AN FTIR SPECTROSCOPIC STUDY OF LOW TEMPERATURE PLASMA TREATED WOOL FABRIC

FTIR-ATR technique with second-order derivative measurement was used for assessing the amount of oxidation products of cystine present on the plasma-treated wool fabric surface. In this paper, three non-polymerising gases namely oxygen, nitrogen and 25% hydrogen/75% nitrogen gas mixture were used for the plasma treatment of wool fabric. The oxidation products of cystine studied included S-sulphonate, cysteic acid, cystine monoxide and cystine dioxide. The variations of the amount of these products as a function of treatment time were studied. Experimental results showed that the oxygen plasma could produce a large amount of oxidation products of cystine on the wool fabric surface followed by nitrogen plasma and gas mixture plasma.     

苎麻竹纤维功能性纺织面料研究

介绍了苎麻竹纤维的特点,用苎麻纱线与竹纤维纱线交织生产苎麻竹纤维织物,并对织物进行丝光、烧毛、低温等离子、生物酶抛光和防皱整理,研制的织物具有透气、挺刮、不贴身、抑菌、抗菌、易吸湿散湿、具有凉爽感和弹性感的特点,又增加了织物的悬垂感等布面光洁清晰,手感柔软,色泽鲜艳亮丽,具有丝绸般的风格.     

六氟丙烯等离子体处理纯棉织物的研究

以六氟丙烯为气氛对纯棉织物进行等离子体处理，通过改变处理功率、时间和压力等条件，考察处理后的纯棉织物表面的拒水性能。采用接触角作为评价拒水性大小的依据，当改变压强、时间和功率中的某一因素时接触角呈现规律性的变化，每个因素都存在相应的最适条件。经过皂洗后，等离子体处理过的纯棉织物的拒水性有一定的下降，再经过数次皂洗则趋于平稳。等离子体处理后织物的拉伸强力增大，颜色和透湿量的变化不大，基本不影响其服用舒适性。     

冷等离子体对涤棉表面改性及其时效性研究

采用不同工作气体的冷等离子体及不同工作压力,对涤棉进行表面改性,同时测试改性前后涤棉表面的毛细效应,分析其毛细效应的变化程度和趋势．实验结果表明,涤棉经空气、氩气、氮气和氧气等离子体处理后,其表面毛细效应会随着处理时间的延长而增强．同时,改性后涤棉的亲水性能会随着放置时间的延长,有逐渐退化的趋势,由于工作气体不同,工作压力不同,其毛细效应随处理时间和放置时间的变化程度也不尽相同．     

低温氧等离子体处理对羊毛织物性能的影响

为了改善羊毛织物的毡缩、润湿等性能,采用低温氧等离子体对羊毛织物进行改性处理.通过单因素实验,综合评价羊毛织物处理前后的性能变化情况,分析了羊毛织物性能变化与等离子体处理时间、功率和压强变化之间的相互关系;利用原子力显微镜表征了处理前后羊毛纤维鳞片结构的变化情况.实验结果表明,利用低温氧等离子体对羊毛织物进行改性处理,可以获得较好的防毡缩效果,并能改善织物的润湿性能.有效控制处理条件,织物的断裂强力和伸长率不但不会减小,反而可以得到一定程度的增强.     

Comparison of Structures and Properties between Wool and Ramie Fibers Treated by Atmospheric Pressure Ar and Ar/O2 Plasma

The technique of atmospheric pressure plasma is of value in textile industry. In this paper, argon (Ar) and argon/oxygen (Ar/O2) atmospheric pressure plasma were used to treat wool and ramie fibers. The structures and properties of treated fibers were investigated by means of SEM, XPS, single fiber tensile tester and so on.The results proved that the effects of plasma treatments depended on structural characteristics of fibers to a great extent, besides conditions of plasma treatment. By atmospheric pressure plasma treatment, wool fiber had significant changes in morphology structure, surface chemical component, mechanic properties and dyeability, while ramie fiber just showed a little change. In additional, Ar/Q2 plasma showed more effective action than argon. And at the beginning of treatment, plasma brought about remarkable effects, which did not increase with prolonging of treat time.     

碱处理对剑麻连续长纤增强聚丙烯复合材料力学性能的影响

以丙纶长纤为经纱,剑麻连续长纤为纬纱,织成剑麻/PP平纹机织物.采用不同浓度的氢氧化钠对织物进行碱处理,将处理后的织物与聚丙烯薄板模压成型,制备出剑麻连续长纤增强聚丙烯复合材料.采用SEM对碱处理前后的剑麻纤维形貌进行分析,讨论不同碱处理浓度对复合材料力学性能的影响.结果表明:碱处理对剑麻连续长纤的表面具有刻蚀作用,以及对剑麻连续长纤增强聚丙烯复合材料的动态热机械性能、拉伸性能、弯曲性能均有一定的影响.     

Plasma Modification of Wool: The Effect of Plasma Gas on the Properties of the Wool Fabric

The wool fabrics were treated with low temperature plasma (LTP) using three different gases, namely (ⅰ) oxygen, (ⅱ) nitrogen and (ⅲ) 25％ hydrogen/75％ nitrogen gas mixture. After LTP treatment, the low stress mechanical properties, surface properties and thermal properties of the fabrics were investigated by kES-F (Kawabata Evaluation System) Instruments composing of KES-FBI for tensile and shear property measurement, KES-FB2 for pure bending measurement, kES-FB3 for compression measurement, KES-FB4 for surface friction and surface roughness measurement, and KES-F7 for thermal property measurement. The first four instruments were used for investigating the charaeterlstlc aspect related to fabrle hand while the last one was mainly for the fabric comfort. The properties of LTP treated fabrics under the effect of different gases were compared with the untreated fabric quantitatively.     

The Application of Microwave Low Temperature Plasma in Pretreatment of Cotton Fabric

The effect of microwave low temperature plasma pretreatment on desizing and removing natural impurity of cellulose fiber was studied. The influencing factors of pretreatment such as treating power, gas pressures and time were discussed in detail and the final effect had been compared with that of traditional pretreating process of cotton fabric. The results showed that better capillary effect, strength, whiteness and dyeing K/S value could be given by means of microwave low temperature plasma treatment.     

棉织物的等离子体聚合涂覆及其拒水性研究

使用某种氟碳化合物的AC等离子体沉积方法 ,在棉织物表面涂覆一层很薄的憎水膜。影像接触角测试表明 ,仅仅经过 3 0s的涂覆处理 ,棉织物表面水接触角就可达 164°左右 ,获得超级憎水特性。棉织物的柔软性、保水率、回潮率、颜色变化、手感、透气性等都采用标准方法进行了详细研究 ,并与商用ScotchgardTM防水防污喷雾型保护剂涂覆的织物进行了比较。研究结果表明 ,除了回潮率基本相同外 ,等离子体涂覆织物的这些性能都优于保护剂涂覆织物的性能。同时 ,对加热后处理对涂层织物憎水性的影响进行了研究 ,结果表明 ,高温后处理有助于织物憎水性的提高。原子力显微镜和二次离子质谱研究结果显示 ,加热后处理后沉积膜的表面形态和化学性能都发生了变化 ,这种变化可能导致了织物憎水性能的改变     

STUDIES ON SURFACE CHARACTERIZATION AND ECOMATERIAL SHEET DEGRADATION OF BASALT FIBERS BY PLASMA TREATMENTS AND WOOD FIBERS

1.INTRODUCTIONDue to the fact that it is difficult to recover for many composites, developing naturally degradable ecocomposites has received increasing attention among scientists [1-4]. Basalt fibers serves as a reinforcement for a wide range of applications such as heat-insulation, resistance combustion, soundproofing. Their advantages include no carcinogenic effect, environmentally friendly, flexible, good temperature resistance and heating insulation property[5-8]. They were regarded …     

服装面料表面反光性能的设计

服装面料表面反射光与面料的光泽及视觉风格有着密切的关系 .从服装面料表面反射光设计的一般原则和主要影响因素两个方面对这一问题进行了分析 ,并以缎纹织物为例对面料表面反射光的设计进行了探讨 .研究可知 ,影响服装面料表面反射光的主要因素包括纤维性状 ,纱线结构和织物结构 .另外 ,面料的后整理方法对面料表面反射光也有较大影响 .在众多影响因素中 ,以纤维的表面、纵向形态及截面性状影响最大 .服装面料表面反射光的设计应综合考虑各种因素 .     

Study on Bombyx mori silk treated by oxygen plasma

Study of the morphology, aggregation structure and properties of Bombyx mori silk treated by low temperature oxygen plasma showed that slight flutes appeared on the surface of Bombyx mori silk fiber and that its surface structure changed after plasma treatment. The conformation also changed and crystalline degree decreased. The stannic filling rate of treated fiber was improved. Because of etching, the weight of the fiber decreased but the breaking strength changed little after short-time treatment.     

电化学处理程度对碳纤维结构及性能的影响

采用质量分数为5%NH4HCO3溶液对聚丙烯腈(PAN)基碳纤维进行不同程度的电化学处理。采用X射线光电子能谱(XPS)和拉曼光谱(Raman)表征电化学处理前后碳纤维表面化学成分和表面微观结构的变化规律。将碳纤维样品与环氧树脂制成复合材料,探究该复合材料的层间剪切强度(ILSS)。研究结果表明:经过3组电化学处理后,碳纤维表面含氧官能团增多、表面有序度下降、复合材料的ILSS提高1.94倍;继续经过3组电化学处理,碳纤维表面含氧官能团下降、表面有序度回升、复合材料的ILSS提高1.53倍;纤维表面含氧官能团含量越多,纤维的结构破坏程度越低,碳纤维/环氧树脂复合材料的ILSS越高。在大规模电化学处理碳纤维过程中,选择3组电化学处理碳纤维,既能大幅度改善碳纤维表面活性,又不会严重影响碳纤维的表面结构。     

低温等离子体处理对羊毛织物性能的影响

采用空气低温等离子体对羊毛表面进行改性处理,探讨了等离子体处理对羊毛织物抗毡缩性、强力、白度、润湿性、染色性能等的影响.正交试验结果表明:等离子体处理羊毛织物的实验室最佳工艺为时间3min、压强50Pa、功率150W.经空气低温等离子体处理,羊毛织物的毡缩率和白度降低,而润湿性、强力和弱酸性普拉红B染色K/S值提高.单独经过空气等离子体处理的羊毛织物达不到"机可洗"的要求.     

聚丙烯腈超滤膜低温氧等离子体表面改性

研究了聚丙烯腈 (PAN)平板超滤膜的低温氧等离子体表面改性 .结果表明 ,改性后的 PAN超滤膜透水率降低 ,截留率上升 .研究了低温等离子体条件 (放电功率、反应腔压力、改性处理时间 )对改性结果的影响 .实验研究表明 ,低温等离子体表面改性技术可用于 PAN超滤膜的改性 .     

空气电晕放电处理涤纶织物表面结构性能表征

利用XPS、ATR-FTIR等手段来研究DMF预溶胀涤纶经电晕放电处理后的表面结构性能.结果表明:电晕处理后表面引入了氧元素;表面晶区下降,非晶区含量提高,经长时间处理后,各含量与原样接近.     

热氧化对PAN基碳纤维结构与性能的影响

将PAN基碳纤维在于400~700℃条件下空气中进行热氧化处理,然后利用扫描电子显微镜(SEM)、X射线光电子能谱(XPS)、密度梯度管和纤维强力仪研究了其表面化学组成、表面形貌与性能的变化。结果表明:热氧化温度低于600℃时,纤维表面含氧量随热氧化温度升高不断增加,到600℃时氧含量增加了7.11%,主要增加的官能团为羟基、醚键以及羰基,纤维体密度、线密度随热氧化温度变化不明显;700℃时由于含氧官能团的裂解,氧含量有所减少,裂解部分主要为羰基,纤维体密度明显增加,线密度急剧减小;纤维强度随热氧化温度升高不断减小,600℃后减小趋势更加明显;模量随热氧化温度变化不明显。     

碳纤维表面处理及其复合材料界面优化的研究Ⅰ．低温等离子处理对碳纤维表面的作用

通过碳纤维表面的扫描电镜观察与复丝力学性能测定，发现等离子处理对纤维的模量几乎没有影响，而强度随着处理功率的增加和时间的延长稍有下降，在外观上仅表现为纤维表面纵向沟槽的加深。氩气等离子比氧化性空气等离子的损伤小。通过碳纤维表面的Ｘ射线光电子能谱分析，结合喇曼光谱的研究，还发现等离子处理的有效深度达到１５ｍｍ左右。其作用是蚀刻去碳纤维表面脂肪链结构，产生石墨等晶体结构富集的高能表面。     

空气等离子体炬改性连续玻纤束的工艺研究

玻璃纤维表面光滑且呈化学惰性,聚丙烯缺少极性官能团,导致玻璃纤维与聚丙烯之间的界面润湿性能较差。为了提升玻璃纤维增强聚丙烯(GFRP)复合材料的界面结合性能,设计并搭建了空气等离子体炬处理装置,通过该装置在连续玻璃纤维束表面沉积SiO_x纳米颗粒,并测定了改性玻璃纤维的润湿性能和GFRP复合材料的界面剪切强度;采用响应曲面法(RSM)分析了喷嘴与纤维间的距离、载气流量、处理时间对玻璃纤维润湿性能的影响,并对这些工艺参数进行了优化。结果表明：当处理距离为20 mm、载气流量为1.5 L/min、处理时间为6 s时,与对照组相比,改性后的玻璃纤维与聚丙烯的接触角降低了49.8%,GFRP复合材料的界面剪切强度提高了94.7%;载气流量对玻璃纤维润湿性能的影响程度最大,处理时间次之,处理距离的影响最小。优化后的工艺参数为：喷嘴与纤维间的距离为18 mm,载气流量为1.7 L/min,处理时间为7 s。在此工艺条件下制备了空气等离子体炬改性的玻璃纤维,实测的接触角(24.6°)与预测值(25.0°)之间的偏差仅为1.6%。