等温过程中奥氏体晶界硼偏聚的非平衡特征

低碳Mn—Mo钢及Fe—Ni合金中硼的非平衡偏聚是一种动力学现象。在一定条件下进行等温处理时,晶界上会出现比平衡偏聚高很多倍的非平衡硼偏聚,但是随保温时间延长,过量偏聚消失。这种偏聚量随等温时间出现峰值变化的现象是这类偏聚非平衡性的重要标志。 在不同温度等温时,硼偏聚量随时间变化曲线呈三种形式,其特征分别是出现峰值后偏聚逐步消失,部分消失和不消失,各种类型温度区间的划分主要取决于非平衡偏聚发生,发展过程与等温时含硼相析出过程的相互关系。     

Reduction of aflatoxin B1 with zinc borohydride: An efficient preparation of aflatoxicol

Summary A simple and mild reduction of aflatoxin B₁, involving treatment of aflatoxin B₁ with ethereal zinc borohydride to give 57–65% yield of diastereomeric aflatoxicols, is described.This work was supported by the College of Agricultural and Life Sciences, the University of Wisconsin, Madison, and by Public Health Service Research, grant No. CA 15064, from the National Cancer Institute, and by funds from contributions of food industries to the Food Research Institute. We are grateful to Professor Dennis Hsieh for a gift of natural aflatoxicol, to Mr William Harder for technical assistance throughout this investigation, and to Mr Gary Girdaukas for taking mass spectra.     

Antiinflammatory reaction associated with murine L1210 leukemia

Summary Mice bearing L1210 leukemia did not show impaired humoral or cellular immune response to antigenic stimulation during the early stage of the tumor, and a depressed response was noted only in the terminal stage. L1210 cells were shown to suppress inflammatory reaction in vivo.Supported in part by USPHS research grant No.5-01-RR05-352-12, and by theIndependent Order of Foresters, San Bernardino District 3208. We acknowledge the valuable assistance ofJudith Johnson andJames Tan in this project. Histopathological examination byDick H. Koobs is appreciated.     

单色光补偿工夫红茶萎凋品质分析

萎凋是工夫红茶加工的首道工序和基础,关系到内含品质成分的转化以及感官品质的形成。文章采用单色LED红光光源进行工夫红茶光补偿萎凋工艺研究。首先,通过单因素试验深入分析了温度、相对湿度以及光照强度3个因子对中小叶种原料萎凋过程中容重、柔性、塑性以及弹性等物理性质,茶多酚、水溶性黄酮、游离氨基酸以及可溶性糖总量等品质化学成分,多酚氧化酶(Polyphenol oxidase, PPO)、过氧化物酶(Peroxidase, POD)等主要酶活性的影响。进而,借助响应面设计,对3个萎凋关键影响因子进行优化。最终,依据感官审评得分,通过方差分析提出以温度27.3℃,光照强度1160 lx,相对湿度59.9%作为浙江中小叶中工夫红茶单色LED红光补偿萎凋的最佳工艺参数。     

棉花病害拮抗菌SC-4鉴定及其抗菌物质分离纯化

从徐州工程学院周围多点取土样,筛选得到一株对多种细菌、真菌(尤其是引起棉花病害的真菌,如棉花立枯病菌、棉花枯萎病菌、棉铃红腐病菌)具有较好抑制作用的放线菌菌株,命名为SC-4.通过形态学、生理生化实验以及菌株16SrDNA序列分析,初步确定其为淡紫灰链霉菌类群中的灰褐链霉菌.通过硫酸铵沉淀获得样品,再经高效液相色谱分离,获得4个组分,其中组分2对棉花致病菌有较好的抑制作用.该研究对于新型生物农药的开发以及棉花病害生物防治具有一定意义.     

A new interpretation of the tectonic setting and age of meta-basic volcanics in the Ondor Sum Group, Inner Mongolia

The Ondor Sum Group in the central Inner Mongolia is mainly composed of meta-basic volcanics intercalated with ferruginous quartzite and quartz schist, and has been interpreted as slices of oceanic crust or an ophiolite suite of the Early Paleozoic or much older ages. This paper presents new LA-ICP-MS zircon U-Pb dating and geochemical data for the meta-basic volcanics. The results show that zircons in the meta-basic volcanics were derived from complicated sources, most of which may be captured by basic magma from the country rocks or other sources. They yield a large age range from the Late Archean to Early Mesozoic with the youngest age group between 246 and 261 Ma, constraining the protolith of the meta-basic volcanics formed in the Late Permian to Early Triassic. The meta-basic volcanics have an affinity to E-MORB in geochemistry, and also a similarity toward OIB, representing a tectonic setting of limited intra-continental ocean basin. This limited basin might have been related to the continuous extension of the area since the Early Permian and finally closed in the Early Mesozoic.     

β-环糊精钴铁氧化物纳米复合材料修饰电极测定对苯二酚

基于β-环糊精钴铁氧化物纳米复合材料研制了一种新型灵敏的电化学传感器,并用于测定对苯二酚.由于在电极上对苯二酚具有高的负载容量和钴铁氧化物直立的导电性,制作的传感器的电化学响应大大提高.结果表明:该方法的线性范围为1~200μmol/L,检出限为0.12μmol/L(R SN=3).所研制的电化学传感器具有良好的选择性和重现性,对对苯二酚合成水样进行了测定,回收率在96.0%~103.5%之间.     

玻璃纤维短切刀具结构参数和材料的优化研究

玻璃纤维短切原丝的生产因对于专用刀具研究不足而生产效率低下、生产成本高.为了改变这一现状,对玻璃纤维短切专用刀具进行研究.首先基于玻璃纤维的特性提出了玻璃纤维的弯曲切断模型,然后对刀具的切入角和切入深度进行了探讨,并基于模型对短切刀具的楔角参数进行了深入研究,得出了楔角参数的优选范围并从企业多年的生产试验数据中得到了验证.研究发现楔角参数的进一步优化与刀具材料有关,因此分析了玻璃纤维短切刀具材料的成分、组织和性能,并据此选用SKS(之后用国产CrWMn材料替代)制成短切刀具与常用的T12A刀具进行短切实验比较,发现CrWMn刀具的使用寿命是碳素钢刀具的5倍,可以极大地提高原丝的生产率.     

预氧化对钒钛磁铁矿球团矿相及内部结构的影响

以钒钛磁铁矿为原料制备氧化球团,利用XRD和SEM等手段,考察室温至500,700,900,1000,1100,1200,1250℃7种情况下预氧化球团的物相组成和微观结构.结果表明,当预氧化温度低于500℃时,球团内部发生γ-Fe2O3向α-Fe2O3的转变,未发生氧化反应;当预氧化温度高于500℃时,随着预氧化温度的升高,球团内部的TTM和FeTiO3氧化生成TTH和Fe2TiO5,白色物相(含Fe,V,Ti)聚合长大与黑色物相(Mg,Al,Si相)逐渐分离,且晶型由较为分散的颗粒状向紧密互联、结构力强的互联状转变.     

以高铬型钒钛磁铁矿制备氧化球团

研究了高铬型钒钛磁铁矿的基础特性,在此基础上考察了该矿对氧化球团制备工艺和冶金性能的影响规律,探索了获得优质氧化球团的高铬型钒钛磁铁矿的最大质量分数.结果表明:高铬型钒钛磁铁矿主要由磁铁矿、镁铁矿、铬铁矿、镁钛矿、钒磁铁矿、钛磁铁矿等组成,其粒度粗,连晶强度较差;随球团原料中高铬型钒钛磁铁矿质量分数的增加,生球性能无显著变化,成品球团抗压强度降低,当其质量分数高于20%时,不能满足高炉生产要求.增大高铬型钒钛磁铁矿的质量分数有助于降低球团矿的还原膨胀率,当其质量分数由0增加到20%时,球团的还原膨胀率由321%降低到211%.