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111.
研究了十六烷基三甲基溴化铵-正庚烷反胶束溶液和牛血红蛋白水溶液的相平衡,探讨了有机相助表面活性剂种类和浓度、水相pH值、水相离子种类和强度、表面活性剂浓度的影响,适宜条件下,牛血红蛋白的萃取率可达95%以上。对实验结果从表面活性剂极性头与蛋白质分子间的相互作用和反胶团包溶蛋白质时的空间阻碍作用上进行了解释。 相似文献
112.
该文简述了常用枪口火焰测量的几种方法,对各方法存在的问题下作了系统分析,类比于枪口噪声的测量科学地提出了评价枪口火焰大小及强弱的评价指标,在此基础上提出了一种行之有效的光电测试方法,文中阐明了该方法的原理及系统组成,通过枪口火焰的实弹实验,证明了该方法的可行性。 相似文献
113.
以5,6-二溴-2,3-二氰基氢醌为底物,在pH值4.50条件下,用分光光度法考察了Cl-、NO-3和SO2-4离子对漆酶催化活性的影响。发现Cl-、NO-3和SO2-4离子对漆酶的催化活性均有不同程度的抑制作用,其最大抑制率分别可达75%、31.4%和17.1%。动力学研究表明,Cl-、NO-3和SO2-4离子的抑制作用是瞬时完成的,属于竞争性抑制过程,是通过与底物分子竞争漆酶分子中的Ⅱ型铜(Ⅱ)部位实现的。经测定,Cl-和NO-3离子与漆酶所形成的复合物其解离常数分别为1.12×10-4mol·dm-3和1.78×10-3mol·dm-3。 相似文献
114.
Genomic organization of EDSV strain AA-2 总被引:1,自引:0,他引:1
Liyu Zeng Qi Jin Jinggang Zhang Maoxiang Li Hong Li Lei Zhu Zhen Yin Yunde Hou 《科学通报(英文版)》1998,43(7):594-594
The genomic organization of egg drop syndrome virus strain AA-2 isolated in China is reported here. The genome was found to be 32 838 bp in length, approximately 2 kb shorter than those of the human subgenus C adenoviruses. Analysis of open reading frames indicated that the genes for major viral structural proteins (55 K, Penton base, pⅦ, pⅩ, pⅥ, Hexon, 100 K, pⅧ and Fiber), as well as EP, DNA polymerase and ⅣaⅡ are present in the expected locations in the genome. EDSV possesses no identifiable E3 and E4 regions and most proteins encoded by E3 and E4 regions of other adenoviruses genome were not presented in EDSV. 相似文献
115.
The relaxation of the highly vibrationally excited CO (v = 1–8) by CO2 is studied by timeresolved Fourier transform infrared emission spectroscopy (TR FTIR). 193 nm laser photolysis of the mixture
of CHBr3 with O2 generates the highly vibrationally excited CO(v) molecules. TR FTIR records the intense infrared emission of CO(v→v-1). The
vibrational populations of each level of CO(v) have been determined by the method of spectral simulation. Based on the evolution
of the time resolved populations and the differential method, 8 energy transfer rate constants of CO(v = 1–8) to CO2 molecules areobtained: (5.7±0.1), (5.9±0.1), (5.2±0.2), (3.4±0.2), (2.4±0.3), (2.2±0.4), (2.0±0.4) and (1.8±0.6) (1014 cm3 · molecule−1 · s−1), respectively. A two-channel energy transfer model can explain the feature of the quenching of CO(v) by CO2. For the lower vibrational states of CO, the vibrational energy transfers preferentially to the u3 mode of CO2 For the higher levels, the major quenching channel changes to the vibrational energy exchange between CO(v→v-1) and the u1 mode of CO2. 相似文献
116.
The vibrational energy transfer from highly vibrationally excited CO to H2O molecules is studied by time-resolved Fourier transform infrared emission spectroscopy (TR FTIR). Following the 193 nm laser
photolysis of CHBr3 and O2 the secondary reactions generate CO(v). The infrared emission of CO(v → v−1) is detected by TR FTIR. The excitation of H2O molecules is not observed. By the method of the spectral simulation and the differential technique, 8 rate constants for
CO(v)/H2O system are obtained: (1.7 ±0.1), (3.4 ±0.2), (6.2 ±0.4), (8.0 ±1.0), (9.0 ±2.0), (12 ±3), (16 ±4) and (18 ±7) (1013cm3 · molecule-1· s-1). At least two reasons lead to the efficient energy transfer. One is the contributions of the rotational energy to the vibational
energy defect and the other is the result of the complex collision. With the SSH andab initio calculations, the quenching mechanism of CO(v) by H2O is suggested. 相似文献
117.
In order to ascertain the mechanism of interaction between carbide and metallic catalyst and formation of diamond under high pressure and high temperature, and find a new method to synthesize diamond with special properties, it is necessary to investigate the reaction behavior of different carbides and metallic solvent_catalysts under high pressure and high temperature. A system of Cr-3C-2 powder and Ni 70Mn 25Co 5 alloy in weight ratio of 1∶6 was treated under 6 0 GPa and 1 500℃ for 20, 30 or 60 min respectively. X_ray diffraction of the samples indicated the Cr 3C 2 decomposed partially after high pressure and temperature treatment, and Cr 7C 3, Cr and diamond formed respectively. There was not any trace of graphite in the samples. The result suggested that the separated carbon atoms could form diamond directly without conversion process of graphite into diamond. The observation of SEI, WDX and EDX also showed that diamond crystals were synthesized in the system, which have perfect surfaces and shapes, with the average grain size of about 40 μm. The properties of the crystals are being investigated. 相似文献
118.
张红 《青岛大学学报(自然科学版)》1998,11(3):47-50
试样经NaOH溶融,水浸取后,使Fe、Mn、Cu、Co、Ni等共存元素形成氢氧化物沉淀与磷分离,滤液中的磷用磷钼黄光度法测定。方法简便、快速、精密度好、准确度高。经对标准物质GBW07249测定,结果与推荐值吻合,RSD(n=10)〈1.4%。 相似文献
120.
关于国民收入随机模型的最小方差控制 总被引:2,自引:0,他引:2
通过对希克斯(Hicks)一般模型的修正,建立一类关于国民收入的Astrom模型.由此讨论最小方差控制策略,同时结合我国实际问题进行计算、分析. 相似文献