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811.
812.
合成了新型配体N-异丙基-2-苯基苯并咪唑(bi)和N-异丙基-2-(4-氟苯基)苯并咪唑(fbi),并用它们与三氯化铱和乙酰丙酮反应,制备了相应的环金属铱(Ⅲ)配合物发光材料(bi)2Ir(acac)和(fbi)2lr(acac)(acac=乙酰丙酮).对其结构用1H NMR和元素分析方法进行了表征,研究了配合物的UV-vis,荧光光谱及电化学性质.两种材料的最大发光波长分别位于514 nm和493nm.电化学研究表明,在苯环上引入氟原子后,配合物的HOMO和LUMO间能隙增大(分别为O.12 eV和0.15 eV),与最大发光波长蓝移结果吻合. 相似文献
813.
Jing Xu Hao Wang Tao Liang XiangSheng Cai XiuRong Rao ZhenBo Huang GuoQing Sheng 《科学通报(英文版)》2011,56(23):2520-2520
The authors report that incorrect figures were included as Figures 4 and 5 in the original publication of this paper. This error occurred during the figure editing process of the publishing company. This information should have been presented as follows: 相似文献
814.
DNA damage response (DDR) is among the most important of the mechanisms that maintain genome stability which, when destabilized, predisposes organs to cancer. Reversible phosphorylation mediated by protein kinases and protein phosphatases regulates most, if not all, cellular activities, including DDR. Protein kinase inhibitors have become the main focus of targeted therapy and anticancer drug development. However, our limited knowledge of protein phosphatase function is compromising our capacity to develop therapeutic agents against phosphatases. In this review, we summarize the roles of serine/threonine protein phosphatases involved in DDR and propose that in situ dephosphorylation of phosphoproteins by protein phosphatases, instead of proteasome-mediated degradation of phosphoproteins, is mainly employed by cells. 相似文献
815.
A collimated light beam will be refracted if it propagates through a flow-field with index-of-refraction variations,and its wavefront will be distorted.If we measure the deflection angle of the light beam,the gradient of the wavefront can be obtained using the Malus law,and the wavefront aberration can be computed with a reconstruction algorithm.Two characteristics of background oriented schlieren(BOS) are conducive to wavefront aberration measurement:BOS can be used to measure the deflection angle of a light beam by measuring the displacement field between the reference image and the experiment image.Moreover,in a BOS system of Schlieren mode,only the ray perpendicular to the background image can be captured with a camera.This is helpful to measure wavefront aberrations that occur after a planar wavefront has passed through the flow-field.Based on these characteristics of BOS of Schlieren mode,a new wavefront measurement technique,which is called the BOS-based wavefront technique(BOS-WT),is proposed in this paper.It works by constructing the relationship between the displacement of the background image and the aero-optical wavefront gradient and uses the Southwell wavefront reconstruction algorithm.A BOS-WT system was assembled,and its temporal resolution was found to be 6 ns,and its temporal-correlation resolution reached 0.2 μs.A BOS-WT can measure the time-correlation transient wavefront quantitatively.It is simple and easy to operate.In this paper,we also present a study of the aero-optical performance of supersonic mixing layer based on our BOS-WT transient wavefronts at an interval of 5 μs.The results showed the wavefront was transient and distorted after it had passed through the mixing layer.Through the analysis of the data at the 5 μs interval,the temporal evolution of wavefront can be obtained. 相似文献
816.
The flame-holding mechanism in hypersonic propulsion technology is the most important factor in prolonging the duration time of hypersonic vehicles.The two-dimensional coupled implicit Reynolds-averaged Navier-Stokes equations,the shear-stress transport k-ω turbulence model and the finite-rate/eddy-dissipation reaction models were used to simulate the combustion flow field of a typical strut-based scramjet combustor.We investigated the effects of the hydrogen-air reaction mechanism and fuel injection temperature and pressure on the parametric distributions in the combustor.The numerical results show qualitative agreement with the experimental data.The hydrogen-air reaction mechanism makes only a slight difference in parametric distributions along the walls of the combustor,and the expansion waves and shock waves exist in the combustor simultaneously.Furthermore,the expansion wave is formed ahead of the shock wave.A transition occurs from the shock wave to the normal shock wave when the injection pressure or temperature increases,and the reaction zone becomes broader.When the injection pressure and temperature both increase,the waves are pushed out of the combustor with subsonic flows.When the waves are generated ahead of the strut,the separation zone is formed in double near the walls of the combustor because of the interaction of the shock wave and the boundary layer.The separation zone becomes smaller and disappears with the disappearance of the shock wave.Because of the horizontal fuel injection,the vorticity is generated near the base face of the strut,and this region is the main origin for turbulent combustion. 相似文献
817.
Zhang Xu Liu Jia Chen ChuangYe Liu Wei Liu JingBin Li BaoHui He Ming Zhou TieGe Zhao XinJie Yan ShaoLin Fang Lan 《科学通报(英文版)》2011,56(35):3884-3887
A new circuit model for designing and manufacturing an S-band low noise amplifier(LNA) with the software,Advanced Design System(ADS),is introduced in this paper.The proposed model involves shunted impedance at the grid to achieve a stable LNA without measuring the S-parameters of transistors at low temperatures.The LNA was measured over the operation band of 2.2-2.3 GHz,which has input and output standing wave ratios below 1.2.The noise figure of the manufactured LNA was about 0.2 dB and the gain was above 22 dB,which indicated that our LNA worked well at 77 K. 相似文献
818.
In this paper,by taking the water-water balanced counterflow heat exchanger as an example,the entransy dissipation theory is applied to optimizing the design of heat exchangers.Under certain conditions,the optimal duct aspect ratio is determined analytically.When the heat transfer area or the duct volume is fixed,analytical expressions of the optimal mass velocity and the minimal entransy dissipation rate are obtained.These results show that to reduce the irreversible dissipation in heat exchangers,the heat exchange area should be enlarged as much as possible,while the mass velocity should be reduced as low as possible. 相似文献
819.
We investigate the energy nonadditivity relationship E(AαB) = E(A) + E(B) + αE(A)E(B) which is often considered in the development of the statistical physics of nonextensive systems. It was recently found that α in this equation was not constant for a given system in a given situation and could not characterize nonextensivity for that system. In this work, we select several typical nonextensive systems and compute the behavior of α when a system changes its size or is divided into subsystems in different fashions. Three kinds of interactions are considered. It is found by a thought experiment that α depends on the system size and the interaction as expected and on the way we divide the system. However, one of the major results of this work is that, for given system, α has a minimum with respect to division position. Around this position, there is a zone in which α is more or less constant, a situation where the sizes of the subsystems are comparable. The width of this zone depends on the interaction and on the system size. We conclude that if α is considered approximately constant in this zone, the two mathematical difficulties raised in previous studies are solved, meaning that the nonadditive relationship can characterize the nonadditivity of the system as an approximation. In all the cases, α tends to zero in the thermodynamic limit (N→∞) as expected. 相似文献
820.
Preliminary regional estimation of carbon sink flux by carbonate rock corrosion: A case study of the Pearl River Basin 总被引:5,自引:0,他引:5
The formation of carbonate rocks has had a dramatic sink effect on atmospheric CO2 throughout geological time.The wide global distribution of carbonate rocks and their strong sensitivity to climate change mean that carbonate rock corrosion consuming air/soil CO2 can play an important role in the global carbon cycle.The carbon sink accounts for 12.00%-35.29% of the missing carbon in the global carbon cycle.Using the Pearl River Basin as a case study,we analyzed comprehensively the factors impacting karstific... 相似文献