NiFeNb种子层对坡莫合金磁滞回线的影响

采用NiFeNb为种子层,制备(Ni82Fe18)1-xNbx(35 )/(Ni82Fe18)(150 )/Ta(30 )系列膜,并对其颗粒大小和磁滞回线等进行测量,探讨种子层中Nb含量x对坡莫合金磁滞回线的影响.结果表明:以NiFeNb作种子层能更好地改善坡莫合金的微结构.种子层厚度为20 ,Nb含量为24 4%时,磁滞回线有最小的回线面积、矫顽力和较小的不对称性.种子层影响坡莫合金磁滞回线的一个重要原因是脱附激活能等因素造成种子层具有不同的表面粗糙度,进而使坡莫合金具有不同的微结构.     

纳米量级超导粒子电子比热中的量子尺寸效应

考虑了奇/偶电子数分布,从配分函数出发,用静态路径近似(SPA)方法和BCS方法计算了随机矩阵理论中高斯正交系综(GOE)所对应的电子能级分布对超导纳米粒子的电子比热的影响,得到了弱自旋-轨道耦合和弱磁场中和奇/偶电子数分布下的电子比热,并做了简单分析.经过计算和分析,发现粒子尺寸和奇/偶电子数对电子比热和转变温度有影响.     

MOCVD法制备Fe/Mo功能梯度材料

利用金属有机化学气相沉积(MOCVD)方法,以Mo(CO)6,Fe(CO)5为物源,在Al2O3陶瓷基片上制备了 Fe/Mo功能梯度材料,并用XPS,XRD,SEM和台阶仪等技术对其成分分布、物相组成、表面形貌和厚度进行测试 和表征.结果表明:材料的组成沿厚度方向呈连续梯度变化,符合功能梯度材料的变化规律.     

苯甲醛缩氨基硫脲铜(Ⅱ)配合物为载体的高选择性硫氰酸根离子电极的研究

以苯甲醛缩氨基硫脲铜(Ⅱ)[Cu(Ⅱ) L2]为中性载体的PVC膜电极对硫氰酸根离子(SCN-)具有优良的电 位响应特性并呈现出反Hofmeister选择性行为,其选择性从大到小的次序为:SCN-,Sal-,ClO-4,I-,Cl-,Br-, Ac-,NO-2,NO-3,SO2-4.电极在pH5.0的磷酸盐缓冲体系中,在1.0×10-1～2.5×10-6mol/LSCN-浓度范围呈 近能斯特响应,斜率为56.0mV(25℃),检测下限为9.0×10-7mol/L.采用交流阻抗技术和紫外可见光谱技术初 步研究了阴离子与载体的作用机理;结果表明,配合物中心金属原子的结构以及载体本身的结构与电极的响应行 为之间有非常密切的构效关系.该电极具有响应快、重视性好、检测限低、制备简单等优点.     

反相高效液相色谱法快速测定靛蓝中残留苯胺

建立了用反相高效液相色谱测定靛蓝中残留痕量苯胺含量的方法.用YWG C18(5μm,300mm×5mmID) 柱,V甲醇∶V水=70∶30的溶液为流动相,柱温30℃时于285nm波长处以外标法测定.结果表明苯胺在6.92× 10-8～3.59×10-4g/mL范围内,浓度与峰面积有良好的线性关系(r=0.9997).苯胺的回收率为98.34%～ 98.36%,相对标准偏差为1.84%～3.03%(n=5).检测限为2.02×10-9g/mL(S/N=3).实验表明该法简便、快 速,应用于实际靛蓝样品中残留痕量苯胺的测定,取得了很好的结果.     

基于电流变的半主动悬架动力学模型的仿真研究

设计了一个混合模式的电流变减振器，将其应用于1／4汽车半主动悬架系统，建立了基于新型电流变减振器的半主动悬架动力学模型，并对其进行了仿真研究，结果表明，该减顺具有良好的隔振性能。     

金属锰氮化的动力学研究

应用真空电阻炉高温渗氮、X射线衍射、惰气熔融法氧氮分析等实验测试方法,研究了金属锰在1173K含氮气氛中的氮化及动力学规律。渗氮时间愈长,试样的氮化量愈多。除有微量的MnO生成外,随渗氮时间的延长,金属锰可全部氮化为Mn4N和ζ-(Mn2N)。建立了金属锰氮化的动力学模型,与实验结果基本符合,能较好地反映氮化规律。     

TMS320C5402 DSP中断资源及其应用

TMS320C5402是美国TI公司推出的TMS320系列中新一代定点数字信号处理器。它以独有的高性能、低功耗及低价位等优势,一经推出便受到业界人士的青睐。该文介绍了该芯片的中断资源,并以定时器中断为例对TMS320C5402中断的实现方法进行了说明,给出了汇编源程序代码。     

Robot Calibration Using Active Vision-based Measurement

This paper presents an efficient robot calibration method with non-contact vision metrology. Using the coplanar pattern to calibrate camera made the active-vision-based end-effector pose measurement be a feasible and cost-effective way. Kinematic parameter errors were linearized and identified through two-step procedure, thus the singular and non-linear condition was overcome. These errors were then compensated using inverse model method. The whole calibration process is flexible, easy to implement and prevents the error propagation from the earlier stages to the later ones. Calibration was performed on MOTOMAN SV3 industrial robot. Experiment results show that the proposed method is easy to setup and with satisfactory accuracy.     

A Study on the Surface Structures of Viscose-based Activated Carbon Fiber by FT-IR Spectroscopy and XPS

Using viscose fiber (VF) as starting material and common steam as activating agent, formation of oxygen structures in activated carbon fiber is investigated. In the preparation of samples, VF was first heated at temperatures between 450℃ and 900℃ in N_2 artmosphere. Then, in a successive activation stage, the product carbonized at 600℃ was activated in steam at 450-900℃ for 30 min, and at 600℃ for 5-30 min. The other carbonization products were activated at 600 and 900℃ for 30 min respectively. The products activated at 900℃ were then activated at 450℃ for 30 min again. The starting materiah carbonized products and all activation products were examined by FT-IR spectroscopy and some products were examined by X-ray photoelectron spectroscope (XPS). And the yields of the carbonized and activated products were calculated. By analysing these spectra, the amount of oxygen-containing functional groups of the activated products attained under various activation time, various activation temperature and