STUDIES ON THE COMPATIBILITY OF PPO MULTI-COMPONENT BLENDS

The compatibility and phase morphology of poly (phenylcne oxide) (PPO) multi-componenet blends with poly (ethylene terephthalate) (PET) and polystyrene (PS) were studied using differentialscanning calorimetry (DSC), dynamic mechanical analysis (DMA) and scanning electron microsopy (SEM) methods. The effect of glycidyl methacrylate-styrene copolymer (GMS), as a compatibilizer, on the morphology of the PPO blends has also been studied in detail. The influence of the moiecular weight of PET and the synergetic effect of the compatibilizers of GMS and phenoxy on the morphology were examined. The DSC and DMA results show that there are two distinct glass transitions correspondinig to PET and PPO existed, however, the Tg of PPO shifts toward lower temperature region due to the addition of GMS and PS. The SEM results reveal that PET component is as dispersed phases in the PPO matrix, part of which is located at the interfaces due to the interaction with GMS while PS is miscible in the PPO matrix. A significant     

配位体亲核竞争取代反应分光光度法的条件选择

对配位体亲核竞争取代反应分光光度法的光谱特征、波长选择、配合物竞争能力和金属离子水解问题进行了较为详细的讨论。该方法通过已知稳定常数的配合物作为指示配合物，由体系光密度和ＰＨ值的变化，可直线外推求解配合物的逐级稳定常数和摩尔消光系数。     

解读会计利润与经济利润

会计利润和经济利润都是以数量来表达,但会计利润主要是从量的方面反映企业经济,而经济利润则从质的方面反映企业经济.文章以会计利润与经济利润的比较分析,增加对经济利润的认识.     

基于XML文档的PIM模型与PSM模型转换研究

MDA的核心特点之一就是模型转换的自动化.目前,MDA仍处于发展阶段,有许多问题需要完善,PIM到PSM的自动转换是急需解决的问题之一.笔者的主要工作如下:首先提出使用UML和OCL结合建模,使得模型更加精确,然后介绍了对建立的可视化概念模型的XML存储,提出了一种基于XML的PIM模型到PSM模型的转换规则,并提出用...     

一类功能反应与脉冲效应的捕食-食饵系统的分析

对一类具有周期脉冲效应与功能反应函数为p(x)=(√x3)的捕食-食饵系统进行了研究,根据脉冲微分方程的比较定理与Floquet乘子理论,给出了食饵根除的周期解全局稳定与系统持续生存的充分条件.最后给出了系统的数值模拟,验证了理论的正确性.     

焦化氨水介质中0Cr17Ni12Mo2不锈钢电化学腐蚀行为研究

采用全浸动态挂片和极化曲线实验法研究0Cr17Ni12Mo2不锈钢在模拟现场工况条件下的腐蚀行为。结果表明,0Cr17Ni12Mo2试样的腐蚀速率随温度的升高不断加快;增大硫离子和氯离子浓度可使0Cr17Ni12Mo2试样腐蚀速率加快;氰根离子浓度不高于临界值时,试样腐蚀速率减缓,反之,腐蚀速率加快。     

基于模糊PID控制策略的ESP控制系统仿真

采用"魔术公式",建立了轮胎的纵向力和侧向力的数学模型,完整地表达了纯工况下轮胎的力学特性,研究了7自由度整车模型ESP控制系统,运用Matlab/Simulink软件建立了包括发动机、制动器、轮胎和车身等子模型的整车动力学模型,设计了模糊PID控制系统的算法和结构,进行了ISO 3888紧急双移线等极限工况下的整车操...     

土壤、岩样、水泥和煤的多孔介质结构特征研究进展

多孔介质结构特征是研究多孔介质流动、传热、传质和化学反应的基础。首先介绍了主要的多孔介质的结构特征及其理论实验研究方法,对比了其优缺点。其次,对目前文献获得的土壤、岩样、水泥和煤的主要结构特征参数进行了分类归纳。最后,对目前多孔介质结构的分形研究成果进行了综述,对各种分维数进行了分析和整理。可以看出,目前对多孔介质结构研究还只是针对某个学科的某种或某类多孔介质,而且集中在很少的几个结构特征参数,系统研究很少,难以从整体上把握多孔介质的共性特征和差异性规律。     

Formation mechanism of interfacial microstructures and mechanical properties of Ti2AlNb/Ni-based superalloy joints brazed with NiCrFeSiB filler metal

Dissimilar brazing of Ti₂AlNb-based alloy and Ni-based wrought superalloy (GH536) was studied using NiCrFeSiB filler metal. The Ti₂AlNb/GH536 joints were analyzed by scanning electron microscope (SEM) equipped with an electron probe micro-analyzer (EPMA), X-ray diffraction (XRD) and transmission electron microscopy (TEM). The formation mechanism of interfacial microstructure and mechanical properties of Ti₂AlNb/GH536 joints were studied. The results indicated that Ti₂Ni(Al,Nb), AlNi₂Ti and TiB₂ reaction layers were formed in the joint adjacent to Ti₂AlNb base metal. These layers resulted in high micro-hardness and the weak link of the joint. γ solid solution was formed through isothermal solidification and β₁-Ni₃Si phase precipitated in the γ solid solution during cooling process. Ni₃B, β₁-Ni₃Si and CrB phases appeared in the centre of the joint. Blocky and needle-like borides formed within the diffusion affected zone of GH536 base alloy. The maximum tensile strength of Ti₂AlNb/GH536 joints reached 425 ?MPa ?at room temperature and the strength value of 373 ?MPa was maintained at 923 ?K.