Drying-mediated self-assembly of nanoparticles

Systems far from equilibrium can exhibit complex transitory structures, even when equilibrium fluctuations are mundane. A dramatic example of this phenomenon has recently been demonstrated for thin-film solutions of passivated nanocrystals during the irreversible evaporation of the solvent. The relatively weak attractions between nanocrystals, which are efficiently screened in solution, become manifest as the solvent evaporates, initiating assembly of intricate, slowly evolving structures. Although certain aspects of this aggregation process can be explained using thermodynamic arguments alone, it is in principle a non-equilibrium process. A representation of this process as arising from the phase separation between a dense nanocrystal 'liquid' and dilute nanocrystal 'vapour' captures some of the behaviour observed in experiments, but neglects entirely the role of solvent fluctuations, which can be considerable on the nanometre length scale. Here we present a coarse-grained model of nanoparticle self-assembly that explicitly includes the dynamics of the evaporating solvent. Simulations using this model not only account for all observed spatial and temporal patterns, but also predict network structures that have yet to be explored. Two distinct mechanisms of ordering emerge, corresponding to the homogeneous and heterogeneous limits of evaporation dynamics. Our calculations show how different choices of solvent, nanoparticle size (and identity) and thermodynamic state give rise to the various morphologies of the final structures. The resulting guide for designing statistically patterned arrays of nanoparticles suggests the possibility of fabricating spontaneously organized nanoscale devices.     

ENVIRONMENTAL CHALLENGES FACING INDIA

INTRODUCTION India is among one of the ten most industrialized nations in the world. Increase in population has raised the urbar industrial, transport and agriculture demands which are major reasons for the degradation of the environmel condition. For India besides land and soil degradation, deforestation, low accessibility of water, ,industrial pollution and urban congestion are the major environmental issues of priority. The industries that generate huge quantities of waste are thermal power station, Iron and Steel Plants, Sugar, Paper and Fertilizer Industries.