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Many molecules can rotate freely around single bonds and thereby interconvert between different conformations, such as gauche and anti 1,2-disubstituted ethane, a classic example of conformational isomerism. Even though rotation occurs rapidly at room temperature, the product selectivity seen in some reactions has been explained by conformation-dependent reaction mechanisms: if reactant molecules differing only in their conformation are located at different positions on the reaction path, they may undergo different reactions. But a direct verification of this effect is difficult, because the energy barrier separating conformational isomers is so low that under ambient conditions reactants with more than one conformation will be present. But by using temperatures low enough to suppress the interconversion between different conformations, gauche-1-iodopropane ions and anti-1-iodopropane ions have been selectively generated. Here we show that the kinetic energy released during the photodissociation of 1-iodopropane ions depends strongly on the conformation of the ions. Thermodynamic arguments and ab initio calculations indicate that this difference in kinetic energy release results from differences in the reaction mechanism, with gauche-1-iodopropane ions forming 2-propyl ions and anti-1-iodopropane ions forming protonated cyclopropane ions. These findings suggest that the well-known concept of conformation selection forms the basis of a simple scheme for reaction control, thus providing in some cases an attractive alternative for more involved schemes that utilize the phase and pulse shape of laser beams to control chemical reactions. 相似文献
3.
金昌虎 《沈阳大学学报:自然科学版》2006,18(1):10-13
以证明在线口传内容对口传效果的影响及收信者的特性的作用为目的。通过已有的研究,把口传内容划分为商品信息和个人经验,把口传效果划分为口传受用和口传行为。以大学生为对象,对MP3购买活动和相关在线口传活动进行了268个问卷调查,并用SPSS 10.0统计法进行了分析。研究结果表明:第一,口传信息的受用度使商品资讯更高,口传行为使个人体验资讯更为受用。第二,商品资讯和个人体验对口传内容的效果(口传受用,口传行为)决定于收信者的产品知识,即对在线的口传内容和口传信息受用的关系有调节作用,而且,对口传行为的影响也有调节效果。最后,关联度变数如先前所设的口传内容和口传效果的关系,对它们的关系有调节作用。 相似文献
4.
Sensor networks consisted of low-cost, low-power, multifunctional miniature sensor devices have played an important role in our daily life. Light and humidity monitoring, seismic and animal activity detection, environment and habitat monitoring are the most common applications. However, due to the limited power supply, ordinary query methods and algorithms can not be applied on sensor networks. Queries over sensor networks should be power-aware to guarantee the maximum power savings. The minimal power consumption by avoiding the expensive communication of the redundant sensor nodes is concentrated on. A lot of work have been done to reduce the participated nodes, but none of them have considered the overlapping minimum bounded rectangle (MBR) of sensors which make them impossible to reach the optimization solution. The proposed OMSI-tree and OMR algorithm can efficiently solve this problem by executing a given query only on the sensors involved. Experiments show that there is an obvious improvement compared with TinyDB and other spatial index, adopting the proposed schema and algorithm. 相似文献
5.
LI Xi-zuo HAN Gui-ying KIM Sun-ho 《武汉大学学报:自然科学英文版》2006,11(1):203-210
0 IntroductionTobadaseyd’s o nintfhoer mflaotiwonof s ywsotrekmss t hhraovueg hbe tehne doervgealnoipzead-tion rather than based ontasks .Duetothistrend,work-flowand business process technology has been applied tovarious applications such as ERP, groupwares , E-mar-ketplaces , E-business etc . When business processes areapplied to these applications ,business processes are de-fined by process designers and business process instancesare executed by workflowengines or workflow manage-ment sys… 相似文献
6.
线性搜索是最优化计算中最普遍应用的方法,文中对Fletcher线性搜索方法作了改进,它具有减少梯度值计算次数的特点,并用数值结果表明了方法的有效性。 相似文献
7.
尾叶香茶菜中对映—贝壳杉烯型二萜 总被引:1,自引:1,他引:1
尾叶香茶菜中对映-贝壳杉烯型二萜王艳红1)陈耀祖2)孙汉董3)金东史4)(1)中山大学化学与化学工程学院,广州510275;2)浙江大学化学系;3)中国科学院昆明植物研究所植化室;4)朝鲜国家科学院植物研究所)关键词唇形科,香茶菜属,尾叶香茶菜,对... 相似文献
8.
Books and archives experience aging which is affected by a variety of factors, such as microorganism, humidity, light and components of paper [1]. Thus, the studies concerning impacts of those factors on paper aging are required. In this paper, an accelerated paper aging was carried out to investigate the effects of acid and metals such as alum, copper ( Ⅱ ) sulfate, copper ( Ⅱ ) chloride, and iron (Ⅲ) chloride on paper aging. It was found that both acid and metals had impacts on paper aging. In particular, paper aging was far more accelerated in case that acid and metals were present in paper at the same time. 相似文献
9.
Minimum information about a microarray experiment (MIAME)-toward standards for microarray data. 总被引:36,自引:0,他引:36
A Brazma P Hingamp J Quackenbush G Sherlock P Spellman C Stoeckert J Aach W Ansorge C A Ball H C Causton T Gaasterland P Glenisson F C Holstege I F Kim V Markowitz J C Matese H Parkinson A Robinson U Sarkans S Schulze-Kremer J Stewart R Taylor J Vilo M Vingron 《Nature genetics》2001,29(4):365-371
Microarray analysis has become a widely used tool for the generation of gene expression data on a genomic scale. Although many significant results have been derived from microarray studies, one limitation has been the lack of standards for presenting and exchanging such data. Here we present a proposal, the Minimum Information About a Microarray Experiment (MIAME), that describes the minimum information required to ensure that microarray data can be easily interpreted and that results derived from its analysis can be independently verified. The ultimate goal of this work is to establish a standard for recording and reporting microarray-based gene expression data, which will in turn facilitate the establishment of databases and public repositories and enable the development of data analysis tools. With respect to MIAME, we concentrate on defining the content and structure of the necessary information rather than the technical format for capturing it. 相似文献
10.
Hyuneui Lim Dae-Hwan Jung Jung-Hyun Noh Gyeong-Rin Choi Wan-Doo Kim 《科学通报(英文版)》2009,54(19):3613-3616
This paper describes a simple fabrication method for creating superhydrophobic and transparent glass surfaces that mimic natural surfaces such as lotus leaves, moth eyes or cicada wings. Nanostructured glass surfaces were created by a combination of colloidal lithography and plasma etching. A colloidal mask was formed simply by the spin coating of the polystyrene beads and with modification of the interparticle distance between the beads. The etching of the glasses was conducted by CF4 plasma. Tower-shaped nanostructures at an aspect ratio of 1:4 were treated using fluoroalkylsilane selfassembled monolayers (SAMs) to obtain the hydrophobic surfaces. The treated glass surfaces showed superhydrophobicity with a water contact angle of around 150° and a hexadecane contact angle of around 110° Furthermore, the nanostructured glass was transparent to visible light. 相似文献