基于树状分子及炭黑复合纳米材料修饰电极的Cr(VI)电化学检测

用树状分子及炭黑纳米复合材料修饰玻碳电极,并对六价铬Cr(VI)进行电化学测定.采用X射线光电子能谱(XPS)、循环伏安法(CV)、交流阻抗法(EIS)、方波溶出伏安法(SWSV)等方法对修饰电极进行了表征.研究发现多种其他离子如Ni~(2+)、Co~(2+)、Pb~(2+)、Cu~(2+)、Cd~(2+)、NO_3~-、SO_4~(2-)、Cl~-等对六价铬离子的测定没有明显干扰,且Cr(VI)的还原峰电流与Cr(VI)的物质的量浓度在4~60 nmol/L和0.06~500μmol/L范围内呈线性关系,检测限达1 nmol/L.该法具有简便快速,选择性好,线性范围宽,灵敏度高等优点.     

Cobalt doped titanate nanotubes: Synthesis and properties

Cobalt oxide doped titanate nanotubes are synthesized with a simple hydrothermal treatment of mixed Co_3O_4 and TiO_2 powders. The formed tubular nanostructure, chemical composition,and the elemental distribution are analyzed using TEM, BET, FTIR, XRD, and XPS. The electrocatalytic activity towards oxygen evolution reactions and photodegradation against Rhodamine B are investigated. It has been found out that the oxygen evolutions starts at 0.8 V and reaches 0.98 mA ·cm~(–1) at 1.4 V vs. SCE. For photodegradation of Rhodamine B, the concentration decreased to 24% after 1 h irradiation using the sample with a mass percentage of 5% cobalt. The results demonstrate that the cobalt oxide doped titanate nanotubes are good candidates as electrocatalysts and photocatalytic materials.     

从《论语》看孔子的孝道观及其当代意义

在中国人传统孝道观的形成过程中,孔子在《论语》中对"孝"的阐释起到了重要的推动作用。随着时代的变迁与社会的发展,孔子的孝道观在某些方面逐步显示其历史局限性和一些消极影响,但有关养亲、敬亲、安亲、顺亲、谏亲、葬亲、继亲、悌亲和孝治的一些孝道观在现代社会仍有其积极意义和影响。     

面向无人自主平台的战场地理环境模型研究

战场环境模型是复杂战场环境面向特定需求的抽象和描述,用以支撑战场环境特性和演变规律的研究和应用。现有的战场环境模型主要面向人类战争活动来描述战场环境,缺乏以无人自主平台为认知主体的设计。提出了一种耦合人机各自优势的多层次战场地理环境模型结构,充分发挥机器在特征层面的快速计算能力,以及人在要素和关系层面的认知经验。提出了一种集环境观测、模型构建和空间决策为一体的建模方法,支撑无人自主平台根据任务和环境实现自主空间决策。     

实现船舶稳性的多油舱自适应调度算法及仿真

针对油舱对船舶浮态与稳性的影响，研究了保持船舶稳性的多油舱自适应调度控制算法，并用WinCC (Windows Control Center)组态软件编写了船舶自动浮态调整仿真系统。在系统架构上，采用布尔逻辑表构建了油舱、泵、管路之间的连通关系，并根据浮态方程计算出舱群之间的调驳油量，再根据多变量多约束的自适应优化调度算法实现了油舱驳油过程中浮态的平衡。仿真结果表明调度算法可以对船舶的浮态进行有效调整，并保持船舶稳性，避免了由油舱油量分布不均给船舶带来的不利影响，保障了航行安全。     

C3N4/ZnO复合材料可见光下的甲醛光电气敏性能

以水热法合成的ZnO纳米棒花为载体,将C_3N_4定量负载在其表面,制备C_3N_4/ZnO复合材料.由于C_3N_4与ZnO的能级匹配,可有效促进其光生电荷的分离,降低光生电荷复合率,显著提高载流子浓度,使其光电流明显增加.C_3N_4与ZnO质量比为2%的样品(2%C_3N_4/ZnO)性能最佳,其光电流在370 nm处可达120μA,为纯ZnO的2.4倍.在室温可见光下,2%C_3N_4/ZnO样品对HCHO的光电气敏响应值可达122%,比纯ZnO高4倍左右.结果表明,适量C_3N_4的负载有效延长了光生电荷的寿命,使ZnO材料在可见光区对HCHO气体表现出高效的光电气敏性能.     

基于动态阈值的混凝土裂缝高抗噪提取及识别方法

针对表面布有蜂窝麻面等复杂噪声的混凝土裂缝,提出了一种基于动态阈值的混凝土裂缝高抗噪提取方法.首先,通过灰度变换、高斯滤波、信息增强等技术弱化、去除噪声,增强图像中裂缝的亮度,提高裂缝与背景的对比度;然后,采用OTSU阈值分割算法去除伪裂缝,基于裂缝与干扰噪声面积的差异,引入动态阈值,实现各类型裂缝的提取;最后,基于边缘检测和裂缝骨架细化处理,计算裂缝的长度、宽度和面积3项特征参数.基于室内实验和室外实际桥梁拍摄的4组裂缝图像结果表明,4组裂缝的平均宽度分别为2.01、1.07、1.34、0.97 mm,说明该方法适用于不同背景下各类型裂缝的提取,具有较强的鲁棒性.     

Effect of Zn addition on microstructure and mechanical properties of an Al–Mg–Si alloy

In the present work, an Al–0.66Mg–0.85Si–0.2Cu alloy with Zn addition was investigated by electron back scattering diffraction(EBSD), high resolution electron microscopy(HREM), tensile and Erichsen tests. The mechanical properties of the alloy after pre-aging met the standards of sheet forming. After paint baking, the yield strength of the alloy was improved apparently. GP(Ⅱ) zones and η’phases were formed during aging process due to Zn addition. With the precipitation of GP zones, β″ phases, GP(Ⅱ) zones and η’phases, the alloys displayed excellent mechanical properties.     

Effect of Graphene Nanoplatelets addition on mechanical properties of pure aluminum using a semi-powder method

In recent years, graphene has attracted considerable research interest in all fields of science due to its unique properties. Its excellent mechanical properties lead it to be used in nano-composites for strength enhancement. This paper reports an Aluminum–Graphene Nanoplatelets(Al/GNPs)composite using a semi-powder method followed by hot extrusion. The effect of GNP nano-particle integration on tensile, compressive and hardness response of Al is investigated in this paper. It is demonstrated that 0.3 wt% Graphene Nanoplatelets distributed homogeneously in the matrix aluminum act as an effective reinforcing filler to prevent deformation. Compared to monolithic aluminum(in tension), Al–0.3 wt% GNPs composite exhibited higher 0.2% yield strength(+14.7%), ultimate tensile strength(+11.1%) and lower failure strain( -40.6%). Surprisingly, compared to monolithic Al(in compression), Al–0.3 wt% GNPs composite exhibited same 0.2% compressive yield strength and lower ultimate compression strength(- 7.8%),and lower failure strain(- 20.2%). The Al–0.3 wt% GNPs composite exhibited higher Vickers hardness compared to monolithic aluminum(+11.8%).Scanning electron microscopy(SEM), Energy-Dispersive X-ray Spectroscopy(EDS) and X-ray diffraction(XRD) were used to investigate the surface morphology, elemental percentage composition, and phase analysis, respectively.     

基于供应链业务流程改造的模块化设计

首先通过对A公司供应链业务流程现状进行分析,发现存在的问题,然后从模块化的角度对业务流程进行改造,并进一步对改造后的业务流程所涉及的4个模块进行了设计.所提出的供应链模块化设计,可将复杂流程简单化,使供应链管理更加明确、清晰,对于提高供应链的运作效率,缩短对需求响应时间具有重要作用.