Shear-thickening behavior of Fe-ZSM5 zeolite slurry and its removal with alumina/boehmites

A cryogenic scanning electron microscopy (cryo-SEM) technique was used to explore the shear-thickening behavior of Fe-ZSM5 zeolite pastes and to discover its underlying mechanism. Bare Fe-ZSM5 zeolite samples were found to contain agglomerations, which may break the flow of the pastes and cause shear-thickening behaviors. However, the shear-thickening behaviors can be eliminated by the addition of halloysite and various boehmites because of improved particle packing. Furthermore, compared with pure Fe-ZSM5 zeolite samples and its composite samples with halloysite, the samples with boehmite (Pural SB or Disperal) additions exhibited network structures in their cryo-SEM images; these structures could facilitate the storage and release of flow water, smooth paste flow, and avoid shear-thickening. By contrast, another boehmite (Versal 250) formed agglomerations rather than network structures after being added to the Fe-ZSM5 zeolite paste and resulted in shear-thickening behavior. Consequently, the results suggest that these network structures play key roles in eliminating the shear-thickening behavior.     

Crystallographic texture and earing behavior analysis for different second cold reductions of double-reduction tinplate

Since the production of tinplate with non-earing properties is difficult, especially when it is produced via the double-reduction process, the optimal degree of second cold reduction is particularly important for achieving desirable drawing properties. The evolution of texture and the earing propensity of double-reduction tinplate with different extents of second reduction were investigated in this study. Optical microscopy and scanning electron microscopy were used to observe the changes in the microstructure at various extents of reduction. Two common testing methods, X-ray diffraction (XRD) and electron backscatter diffraction, were used to investigate the texture of the specimens, which revealed the effects of deformation percentage on the final texture development and the change in the grain boundary. The earing rate was determined via earing tests involving measurement of the height of any ear. The results obtained from both XRD analyses and earing tests revealed the same ideal value for the second cold reduction on the basis of the relationship between crystallographic texture and the degree of earing.     

分级多孔纳米炭纤维的结构及电容性能

以酚醛树脂为碳源、PVP为纺丝助剂、纳米MgO颗粒为模板剂,通过静电纺丝法制得酚醛树脂基纳米炭纤维,经过炭化、KOH活化、酸洗后得到分级多孔纳米炭纤维,利用SEM、XRD、XPS、拉曼光谱仪及氮气吸脱附实验,对所制多孔纳米炭纤维的结构和形貌进行表征,并将其作为模拟电容器的电极,利用循环伏安、恒电流充放电及交流阻抗方法测试了材料的电化学性能。结果表明,KOH活化引入了数量可观的微孔,所得纳米炭纤维表现出明显的"微孔-中孔-大孔"分级孔分布的特点,其比表面积达到1058.4m~2/g,总孔容为1.64cm~3/g。电化学测试结果表明,所制分级多孔纳米炭纤维在6mol/L KOH电解液中显示出优异的电容性能,在0.2A/g的电流密度下,其放电比容量达到198F/g,在20A/g电流密度下,电容保持率达到65%。     

Microstructure and corrosion behavior of Al<Subscript>3</Subscript>Ti/ADC12 composite modified with Sr

In this study, we investigated the effect of the addition of Sr (0wt%, 0.1wt%, 0.2wt%, and 0.3wt%) on the microstructure and corrosion behavior of Al₃Ti/ADC12 composite by optical microscopy, X-ray diffraction, scanning electron microscopy, and energy diffraction spectroscopy. The results reveal that the α-Al phases were nearly spherical and 40 μm in size and that the eutectic Si phases became round in the composite when the Sr content reached 0.2wt%. The Al₃Ti particles were distributed uniformly at the grain boundary. The results of the corrosion examination reveal that the Al₃Ti/ADC12 composite exhibited a minimum corrosion rate of 0.081 g·m–2·h–1 for an Sr content of 0.2wt%, which is two thirds of that of unmodified composite (0.134 g·m–2·h–1). This improved corrosion resistance was due to galvanic corrosion, which resulted from the low area ratio of the cathode to anode regions. This caused a low-density corrosion current in the composite, thereby yielding optimum corrosion resistance.     

南图尔盖盆地SA区块河道砂体演化及定量刻画

针对河道砂体横向变化快而难以有效刻画评价的问题,综合应用分频检测、相位调整、地层切片及地质体雕刻等技术对南图尔盖盆地SA区块上侏罗统阿克萨布拉克组河道发育特征及期次进行了研究。首先,利用分频方法检测出目的层段可能存在的两期调谐厚度不同的河道沉积体;然后,采用波阻抗分析和90°相位转换,揭示目的层段地震负振幅与河道砂岩具有较好的对应关系;最后,在高频层序地层格架内制作等时地层切片的基础上,通过河道沉积特征及典型地层切片振幅的单井标定分析,识别并分期刻画出两期不同类型的河道砂体。结合河道弯度、宽厚比及储集体积等参数综合分析认为,早期河道具有低弯度曲流河特征,晚期河道为具有平直河特征的三角洲平原分流河道,且早期河道储集体积明显高于晚期河道。     

不确定条件下多产品第四方物流闭环网络鲁棒优化研究

在不确定条件下,构建了一个包括生产商、集中退货中心、消费区/初始退货点、维修处理中心、分销中心和废弃处置中心的单周期多产品第四方物流闭环网络选址模型。在销售量和退货率均不确定的情况下,用鲁棒优化的方法进行优化,目标是使总成本最小。通过lingo 10对具体算例进行求解。结果验证了该模型的鲁棒性。     

硝苯地平与拉贝洛尔治疗高龄孕妇妊娠期高血压的疗效对比

目的比较硝苯地平与拉贝洛尔对高龄孕妇妊娠高血压病的疗效。方法选取2017年11月至2018年4月治疗的高龄孕妇妊娠期高血压病患者40例,按照随机数字法分为两组,实验组与对照组均为20例。两组患者按照常规给予硫酸镁解痉、镇痛等治疗,对照组采用硝苯地平控释片降压治疗。试验组采用拉贝洛尔降压治疗。连续用药1周。比较两组收缩压及舒张压变化水平、分娩结局、不良反应发生率。结果两组患者的收缩压与舒张压较治疗前均有下降(P 0.05),两组比较无统计学意义(P 0.05);实验组的早产率、新生儿窘迫率、产后出血率均低于对照组,差异有统计学意义(P 0.05);实验组不良反应发生率低于对照组,差异有统计学意义(χ~2=5.03,P0.05)。结论硝苯地平与拉贝洛尔均可控制高龄孕妇妊娠高血压病情,但拉贝洛尔更具优势,不良反应较少,安全性更优。     

甘草酸二钾护理液皮肤修复作用的研究

目的研究甘草酸二钾护理液及含甘草酸二钾卫生巾对擦伤皮肤的修复作用。方法用SD大鼠,制造皮肤擦伤模型,将动物随机分为阳性对照组、阴性对照组、甘草酸二钾护理液高、中、低剂量组、甘草酸二钾卫生巾组,一定时间后,检测创面愈合率,通过HE染色观察损伤皮肤组织病理学变化。结果造模后第7 d和第14 d护理液高、中剂量组和卫生巾组大鼠的皮肤愈合率和组织学评分与阴性组比较具有统计学意义(P 0.05)。结论甘草酸二钾护理液及含甘草酸二钾卫生巾具有促进皮肤修复的作用。     

空气动力学仿真在摩托车造型开发中的应用

摩托车空气动力学特性对摩托车的动力性、经济性和操作稳定性有直接影响。由于国内没有摩托车专用风洞,道路滑行试验无法适用于所有车型,所以在一款新型巡航车造型开发阶段,采用空气动力学仿真方法分析实车模型的空气动力学特性,在此基础上指导多个部件优化设计,并对优化后提供的两个挡风板安装方案分别进行了整车仿真分析。仿真结果显示,优化后的两方案整车阻力系数Cd值均降低,两挡风板安装方案的空气动力学性能对比为进一步选型提供了参考依据。     

高精度数字梯度敏感法测量PMMA板的转角场

用数字梯度敏感法(DGS)测量聚甲基丙烯酸甲酯(PMMA)板的应力梯度(偏转角)。首先,利用数字图像相关方法(DIC)测量了PMMA板在三点弯曲作用下应力集中区域的全场位移,再根据光弹效应建立PMMA板的应力梯度与光线穿过透明件后的偏转角之间的关系,得到PMMA板的转角场。将直接测得的转角场与解析值进行对比,发现存在误差。这是由于试验中不可避免地存在面内刚体平移及离面位移,导致试验中得到的转角场产生误差。通过补偿区域法消除上述影响因素,并讨论了面内刚体平移和离面位移对试验的影响。最后,与解析值对比,结果表明,通过补偿区域法降低了测量误差,得到高精度的转角场。x和y方向转角场的平均相对误差分别为4.90%和5.89%。