配体二吡啶胺单氧化物的配位多样性(英文)

本文报道了以二吡啶胺单氧化物为配体的三个铜配合物的合成和X-射线衍射数据分析。在不同配位条件下,二吡啶胺单氧化物显示了配位多样性,配体酰胺上的氢原子发生转移或者消除,分子骨架在顺式和反式之间变换。此外,还发现了一个不同寻常的分子构型转换现象。     

金刚石钻进能量与花岗岩地层风化程度的关系

基于钻进过程监测系统在充填土-风化花岗岩地层中对液压旋转钻进的监测数据,对金刚石钻进系统的能量进行了分析.结果表明,钻进系统的能量分布与在普通风化花岗岩地层中的结果一致,黏滞能、动能以及钻进总能量与岩石的风化程度呈负相关,轴力功与岩石的风化程度呈正相关,说明金刚石钻进能量与岩石风化程度具有很好的响应关系.动能、轴力功及黏滞能受钻进方式影响,用于地层识别将受严格的可比条件限制.金刚石钻进比功随岩石风化程度的增强而减少,在不同风化程度的岩层中具有很好的分区性.而且,在充填土及全风化、强风化花岗岩地层中,金刚石旋转钻进比功值明显低于冲击凿碎比功,在微风化的坚硬岩中,旋转钻进比功则明显高于冲击凿碎比功.     

Coral Sr thermometer simplified from Sr/Ca thermometer

Cubic sub-samples obtained from a Porites coral slice collected from Xisha Islands, South China Sea, were weighed with precise micro-balance. The Sr and Ca concentrations were analyzed with isotope dilution thermal ionization mass spectrometry. Our results demonstrate that Ca concentrations in all samples are very uniform ( mean = 9.52mmol/g, la = 0.02mmol/g) ; Sr concentrations and Sr/Ca ratios are well correlated (correlation coefficient r = 0.9968) . It implies that the Sr thermometer can replace Sr/Ca thermometer and the determination of Ca can be omitted. This can save up to 50% time and cost, and more importantly, paleoclimate study using coral proxy can now be carried out in routine Sr isotope laboratories.     

各向异性岩体破坏过程声发射测量及其定位实验研究

应用改进后的声发射设备,实验测量了花岗岩试样在单轴压缩加载条件下变形破坏过程中声发射现象;讨论分析了该试样损伤破坏过程中的诱发微裂纹相互作用、积累等.同时采用对速度结构依赖较少的相对定位方法,对非均质岩石试验中的声发射事件进行了定位研究.结果表明,相对定位方法可用于复杂试样和工程岩体的声发射事件定位,其可靠性及精度比以往有所提高,能够初步定量分析岩石在外载荷作用下的破坏过程的定位问题,对于工程岩体破坏问题分析具有很好的借鉴意义.     

以核苷酸短程关联为基础的进化树重建

据DNA序列中核苷酸短程关闻为主及其进化依赖性，本提出了一个以少核苷酸频数为基础的进化距离的定义，据此用35个物种的16S（18S）RNA序列构建进化树，得到了和生物学公认的进化树一致的结果。最佳的树为用7－8核苷频数作为距离定义构建而成，这意味着存在着一些7－8核苷酸组成的字串，它们与进化强相关。论的最后部分把这些进化相关字串全部找出。     

Factors of 3GWC systems for drawing up customized strategies of promotion

This study utilizes fuzzy analytic hierarchy process(FAHP) to analyze decision-making patterns with regard to third-generation wireless communications(3GWC) service adoption,and to provide customized strategic recommendations to suppliers of 3GWC services regarding marketing and resource allocation in the context of the Chinese 3GWC market.First of all,a three-layer hierarchy of 3GWC adoption factors is developed by referring to the relevant literature and industry reports.A questionnaire of pairwise com...     

高分子土壤改良剂对种籽萌芽之影响研究

以高分子材料为土壤改良剂可使土壤团粒化，增加水份人渗效率，减少土壤冲蚀，为研究环境问题之重要课题。但此类土壤改良剂可能抑制植物种籽萌芽，为使用此种材料的一大问题。以压克力与聚乙烯醇对Bahia种籽做一系列萌芽实验探讨。实验结果发现，压克力对种籽萌芽率与萌芽势能有严重之抑制作用。但适量之聚乙烯醇添加可克服此问题。     

鸭嘴阀扩散器卷吸特性研究

对同向流动环境中的水平DBV射流的掺混特性进行了一系列试验研究,对不同试验组次下的时均速度分量、射流边界、射流动量、紊动强度、雷诺应力和射流卷吸参量做了研究.研究结果表明：按时均中心线流速衰减规律,可将流动划分为3个区域,每个区域有其自身特定的指数衰减率;当x/D＞1.5,除主轴平面内的紊动应力以外,时均速度,紊动强度,雷诺应力出现自相似;轴变换发生在x/D＝1～1.5附近;平均稀释度和无量纲的沿程距离之间存在线性关系,相比于具有相同名义直径的同向流动环境中的圆射流,在相同排放流量条件下,DBV射流具有更好的稀释效果.     

An improved R-tree based on childnode''''s probability

R Tree is a good structure for spatial searching. But in this indexing structure, either the sequence of nodes in the same level or sequence of traveling these nodes when queries are made is random. Since the possibility that the object appears in different MBR which have the same parents node is different, if we make the subnode who has the most possibility be traveled first, the time cost will be decreased in most of the cases. In some case, the possibility of a point belong to a rectangle will shows direct proportion with the size of the rectangle. But this conclusion is based on an assumption that the objects are symmetrically distributing in the area and this assumption is not always coming into existence. Now we found a more direct parameter to scale the possibility and made a little change on the structure of R tree, to increase the possibility of founding the satisfying answer in the front sub trees. We names this structure probability based arranged R tree (PBAR tree).     

Advanced Credit-Assignment CMAC Algorithm for Robust Self-Learning and Self-Maintenance Machine

Smart machine necessitates self-learning capabilities to assess its own performance and predict its behavior. To achieve self-maintenance intelligence, robust and fast learning algorithms need to be embedded in machine for real-time decision. This paper presents a credit-assignment cerebellar model articulation controller (CA-CMAC) algorithm to reduce learning interference in machine learning. The developed algorithms on credit matrix and the credit correlation matrix are presented. The error of the training sample distributed to the activated memory cell is proportional to the cell‘s credibility, which is determined by its activated times. The convergence processes of CA-CMAC in cyclic learning are further analyzed with two convergence theorems. In addition, simulation results on the inverse kinematics of 2degree-of-freedom planar robot arm are used to prove the convergence theorems and show that CA-CMAC converges faster than conventional machine learning.