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1.
测量了聚对苯二甲酸乙二醇酯的微分时域介电谱.在它的低温β转变中快极化不出现奇异,但3个慢极化机构出现抛物型软化  相似文献   

2.
基于热平衡态的冷冻介电谱可提供慢极化响应过程的能谱信息,用此方法研究了苯和石 慢极化响应过程,发现在接近各处在的高温极化温度前谱线均发生分裂,研究石蜡的两个冷冻放电过程中束缚电荷引起的活化能与温度的关系,发现温度增加,石蜡的束缚电荷能级势垒降低,极化成份增加,量增大,慢极化电荷对两种冷冻方法表现出没的温度关系。  相似文献   

3.
聚对苯二甲酸乙二醇酯的冷冻介电谱   总被引:1,自引:1,他引:0  
用冷冻介电谱方法将聚对苯二甲酸乙二醇酯在液氮温度下冷冻下来的驻极体效应的不同微观机构分开,得到1个快极化和3个偶极取向慢极化成份.  相似文献   

4.
在104至10-5Hz频段,聚合物的介电谱只能用时域参数描述.介质的极化响应可描述为Aεsexp[-(t/τ)类型的若干个项之和.实验证明在随机驰豫中α=1,在自由驰豫中则α=1/2.在低频段用频域方法测量εs时.样品中的慢响应极化机构的贡献表现为吸收电流;它使得εs没有确定值,时域参数是十分灵敏的方法,它可以检测出对εs的贡献只有10-4的微量极化机构.对于同一种聚合物、慢极化响应的成份决定于材料的加工工艺和添加物.  相似文献   

5.
聚合物极化的非马尔可夫过程   总被引:1,自引:1,他引:0  
聚合物极化是典型的非马尔可夫过程,其中存在极化强度等于零而与温度或时间均无关的原始态.由此以后经历的过程,只要温度不太高而电场不太强,体系的热平衡极化性质确定并和弱场有线性关系而同以前的历史无关,但必须计及由原始态起的全过程的记忆效应.聚合物的动态极化性质,只能在全过程中以经历过的不同热平衡态隔开的每个片段中分别研究,不同片段的动态过程可以有完全不同的规律.给出了研究非马尔可夫过程的实验和理论方法实例  相似文献   

6.
采用线变零起始电压法,对Pb(Zn1/3Nb2/3)O3基陶瓷样品在-150~160℃温度范围内的超慢介电弛豫进行了详细测试;并结合普适型弛豫函数进行了实验数据的有效拟合,实现了介电常数从时域向频域的傅利叶转换,从而得到该样品的超低频(10-5~10-1Hz)介电频谱、温谱.观察到该样品的超低频介电温谱在居里温度点110℃附近存在扩散相变温区,并且在相变温区以下表现出明显的弛豫弥散现象、用热刺激电流(TSC)得到样品的弛豫激活能E和本征驰豫时间τ0,并对其弛豫极化机制进行了讨论.  相似文献   

7.
汽油中杂质的慢介电谱   总被引:4,自引:0,他引:4  
石油产物中含有微量杂质时频域介电谱无法觉察,但会引起显著的慢介电谱.时域方法可检测出汽油中10mg/kg的杂质硫和氧  相似文献   

8.
给出了一个简化模型描述载流子在电流变液中的输运 .颗粒极化可分为两部分 ,慢极化分量由载流子的受阻输运所致 ;快极化分量是载流子所在介电背景的极化 .在切变场中 ,一个强的电流变强度要求强而相对稳定的颗粒相互作用 .大的极化强度确保相互作用强度 ,合适的极化速率和介电损耗以保证颗粒相互作用的相对稳定性 .根据计算结果并考虑到切变场对介电响应的影响 ,这里给出一个半经验电流变活性判据 :对于ω <10 3s-1,ωτ >10 -4 ,存在 1相似文献   

9.
在慢应变速率拉伸过程中通过施加循环电位扫描及电位阶跃等不同的电位极化方式,研究了奥氏体不锈钢在酸性氯化物溶液中的应力腐蚀开裂敏感性,并利用SEM技术观察了断口形貌.结果表明,电位扫描速度和电位阶跃频率对裂纹萌生扩展起决定作用.相同电位范围内,电位阶跃比电位扫描导致更高的材料断裂敏感性.  相似文献   

10.
钛酸锶钡的极性相变和介电谱   总被引:1,自引:1,他引:0  
从不同含锶量的Ba1-xSrxTiO3陶瓷的频域介电谱测量结果看出,德拜偶极取向极化理论不适用于Ba1-xSrxTiO3陶瓷.结合Ba1-xSrxTiO3的时域介电谱分析可知,频域Ch偏离了严格定义的快C1是由慢极化对频域测量的干扰所引起的  相似文献   

11.
Language markedness is a common phenomenon in languages, and is reflected from hearing, vision and sense, i.e. the variation in the three aspects such as phonology, morphology and semantics. This paper focuses on the interpretation of markedness in language use following the three perspectives, i.e. pragmatic interpretation, psychological interpretation and cognitive interpretation, with an aim to define the function of markedness.  相似文献   

12.
何延凌 《科技信息》2008,(4):258-258
Language is a means of verbal communication. People use language to communicate with each other. In the society, no two speakers are exactly alike in the way of speaking. Some differences are due to age, gender, statue and personality. Above all, gender is one of the obvious reasons. The writer of this paper tries to describe the features of women's language from these perspectives: pronunciation, intonation, diction, subjects, grammar and discourse. From the discussion of the features of women's language, more attention should be paid to language use in social context. What's more, the linguistic phenomena in a speaking community can be understood more thoroughly.  相似文献   

13.
理论推导与室内实验相结合,建立了低渗透非均质砂岩油藏启动压力梯度确定方法。首先借助油藏流场与电场相似的原理,推导了非均质砂岩油藏启动压力梯度计算公式。其次基于稳定流实验方法,建立了非均质砂岩油藏启动压力梯度测试方法。结果表明:低渗透非均质砂岩油藏的启动压力梯度确定遵循两个等效原则。平面非均质油藏的启动压力梯度等于各级渗透率段的启动压力梯度关于长度的加权平均;纵向非均质油藏的启动压力梯度等于各渗透率层的启动压力梯度关于渗透率与渗流面积乘积的加权平均。研究成果可用于有效指导低渗透非均质砂岩油藏的合理井距确定,促进该类油藏的高效开发。  相似文献   

14.
As an American modern novelist who were famous in the literary world, Hemingway was not a person who always followed the trend but a sharp observer. At the same time, he was a tragedy maestro, he paid great attention on existence, fate and end-result. The dramatis personae's tragedy of his works was an extreme limit by all means tragedy on the meaning of fearless challenge that failed. The beauty of tragedy was not produced on the destruction of life, but now this kind of value was in the impact activity. They performed for the reader about the tragedy on challenging for the limit and the death.  相似文献   

15.
正The periodicity of the elements and the non-reactivity of the inner-shell electrons are two related principles of chemistry,rooted in the atomic shell structure.Within compounds,Group I elements,for example,invariably assume the+1 oxidation state,and their chemical properties differ completely from those of the p-block elements.These general rules govern our understanding of chemical structures and reactions.Using first principles calcula-  相似文献   

16.
We have developed an adiabatic connection to formulate the ground-state exchange-correlation energy in terms of pairing matrix linear fluctuations.This formulation of the exchange-correlation energy opens a new channel for density functional approximations based on the many-body perturbation theory.We illustrate the potential of such approaches with an approximation based on the particle-particle Random Phase Approximation(pp-RPA).This re-  相似文献   

17.
正The electronic and nuclear(structural/vibrational)response of 1D-3D nanoscale systems to electric fields gives rise to a host of optical,mechanical,spectral,etc.properties that are of high theoretical and applied interest.Due to the computational difficulty of treating such large systems it is convenient to model them as infinite and periodic(at least,in first approximation).The fundamental theoretical/computational problem in doing so is that  相似文献   

18.
<正>"The Journal of Shanghai Normal University:Mathematics"is published by Shanghai Normal University as regular issues of The Journal of Shanghai Normal University each year from 2014 in English.The editors-in-chief of the issues are professors Yuhao Cong and Maoan Han.The Journal of Shanghai Normal University was started in 1958 with  相似文献   

19.
20.
<正>"Journal of Jilin University(Science Edition)"is a comprehensive academic journal in the fields of science sponsored by Jilin University and administrated by the Ministry of Education of the Peoples Republic of China.The journal started publication in 1955.The original name at starting publication was"Journal of Natural Science of Northeast People University",which was changed into"Acta Scientiarum Naturalium Universitatis Jilinensis"in 1958 owing to the name change of the university.The present journal name has  相似文献   

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