冀北退变榴辉岩的Pb同位素特征

冀北退变榴辉岩的全岩Pb同位素比值(206Pb/204Pb)i,(207Pb/204Pb)i和(208Pb/204Pb)i分别为17.324～17.460,15.412～15.464和37.216～37.380;△(207Pb/204Pb)i和△(208Pb/204Pb)i相应为4.026～8.034和61.285～69.928,表明岩浆源区为具DUPAL异常的富集地幔,可能为亏损的软流圈地幔(DMM)与第一类富集地幔端元(EMI)相混合的异常地幔,指示该区早先存在有一次板块消减事件.这对正确认识华北古陆块北缘的大地构造格局和演化具有十分重要的意义.     

Occurrence of Neoproterozoic low-grade metagranite in the western Beihuaiyang zone,the Dabie orogen

Based on detailed field investigations and petrographic observations, we discovered Neoproterozoic-emplaced granite from the metavolcanics of the Dingyuan Formation in the western Beihuaiyang zone, the Dabie orogen. This study reports the results of zircon U-Pb dating and preliminary petrographic observations on two metagranite samples. The studied rocks experienced epidote-amphibolite facies metamorphism and strong structural deformation. Their U-Pb ages are 726 ± 6 and 758 ± 12 Ma, respectively, similar to those for the Luzhenguan complex in the eastern segment of the Beihuaiyang zone. In combination with previously determined 635 ± 5 Ma low-grade metagabbro, this study suggests the occurrence of at least two types of Neoproterozoic intrusive rocks in the Beihuaiyang zone, the northern margin of the South China Block (SCB): 726–758 Ma metagranite and 635 Ma metagabbro. These rocks occur within the metamorphosed Ordovician volcanic zone (originally named the Dingyuan Formation) and are in tectonic contact to each other, but they formed in different tectonic settings. The protolith ages for the Neoproterozoic low-grade metaigneous rocks are in good agreement not only with ages for two episodes of mid- and late-Neoproterozoic mafic and felsic magmatism in the Suizhou and Zaoyang area, Hubei Province, but also agree with protolith ages of ultrahigh-pressure metaigneous rocks in the Dabie-Sulu orogenic belt. In view of their tectonic relationships to country rocks, it appears that these Neoproterozoic low-grade rocks are exotic and they may have been detached and scraped from subducting SCB crust in the early Triassic during the initial continental subduction, and thrusted over Paleozoic metamorphosed rocks in the southern margin of the North China Block during continental collision.     

Pb-Pb isotope dating of black shales from the Lower Cambrian Niutitang Formation, Guizhou Province, South China

Withthedevelopmentofnewanalyticaltech niquesandstate of artinstruments ,isotopetracinganddatingmethodshavemadeconsiderableprogressinrecentyears .Inparticular ,variouskindsofradio genicisotopedatingmethodshavebeenappliedsuc cessfullyinigneousrocks.However,directdatingofsedimentaryrocksremainsundevelopedandcontro versial.Inmostcases ,researchersapplyU PbandK ArorAr Armethodstodatingvolcanicashesthatareinterbeddedwithinsedimentarystratainanattempttoobtaintheageofsedimentsindirectly[1] .Howev e…     

Isotopic composition of helium in eclogite from the Dabie Mountains, central China and its geological significance

Isotopic geochemical characteristics of helium in garnet and omphacite of eclogite in the Dabie Mountains are discussed. Concentrations of³He and⁴He in garnet and omphacite are 3.9 × 10⁻¹⁴–24.0 × 10⁻¹⁴ and 0.48 × 10⁻⁷–9.42 × 10⁻⁷cm¹³.g⁻¹, respectively. Values of³He/⁴He have a range of (1.19–4.63) × 10⁻⁷. Helium In the eclogite is derived from both mantle and crust. Isotopic geochemical data of helium indicate that eclogite in the Dabie Mountains might be formed in depleted mantle and the age of the cologite would be Indo-China epoch.     

Isotope composition of helium in eclogite from the Dabie Mountains, central China and its geological significance

Isotopic geochemical characteristics of helium in garnet and omphacite of eclogite in the Dabie Mountains are discussed. Concentrations of 3He and 4He in garnet and omphacite are 3.9×10 -14- 24.0×10 -14 and 0.48×10 -7-9.42×10 -7cm+3·g -1, respectively. Values of 3He/ 4He have a range of (1.19-4.63)×10 -7. Helium in the eclogite is derived from both mantle and crust. Isotopic geochemical data of helium indicate that eclogite in the Dabie Mountains might be formed in depleted mantle and the age of the cologite would be Indo-China epoch.     

Determination and geological significance of the eclogites from the northern Dabie Mountains, central China

Numerous eclogite-amphibolite blocks have been found along the Mayanling fault in the northern Dabie complex. Most of the eclogites are strongly retrograded and contain garnet, rutile and the amphibole-plagioclase symplectite. The occurrence of these eclogites may have something to do with the inverted movement of the Mayanling thrust fault.     

Adakites related to subduction in the northern margin of Junggar arc for the Late Paleozoic: Products of slab melting

Volcanic rocks with adakitic compositional signature have been recognized in the northern margin of ancient Junggar island arc for the Late Paleozoic. These adakites for the early Devonian from the Tuoranggekudouke Group (D_1t) are characteristic of high Sr, Sr/Y and (La/Yb)_N but low Y, Yb and HREE. Their compositional characteristics are much similar to those of the typical adakites in the world but distinct from those of the normal arc volcanic rocks from the same Group. We conclude that these adakitic volcanic rocks were produced by slab melting during the early period of Paleoasia-ocean lithosphere subduction. This infers that the Paleoasia Ocean in the north Junggar area began a new subduction process in the early Devonian.     

华北克拉通北缘早白垩世岩石圈减薄: 钾玄岩的Pb同位素证据

内蒙古四子王旗地区出露的早白垩世玄武岩属于钾玄岩。岩石富集大离子亲石元素（LILE）、轻稀土元素（LREE）,亏损高场强元素（HFSE）,其地球化学特征总体与洋岛玄武岩(OIB)相似。w(Rb)/w(Nb)、w(K)/w(Nb)、w(Zr)/w(Nb)、w(Th)/w(Nb)和w(Th)/w(La)比值主要落在EM1-OIB范围内。w(²⁰⁶Pb)/w(²⁰⁴Pb)、w(²⁰⁷Pb)/w(²⁰⁴Pb)和w(²⁰⁸Pb)/w(²⁰⁴Pb)分别变化在17.18～17.81, 15.40～15.50和37.54～38.05之间,岩石的Pb同位素组成接近EM1型地幔端元。随着Pb含量(质量分数)的增加,Pb同位素比值几乎没有变化,表明四子王旗钾玄岩没有经历明显的地壳物质混染。钾玄质母岩浆源于软流圈地幔的减压低度部分熔融。四子王旗钾玄岩是华北克拉通岩石圈减薄事件的产物。     

鄂尔多斯北部杭锦旗探区上古生界烃源岩评价

鄂尔多斯盆地北部杭锦旗探区上古生界烃源岩问题争议大。通过有机地球化学分析、盆地模拟等方法手段对研究区上古生界烃源岩展开研究。结果表明,上古生界发育石炭系、二叠系两套烃源岩,煤层是最好的烃源岩,泥岩为差烃源岩。煤层有机碳的质量分数最高,平均值为61.32%;有机质类型好,以Ⅲ型干酪根为主,属于生气型源岩;有机质成熟度为0.8%~1.3%,已经进入生气高峰阶段。烃源岩生气强度为(0.1~1.3)×109m3/km2,具备为研究区天然气成藏提供物质基础的条件。盆地模拟结果表明山西组总生气量大于太原组,是主要的烃源岩层系。烃源岩从侏罗纪末进入大规模生烃阶段,生烃高峰为早白垩世。研究区石炭系和二叠系煤层是上古生界天然气成藏的主要气源岩,天然气组分中甲烷含量变化、天然气侧向运移距离等证据进一步佐证了上述观点,突出了研究区上古生界烃源岩的原地性特征。     

豫西栾川中鱼库锌(铅)矿床闪锌矿Rb-Sr年龄及其地质意义

中鱼库矽卡岩型锌(铅)矿床位于华北陆块南缘河南省西部栾川Mo-W-Pb-Zn-Ag多金属矿集区南部,矿体呈层状-似层状赋存于新元古界栾川群三川组碎屑岩、碳酸盐岩地层中.因缺乏精确的成矿年代学研究,对该矿床成因的争议较大.本文在矿床地质背景和岩石矿物学研究的基础上,对13件矿石样品中的闪锌矿进行Rb-Sr同位素年代学研究.闪锌矿87 Rb/86 Sr和87 Sr/86 Sr同位素比值分别集中在0.802～18.98和0.713 359～0.748 684,二者具有良好的线性关系;其等时线年龄为(136.4士0.8) Ma (2σ,MSWD=3.6),(87 St/86 Sr)t=0.711 913士0.000 074.Rb-Sr同位素年龄反映该矿床形成于早白垩世,稍晚于研究区内的斑岩-矽卡岩型Mo-W矿床(146士2 MaB.P.),与区内最后一阶段花岗质岩浆活动(142～136MaB.P.)有关,属于栾川Mo-W-Pb-Zn-Ag多金属成矿系统.结合区域资料,认为该矿床形成于中生代陆-陆碰撞过程中由挤压向伸展转变的阶段,或碰撞后造山的局部伸展背景.     

南兴安岭晚中生代火山岩的岩石成因(II):Pb同位素制约

 对南兴安岭地区晚中生代火山岩的Pb同位素进行了分析,结合其主微量元素和Sr-Nd同位素地球化学特征,探讨了火山岩的岩石成因。满克头鄂博组低钾拉斑-钙碱性玄武安山岩表现出富集LILE、LREE和HFSE亏损元素地球化学特征以及稍高放射性成因Sr、Pb (⁸⁷Sr/⁸⁶Sr=0.704 88～0.704 99; ²⁰⁶Pb/²⁰⁴Pb=18.18～18.23)和弱相对亏损至弱富集的Nd同位素组成(ε_Nd((t)=-0.12～+0.68),其来源于俯冲沉积物参与改造富集地幔熔融源区。该组的英安岩-流纹岩较基性岩浆具有稍高放射性成因Sr、Pb (⁸⁷Sr/⁸⁶Sr=0.705 22～0.707 09; ²⁰⁶Pb/²⁰⁴Pb=18.16～18.33)和低Nd同位素组成 (ε_Nd(t))=-1.5～-0.4), 且在空间上与玄武岩共生,为玄武质岩浆结晶分异,并同化混染作用 (AFC)的产物。玛尼吐组英安岩具有与现代俯冲带adakite岩石相似的特征;在Sr-Nd-Pb同位素组成上,它们较同期或近期玄武安山岩更低Sr、Pb (⁸⁷Sr/⁸⁶Sr=0.704 09~0.704 25;²⁰⁶Pb/²⁰⁴Pb=18.15~18.17)和高Nd同位素比值(ε_Nd((t))=+0.9~+2.1),为造山带下地壳镁铁质岩石的部分熔融产物。     

Stable carbon isotope compositions of isoprenoid chromans in Cenozoic saline lacustrine source rocks from the Western Qaidam Basin,NW China: Source implications

Although the distribution of mono-,di-and trimethylated 2-methyl-2-(4,8,12-Trimethyltrideeyl) chromans(MTTCs) is well understood as an indicator of water salinity,their origin and formation mechanism are still ambiguous and under debate.In this paper,abnormally high levels of MTTCs were detected in Cenozoic saline lacustrine source rocks from the Western Qaidam Basin.Using a two-step column chromatography method,the MTTCs and naphthalenes were separated from other aromatic compounds and concentrated in one fraction,so that the stable carbon isotope compositions of these compounds could be accurately measured.Similar carbon isotope ratios for the mono-,di-and trimethylated 2-methyl-2-(4,8,12-Trimethyltrideeyl) chromans in a given sample suggest the MTTCs may share the same biological source(s).The MTTCs from the Western Qaidam Basin have similar carbon isotope compositions to primary producer-derived pristane and phytane.However,the ? 13C values for the MTTCs showed significant differences with other primary producers-derived biomarkers(e.g.C27 and C29 steranes),probably indicating a distinct microalgae source from specific niches for the MTTC compounds.We speculate that the MTTCs distribution patterns may be controlled by the water chemistry dynamics in niches,which,in turn,is affected by hypersaline bottom water.     

Petrogenesis of the Neoproterozoic bimodal volcanic rocks along the western margin of the Yangtze Block： New constraints from Hf isotopes and Fe/Mn ratios

High-precision major element and Hf isotope data are reported for the Neoproterozoic Suxiong volcanic rocks along the western margin of the Yangtze Block. These volcanic rocks have variable εHf（T） values and Fe/Mn ratios. The relatively primitive basalts have high Fe/Mn ratios and high Hf-Nd isotopic compositions, indicating that they were generated by partial melting of garnet clinopyroxene in mantle plume at high pressure. Thus, the Suxiong basalts are genetically related to the proposed Neoproterozoic superplume. On the contrary, a few differentiated basalts have low Fe/Mn ratios and low Hf-Nd isotopic compositions. They are likely to experience assimilation-fractional crystallization process. The Suxiong rhyolites have consistent Hf and Nd model ages of 1.3-1.4 Ga. They are likely generated by shallow dehydration melting of pre-existing young arc igneous rocks associated with the basaltic underplating/intrusion in a continental rift.     

东秦岭-大别造山带南缘印支期以来构造层序耦合特征分析

通过对东秦岭-大别山造山带南缘鄂东地区、荆当盆地、秭归盆地和川东北地区三叠纪-古近纪的构造层序对比研究,划分出三个大的构造层序,并分析了中上扬子地区印支期以来沉积盆地性质转换和迁移过程与构造层序的耦合关系,揭示了东秦岭-大别造山与成盆作用过程.认为早三叠世至中三叠世构造层序Ⅰ记录了扬子地台由克拉通盆地逐渐萎缩的过程,反映了印支期华北板块与扬子板块之间软碰撞未造山的过程;晚三叠世至早白垩世构造层序Ⅱ记录了前陆盆地的三次幕式演化过程,反映了早燕山期华北板块与扬子板块之间呈斜向、剪刀式由东向西陆-陆碰撞关闭以及前展逆冲叠置造山作用过程,与江南逆冲带联合作用形成前陆盆地沉降和沉积中心向西的迁移.晚白垩世至古近纪区域构造背景发生重大变化,构造层序Ⅲ记录了晚燕山期地壳快速均衡隆升,伸展断陷盆地形成演化过程.     

Paleomagnetism of early Paleozoic volcanic rocks from the Beishan area,Gansu of northwest China: Preliminary insight into early Paleozoic kinemics of the Beishan terrane

We report rock magnetic and paleomagnetic results for Middle Silurian Gongpoquan and Middle Ordovician Huaniushan volcanic samples collected from the Mazongshan and Hongliuyuan areas of Gansu Province, northwest China. The resultsindicate that the main magnetic mineral of the Gongpoquan and Huaniushan volcanic rock is magnetite, and it may remain characteristic remanent magnetization acquired at the time of formation of the rocks. However, with the exception of samples from site go20, most of Middle Ordovician Huaniushan volcanic samples have a very weak nature remanent magnetization, and generally show an erratic demagnetization behavior, which does not allow isolation of characteristic remanent magnetizations from these samples. Comparison of paleomagnetic results obtained from the Beishan area of Gansu with Paleozoic apparent polar wander paths for Tarimand Siberia suggests that the Beishan tarrane, the southern part of the Beishanarea of Gansu beyond the Mingshui-Shipanjin-Xiaohuang- shan zone, and adjacent Tarim block and Siberia plate could not have been connected in their present configuration by the Middle Silurian time. On the other hand, we infer that the early Paleozoic Mingshui-Shipanjin-Xiaohuangshan oceanic basin may open from west to east during period from the Ordovician to Silurian, and the post-Middle Silurian closing of this oceanic basin may result from a progressed eastward scissor-like rotation.     

Diachroneity of continental subduction and exhumation: Constraints from the Permian-Triassic HP metamorphic terrane in the Tongbai orogen, central China

High-pressure （HP） metamorphic terrane in the Tongbai orogen comprises two HP slices （I and II） and a tectonic m61ange zone in the northeast and a blueschist-greenschist zone in the southwest. HP slice I is represented by the northern and southern eclogite zones on the two sides of the Tongbaishan antiform. HP slice II is represented by retrograded eclogite-bearing metamorphic en- claves in Cretaceous gneissic granites in the Tongbai Complex. U-Pb, Lu-Hf, Rb-Sr and 4Ar/39Ar multichronometric data indi- cate that the peak metamorphism of HP slice I took place at -255 Ma, whereas the metamorphic ages of HP slice II are as young as 232-220 Ma. By contrast, the tectonic melange zone near the suture was metamorphosed at -256 Ma. Such a diachroneity of dif- ferent slices across the direction of the orogen in the Hong＇an-Dabie-Sulu HP/UHP terrane is ubiquitous, and it can be interpreted by a syn-subduction detachment/exhumation model. Furthermore, the metamorphic age of HP slice I in the Tongbai orogen is older than that of the equivalent HP slice in the Hong＇an orogen by ~15 Ma, suggesting that the diachroneity may have also ex- isted along the direction of the orogen. A seesaw-type subduction/exhumation model is proposed to explain this age disparity and the subduction of the South China Block becomimg shallower towards the west.     

K-Ar dating of late Mesozoic volcanism and geochemistry of volcanic gravels in the North Huaiyang Belt, Dabie orogen: Constraints on the stratigraphic framework and exhumation of the northern Dabie orthogneiss complex

Two eruption episodes are identified through systematic field investigations and K-Ar dating of the lateMesozoic volcanic rocks in the North Huaiyang belt (NHB),Dabie orogenic belt, of which the earlier volcanic suitetermed Maotanchang Fm. (Fm.) occurring at Jinzhai,Xianhualing and Maotanchang, etc., was erupted from 149Ma to 138 Ma. The other named Xiaotian Fm. mainly dis-tributed at Xiaotian, Shucheng, etc., was formed between132 Ma and 116 Ma. During the eruption gap of the two vol-canic suites deposited a volcano-sedimentary conglomeratelayer, which are composed of the multi-compositional gravels, including the North Dabie orthogneiss complex (NDOC),volcanic gravels, etc. These volcanic gravels in the con-glomerate layer show identical geochemical and isotopic compositions (87Sr/86Sr(t) =0.7084-0.7092, (Nd (t) = 21.8-24.4) to the Maotanchang Fm. volcanic rocks (87Sr/86Sr = 0.7086-0.7102, (Nd = 19.2-24.4), but significantly distinct from those of Xiaotian Fm. (87Sr/86Sr = 0.7076-0.7084, (Nd = 17.2 - 19.2). K-Ar dating results of its underlying andoverlying volcanic sequences indicate that the conglomerate layers were deposite d at ~135 Ma. This suggests that the NDOC was rapidly exhumed to the surface dur ing or shortly before ~135 Ma and became the important provenance of the late Me sozoic volcano-sedimentary basins in the NHB. In combination with the regional v olcano-sedimentary correlation, we divided the Mesozoic stratigraphic sequence i n the NHB from base to top into Fanghushan Fm. (>160 Ma), Yuantongshan Fm. (/mid dle- lower segment of Sanjianpu Fm.) (160-149 Ma), Maotanchang Fm. (/Zhougongsh an Fm./upper segment of Sanjianpu Fm./Fenghuangtai Fm.) (149-135 Ma) and Xiaoti an Fm. (/Baidafan Fm./Heshidu Fm.) (135-116 Ma).     

鄂尔多斯盆地西缘北段上古生界储集层研究

在鄂尔多斯盆地西缘北段上古生界储层地质研究的基础上,通过大量实验分析研究,揭示了本区储集层的孔隙结构特征,划分出高孔渗粗喉型、高孔渗中细喉—中孔渗中细喉型、中孔中低渗细喉型、中低孔低渗细微喉型和中低孔低渗微喉型5个主要孔隙结构类型。认为：溶解、机械压实、压溶、构造应力及重力、沉积物成分、自生矿物是影响孔隙发育的6种主要因素;储层孔渗性的好坏主要受溶孔含量高低的控制;最有利的储集区为桌子山地区,次为盆地内缘部托克旗以北广大地区;最好的储集层为太原组,次为山西组、下石盒子组及上万盒子组下部。