridge (abbreviated to Co₂PP₈ and Co₂PP₄) in N,N-dimethylformamide at room temperature. The partial pressure of dioxygen necessary for half-oxygenation (P _1/2) and hill coefficient (n) at 298 K were determined as follows:P _1/2=54.2 kPa,n=2.0 for Co₂PP₈ andP _1/2=6.8 kPa,n=1.8 for Co₂PP₄, respectively. The rate equations of reversible oxygen binding by Co₂PP₈ were determined and the reaction path was proposed. The results of ther-modynamic and kinetic studies indicate that there exists strong cooperative effect during oxygenation of the compounds. The ESR observation reveals that the dioxygen complexes formed in the solutions are of superoxo (Co-O ₂ ⁻ ) type. Supported by the Research Foundation of the State Education Commission of China Zhou Xiaohai: born in 1962, Ph.D. Associate professor     

Studies on the reaction between Laccase ando-methoxyphenol by microcalorimetry

The reaction between Laccase ando-methoxyphenol have been studied by LKB-2107 batch microcalorimetry system. Thermodynamic parameters Δ _r H _m , ΔG _o , ΔG _T ^≠ and kinetic parameters (K _m ,k ₂) have been determined. The process of the reaction has been analyzed from changes in energy by using the transition state theory. Two methods for enhancing catalytic power of Laccase are proposed. The results shown that formation of an enzyme-substrate complex is “anticatalytic”. The enter and sole source of catalytic power is the stabilization of transition state; reactant-state interactions are by nature inhibitory and only waste catalytic power. Supported by the National Natural Science Foundation of China Wang Tianzhi: born in 1968. Ph D     

全层片组织 TiAl 基合金室温断裂机理的研究

在ＳＥＭ和ＴＥＭ下对Ｔｉ３３Ａｌ３Ｃｒ０．５Ｍｏ合金全层片组织薄板状和薄膜状试样分别进行了动态拉伸，并原位观察了试样中裂纹的形核及扩展过程．发现裂纹遇到内相界面时会发生偏转或裂尖发生钝化；主裂纹主要以使剪切带断裂而与微裂纹相连接的方式扩展并沿曲折路径进行．     

一种ARROW型弯曲波导研究

分别用射线分析法和电磁场分析法，通过保角变换在直角坐标系下研究ＡＲＲＯＷ型弯曲波导特性，导出了其模色散方程（本征模方程）。经优化设计的ＡＲＲＯＷ型弯曲波导结构，使ＴＥ０模的损耗降至为０．０３２９ｃｍ＾－１。     

总线式楼宇安全管理系统的研究

根据国内现有公寓及住宅楼宇的管理系统和安全系统的状况，给出一种总线式楼宇安全管理系统的结构、原理，并总结了实际应用中的特点。     

基于行为建模的机器人混合模糊-神经控制方法

本文提出了一种设计机器人模糊－神经控制器的新方法。因为模糊逻辑控制器的控制信号是由系统的响应行为而不是由其分析模型决定的，所以机器人的开环响应可以用一系列二阶系统来描述。然后，用Ｎｅｌｄｅｒ－Ｍｅａｄ单纯形算法离线优化与该系统相关的模糊逻辑控制器的参数，并用人工神经网络来训练开环响应与这些优化了的参数之间的匹配关系。该方法的优点在于当它用于设计模糊－神经控制器时，在自适应过程中不必考虑收敛问题     

RESEARCH ON THE STRUCTURE AND THE PROPERTY OF THE HYGROSCOPIC AND PERMEABLE FABRIC FOR SPORTSWEAR

Two structure models for knitting fabric are set up according to the wet-heat transmission principle of the fabric. Four kinds of knitted fabrics for sportswear are designed and produced. The wet-heat property of these fabrics is researched.     

桩基动态检测分析

提出的桩基动态检测方法可以诊断混凝土灌注桩的桩身质量.判断桩基混凝土的强度和桩长,根据应力波在传播途中遇到阻抗面时会产生反射波与透射波的原理,诊断桩基缺陷的类型,并用相关分析法确定了单桩允许承载力.     

银行资产负债比例管理监控模型及评价

通过对我国中央银行规定的资产负债比例指标建立数学模型，为监控商业银行比例管理实施效果提供了一种科学的综合评价方法     

一致凸线性距离空间的最佳联合逼近性

本文证明了一致凸线性距离空间存在唯一的最佳联合逼近元。