Diagenetic-metallogenic ages of pyritic cherts and their implications in Mojiang nickel-gold deposit in Yunnan Province, China

Diagenetic-metallogenic ages of pyritic cherts formed by the syn-sedimentation of hydrothermal vent and ages of the Jinchang Rock Formation in the Mojiang large nickel-gold deposit in the Ailaoshan gold metallogenic belt have been discussed on the basis of chronology of isotopic geochemistry. Nickel-gold-bearing pyritic cherts in the mining were formed by syn-sedimentation of hydrothermal vent in the Late Devonian, i.e. age by Sm-Nd isochronal method (t) = (358±8.6) (2σ) Ma and age by Rb-Sr isochronal method (t) = (354.7±0.72) (2σ) Ma. On the other hand, deep-water cherts from the Jinchang Rock Formation of the Upper Devonian in the area were initiated at the same time; that is, age by Sm-Nd isochronal method (t) = (359±21) (2σ) Ma and age by Rb-Sr isochronal method (t) = (358.02±0.30) (2σ) Ma.     

江西乐平塔前钼(钨)矿床成岩成矿时代及意义

探讨江西省乐平市塔前钼(钨)矿床成矿岩体的形成时代。通过对塔前钼(钨)矿床进行野外地质调查和SIMS锆石U-Pb测龄,结果表明其成矿母岩为花岗闪长斑岩,其加权平均年龄为160.9±2.5 Ma(MSWD=0.69),代表矿区花岗闪长斑岩的结晶时间。这与矿区矽卡岩矿石中辉钼矿Re-Os同位素年龄(162±2 Ma)在误差范围内一致,说明此矿床形成于中侏罗世晚期。将其与钦杭成矿带东段塔前-赋春成矿带与乐华—德兴成矿带中同类矿床进行对比发现,前者成矿年龄集中于161 Ma±,控岩控矿构造皆以北东向为主;而后者成矿年龄集中于170 Ma±,控岩控矿构造以北西向为主,预示钦杭成矿带东段2个成矿阶段(170~161 Ma B.P.)区域构造应力方向可能发生了重大转变。     

西藏蒙亚啊铅锌矿床成矿流体来源及特征

探讨西藏蒙亚啊铅锌矿床成矿流体来源及其特征,结合区域典型矿床研究厘定矿床成因类型。通过矿床近矿体蚀变灰岩和热液成因方解石碳-氧同位素及成矿不同期次石英氢-氧同位素分析手段,结合流体包裹体岩相学、温度和盐度测试研究,分析了矿床成矿流体的特征及成矿流体来源。结果表明,成矿早期流体以岩浆水为主,成矿晚期有大量天水混入;主成矿期成矿流体总体具有中高温和中低盐度特征,成矿从早期到晚期流体降温趋势明显。矿床形成与岩浆作用关系密切,矿床类型属于远接触端夕卡岩型铅锌矿床。     

Minerogenetic mechanism of Rushan gold deposit, Shandong Province——Evidence of ore-forming fluid and H, O, Sr isotopes

granite, quartz-vein type gold deposit, ore-forming fluid, origin of deposit.     

Single grain Rb-Sr dating of euhedral and cataclastic pyrite from the Qiyugou gold deposit in western Henan, central China

The Rb-Sr isotopic dating of pyrite mineral from ore deposits can directly provide mineralization age. However, many geological factors may affect the Rb-Sr isotopic system,which baffles application of this method. Employing ultra-low procedural blank Rb-Sr method,we have dated pyrites separated from the No. 4 breccia pipe of the Qiyugou gold deposit,western Henan Province. Single grains of euhedral pyrite crystal with few microcracks yield an isochron age of 126 ± 11 Ma, which represents time of the main mineralization stage of the deposit. Pyrite grains of cataclastic type show nevertheless scattered Rb-Sr isotopic composition and no reasonable isochron can be defined. Crystal morphology and mineral inclusion studies reveal that Rb and Sr of pyrite mineral probably are preserved mainly in biotite, K-feldspar, and sericite mineral inclusions. The dating results likely suggest that cataclastic pyrite is not suitable for the Rb-Sr dating due to modification of the Rb-Sr isotopic system by later hydrothermal activity of fluid.     

Molybdenum isotopic composition as a tracer for low-medium temperature hydrothermal ore-forming systems: A case study on the Dajiangping pyrite deposit,western Guangdong Province,China

Little is known about the range or controls on the molybdenum isotopic composition of low-medium temperature hydrothermal ore-forming systems. We present molybdenum isotope data from 12 hydrothermal syndepositional silicalite and carbonaceous slate samples from the Dajiangping pyrite deposit in western Guangdong Province, South China. The δ ^97/95 Mo values from Orebody III range from −0.02‰ to 0.29‰, with an average of 0.18‰. In contrast, the composition values from Orebody IV display a larger variation from −0.70‰ to 0.62‰. However, the five samples from the main ore bed all show strong negative values. This indicates that the significant variation in molybdenum isotopic composition supports different hydrothermal ore-forming metallogenesis and a metallogenic environment between the two orebodies. Orebody III is likely to have been deposited from submarine exhalative hydrothermal fluids under a relatively strong reducing environment and Orebody IV may have also been influenced by hydrothermal superimposition in a more oxidized disequilibrium condition. In addition, the δ ^97/95 Mo values of Orebody IV are clearly negative, together with the values increasing stratigraphically upward in the ore beds, suggesting that the metallogenic environment of Orebody IV is different from the open oceanic systems. There might be dynamic fractionation in this restricted environment. Therefore, the molybdenum isotope can be used as an effective tracer for the ore-forming fluid and metallogenic environment.     

西成矿田洛坝矿床含矿层物性特征及成矿条件分析

采用压汞分析技术对秦岭多金属成矿带西成矿田洛坝铅锌矿床含矿层各岩系的物性特征进行了研究,结果表明含矿层各岩系物性特征具有孔隙度小、渗透率低、孔喉连通性差的特点,这一特征对洛坝大型矿床的形成是极为不利的.结合该矿床成矿期盆地水体较浅的特征,可以说明后期的构造运动对洛坝矿床的形成起了决定性作用.一方面,后期构造运动除了形成褶皱和断裂外,还形成大量的微裂隙、缝隙、虚脱部位,为洛坝矿床的形成提供了储集空间;另一方面,后期构造运动形成的断裂、微裂隙、缝隙提高了孔隙间的连通性,使水岩反应得以进行,成矿元素从碳酸盐岩地层中淋滤出来随成矿流体运移参与成矿.     

班公湖—怒江成矿带西段尕尔穷铜金矿床辉钼矿Re-Os年龄及其地质意义

尕尔穷铜金矿床的夕卡岩矿体之下陆续发现花岗斑岩脉,该花岗斑岩与夕卡岩存在密切的成生联系.通过辉钼矿的Re-Os同位素年龄测定技术,确定其成矿年龄为86.79 Ma,成矿时代是晚白垩世,矿床形成于班公湖—怒江洋盆向南俯冲碰撞和雅鲁藏布江洋盆向北俯冲碰撞的间歇期;狮泉河结合带在晚白垩世处于同碰撞期,大量中酸性岩浆岩侵位事件...     

The Rb-Sr isochron of ore and pyrite sub-samples from Linglong gold deposit, Jiaodong Peninsula, eastern China and their geological significance

Here we report the first direct Rb-Sr dating of pyrites and ores using sub-sampling from lode gold deposits in Linglong, Jiaodong Peninsula, which is a supra-large lode gold deposit and propose this as a useful geochronological technique for gold mineralization with poor age constraint. The Rb-Sr data of pyrites yield an isochron age of (121.6±8.1) Ma, whereas those of ore and ore-pyrite spread in two ranges from 120.0 to 121.8 Ma and from 110.0 to 111.7 Ma. Studies of characteristic of gold deposit and microscopy of pyrite and quartz indicate that the apparent ages of ore and ore-pyrite are not isochron ages, only mixed by two end members, i.e. the primitive hydrothermal fluids and wall rocks, whereas the isochron age of pyrite sub-samples constrains the age of gold mineralization (121.6±8.1) Ma, i.e. early Cretaceous, which is in good agreement with the published SHRIMP zircon U-Pb ages.     

新疆东天山三岔口铜矿床同位素组成及成矿物质来源示踪

三岔口铜矿床位于新疆东天山大南湖岛弧带内,为近年来新发现的一个中型矿床。根据新疆东天山三岔口铜矿矿区出露地层从古到新有下石炭统干洞组、中石炭统梧桐窝子组和中新统桃树组。矿床类型为斑岩型。矿体形态主要为细脉状、浸染状,矿化发育于雁列花岗闪长斑岩及石英闪长玢岩中,该岩体受北东东向脆韧性剪切带控制。矿石矿物以黄铜矿为主,其次为黄铁矿、辉钼矿、辉铜矿。铜矿化主要发育于石英-黄铜-黄铁矿脉。三岔口铜矿床硫化物中的黄铜矿和黄铁矿进行S、Pb同位素组成分析,S同位素黄铜矿的δ34S变化范围在0.1‰~0.2‰之间;黄铁矿的δ34S变化范围在0.4‰~0.5‰之间,从矿物的同位素组成上看,表现出幔源硫特点。Pb同位素黄铜矿的206Pb/204Pb值为18.2345~18.2663、207Pb/204Pb值为15.6033~15.6197、208Pb/204Pb值为37.8136~37.8725;黄铁矿的206Pb/204Pb值为18.1779~18.1937、207Pb/204Pb值为15.5917~15.5998、208Pb/204Pb值为37.7563~37.7782。根据铅同位素构造环境演化图解及参数综合分析,表明铅来自于壳幔物质混合。通过对三岔口铜矿床地质特征、成矿物质来源研究,认为三岔口铜矿床属于斑岩型矿床。     

河南老湾金矿床流体包裹体及稀土元素地球化学研究

老湾金矿床产于中元古界龟山组,主要岩性为二云石英片岩和斜长角闪片岩。矿体受NWW向的韧脆性构造和NE向及NW向的次级构造控制,呈似层状、层状和脉状产出。矿床流体包裹体研究表明,成矿流体具有中-低温度、低盐度和低密度特征;流体包裹体液相成分中富含K+、Na+,二者比值显示成矿流体主要为岩浆水。矿床、围岩和老湾花岗岩的稀土元素研究认为,成矿物质主要来源于围岩和花岗岩。     

云南普朗超大型斑岩铜矿特征及成矿模型

普朗斑岩铜矿床位于义敦岛弧带南端,是中国目前可以确定的印支期斑岩铜矿床的典型代表.矿床产于由石英闪长玢岩、石英二长斑岩小岩株组成的复式岩体中,通过野外观察和典型地质体的辉钼矿Re-Os年龄、黑云母Ar/Ar年龄和K-Ar年龄测定,确定成矿年龄为(213±3.8)～(216.0±1) Ma,为晚三叠世诺利期,表明普朗斑岩铜矿床的成矿作用在印支期完成.含矿岩体蚀变分带明显,由中心向外发育强硅化带(局部)→钾长石、黑云母化带→石英、绢云母化带→青磐岩化带(局部发育伊利石-碳酸岩化带).工业矿体主要产于石英二长斑岩中的钾长石、黑云母化带和石英、绢云母化带.矿床具有斑岩铜矿中下部细粒状浸染、中上部细网脉状浸染和顶部围岩中产出大脉状矿体的"三层楼"模式.其斑岩体、元素组合及矿化特征与蒙古的欧玉·陶勒盖斑岩铜矿可以对比,资源潜力巨大.     

川西丹巴燕子沟金矿床流体包裹体特征及矿床成因

燕子沟金矿床位于四川省丹巴县,大地构造位置位于扬子准地台西缘,松潘-甘孜造山带东缘.泥盆系危关组炭质千枚岩、板岩是主要的赋矿围岩.成矿过程分为沉积成矿期、热液期和风化期,其中热液期是金的主要成矿期.流体成矿过程包括3个阶段:石英-金硫化物阶段、硫盐-金(银)石英阶段和铅锌硫化物-金-碳酸盐阶段.流体包裹体以VCO2、LCO2和LH2O三相与两相包裹体为主,主要是H2O-CO2三相水溶液包裹体,另有纯液相和含CO2单相包裹体存在.金的成矿作用主要发生在中温(285～295 ℃)、浅成(0.11～0.92 km)、低盐度(w(NaCl) =2.22％～9.21％)、低密度(0.75～0.85 g/cm3)的物理化学条件下,岩浆岩体与矿化关系密切,既为成矿提供热源,也提供了一定的物质来源,并与大气降水共同作用,从而形成了沉积-热液改造型浅成中温金矿床.     

西南天山金锑成矿带成矿远景

中国新疆西南天山是中亚南天山金和有色金属成矿带的东延部分,成矿潜力巨大.分析了区域成矿背景,总结了金、锑成矿规律,划分了6个成矿带和15个金、锑成矿区,对4个重点成矿区的成矿远景进行了分析.指出萨瓦亚尔顿河上游、乌兰赛尔-萨恨托亥、乌什北山、哈尔克成矿带的西北部、查汗萨拉、卡拉脚古牙应作为首批重点研究和找矿靶区.提出穆龙套型金矿应作为主攻类型,对于锑矿应重视碳酸盐岩与碎屑岩接触部位的破碎带,并注意锑与其他金属的共生规律.