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1.
The phase relations at the 600℃ and 700℃ isothermal sections of the ternary systems R-Co-B for R= Nd, Pr and R = Sm, Gd respectively were summarized in this paper. For Rm+ n Co5m+3n B2n, two new types ofcompounds R3Co13B2(R=Pr, Nd, Sm, Gd, Dy, Ho, Er, Y) (m=2, n=1) andR5Co19B6(R=Pr, Nd) (m=2,n = 3 ) were synthesized by utilizing the principle of structural combination. Their crystalstructures and easymagnetization direction were determined by X-ray powder diffraction, and structures were refined by the Rietveldmethod. The Curie temperature Tc, saturation magnetization M8 and anisotropic field HA of the new compounds weremeasured using a vibrating-sample magnetometer, an extraction sample magnetometer and M(H) - H curves of samplesin different magnetization directions respectively. The Tc and Ms of Rm + n Co5 m + 3 n B2n increase with increasing values of mat a given n value. HA increases with an increase in n when m is kept invariable. The effects of the substitution of Ni for Co on the magnetic properties of Nd13 Co15- x Nix B2 were also investigated. It was found that TsR decreased monotonously as the concentration of Ni increased, and at x = 3 the easy magnetization direction becomes axial at room temperature. The relations between crystal structure and magnetic properties of Rm + nCo5m+ 3nB2n and the possible routes of synthesizing permanent magnetic materials are also discussed. 相似文献
2.
H.K.Liu S.H.Zhou S.Soltanian J.Horvat A.V.Pan M.J.Qin X.L.Wang M.Ionescu S.X.Dou 《清华大学学报》2003,8(3):307-315
The discovery of superconductivity in magnesium diboride (MgB2) has opened up a new field in materials science research. It offers a possibility of a new class of high performance superconducting materials for practical applications because of the relatively low cost of fabrication, high critical current densities (Jc)and fields, large coherence length, absence of Weak links, higher Tc (Tc = 39 K) compared with Nb3Sn and Nb-Ti alloys (two or four times that of Nb3Sn and Nb-Ti alloys). However, the weak flux pinning in the magnetic field remains a major challenge. This paper reports the most interesting results on nenomaterial (SiC and Si) doping in magnesium diboride. The high density of nano-scele defects introduced by doping is responsible for the enhanced pinning. The fabrication method, critical current density, microstructures, flux pinning and cost for magnesium diboride bulks, wires and tapes are also discussed. It is believed that high performance SiC doped MgB2 will have a great potential for many practical applications at 5K to 25K up to 5T. 相似文献
3.
The structural and magnetic properties of essentially phase pure AlFe_2B_2 prepared by arc melting were compared with a sample containing impurities. Analysis was carried out by means of synchrotron X-ray diffraction, magnetic measurements and M?ssbauer spectroscopy. The analysis of synchrotron X-ray diffraction data confirmed the orthorhombic structure of space group Cmmm for AlFe_2B_2 with Al_(13)Fe_4 as main impurity phase. The magnetic measurements revealed an unsaturated ferromagnetic state in AlFe_2B_2 with a transition temperature(T_c) of 286 K. Isothermal magnetization measurment at 5 K gave a saturation magnetization of 0.7 μB per Fe atom while Arrott plots establish the second order nature of ferromagnetic transition. The thermal evolution of M?ssbauer spectra confirmed the ferromagnetic nature of this material revealing an hyperfine field of 73 kOe and an isomer shift of 0.46 mm/s at 100 K. The M?ssbauer spectra of a phase pure sample was compared with the one containing impurity phases. It is suggested that the low temperature paramagnetic contribution in M?ssbauer spectra of phase pure material may have its origin in some intrinsic phenomena arising from defects or inhomogeneities in crystal structure. 相似文献
4.
Hole carrier mediated magnetization in Cu-doped GaN is investigated by using the first-principles calculations.By studying the sp-d interaction and the direct exchange interaction among the dopants,we obtain an equation to determine the spontaneous magnetization as a function of the Cu dopant concentration and the hole carrier density.It is demonstrated that nonmagnetic Cu doped GaN can be of room-temperature ferromagnetism.The system’s Curie temperature Tc can reach about 345 K with Cu concentration of 1.0% and hole carrier density of 5.0×1019 cm-3.The results are in good agreement with experimental observations and indicate that ferromagnetism in this systems is tunable by controlling the Cu concentration and the hole carrier density. 相似文献
5.
A new type Ni-P hollow material with rod-shape is prepared by electroless deposition method and heat treatment based on the shape of Nocadia, a kind of bacteria. The material is characterized and its magnetic, electromagnetic and mechanical properties are measured. It is found that the Ni-P coating transforms from a disordered structure before hollowing to an ordered arrangement of face centered cubic (FCC) Ni after hollowing at 673 K and body centered tetragonal Ni3P occurs. After hollowing no change of the surface morphology has been found. But the cytoplasm disappears and the Ni-P layer becomes more compact. A new type hollow material with shell thickness of 150-200 nm is obtained. The saturation magnetization (Ms), remanent magnetization (Mr) and coercivity (Hc) are enhanced to 20 emu/g, 2.7 emu/g and 117.5Oe, respectively. The dielectric and magnetic loss are improved to 14 and 0.4, respectively. The hardness and the elastic modulus are raised to 1.80 GPa and 23.79 GPa, respectively. All show great improvement compared with those before hollowing. 相似文献
6.
《科学通报(英文版)》2008,(20)
A new type Ni-P hollow material with rod-shape is prepared by electroless deposition method and heat treatment based on the shape of Nocadia, a kind of bacteria. The material is characterized and its magnetic, electromagnetic and mechanical properties are measured. It is found that the Ni-P coating transforms from a disordered structure before hollowing to an ordered arrangement of face centered cubic (FCC) Ni after hollowing at 673 K and body centered tetragonal Ni3P occurs. After hollowing no change of the surface morphology has been found. But the cytoplasm disappears and the Ni-P layer becomes more compact. A new type hollow material with shell thickness of 150―200 nm is obtained. The saturation magnetization (Ms), remanent magnetization (Mr) and coercivity (Hc) are enhanced to 20 emu/g, 2.7 emu/g and 117.5 Oe, respectively. The dielectric and magnetic loss are improved to 14 and 0.4, respectively. The hardness and the elastic modulus are raised to 1.80 GPa and 23.79 GPa, respectively. All show great improvement compared with those before hollowing. 相似文献
7.
ZnO:Cr layer was prepared by Cr ion implantation into ZnO bulk crystals. The structural, optical, and magnetic properties of the ZnO:Cr layer were studied with X-ray diffraction, photoluminescence, and superconductor quantum interferometer, respectively. The ZnO:Cr layer implanted Cr with a dose of 5 10 16 cm 2 remained wurtzite structure and exhibited near-band-edge photoluminescence at 3.365 eV with full-width at half-maximum of 8.4 meV at 10 K. The magnetic measurement showed that the ferromagnetism changed at room temperature by different Cr concentration. For samples implanted to high doses, remanent magnetization reached 1.805 10 -4 emu/g and coercive field was 244.5 Oe. Hall effect measurement showed a decrease of the resistivity from 251.7 cmto 28.6 cmafter annealing at 800 ℃. The magnetism is interpreted by bound magnetic polarons, which were taken into account of the process that electrons were locally trapped by oxygen vacancies and occupied the orbitals that overlapped with d shell of neighboring Cr ions. 相似文献
8.
MA Yanwei 《科学通报(英文版)》2006,51(21):2669-2672
We have investigated the effects of ZrC and ZrB2 doping on the superconducting properties of the powder-in-tube processed MgB2/Fe tapes. Sam- ples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM/EDX), transport and magnetic measurements. We confirmed the fol- lowing quite different roles of ZrC and ZrB2 in MgB2. ZrC doping was found to decrease the transport critical current density (Jc) at 4.2 K, while the critical temperature (Tc) kept constant. In contrast, the Jc values in magnetic fields were enhanced greatly by the ZrB2 addition, which resulted in a decrease in Tc by only 0.5 K. The reason for different effects of two dopants is also discussed. 相似文献
9.
In January of 2001 the superconductivity of the compound MgB2 with a critical temperature Tc of up to 39 K was discovered. This Tc is the highest in all intermetallic compound and alloy superconductors. MgB2 has a simple structure and its manufacturing capital cost is lower, therefore it could become a practical superconductor in the future. The recent progress is reviewed here which covers the progress in electronic structure, high Tc mechanism, superconducting parameters (Debye temperature, specific heat coefficient of electron, critical fields, coherent length, penetration depth, energy gap, critical current and relaxation rate of flux). Moreover the issue on power transmission is discussed. 相似文献
10.
The magnetic properties of highly grain-oriented electrical steel vary along different directions. In order to investigate these properties, standard Epstein samples were cut at different angles to the rolling direction. The hard magnetization direction was found at an angle of 60° to the rolling direction. To compare the measured and fitting curves, when the magnetic field intensity is higher than 7000 A/m, it is appropriate to simulate the relation of magnetic permeability and magnetization angle using the conventional elliptical model. When the magnetic field intensity is less than 3000 A/m, parabolic fitting models should be used; but when the magnetic field intensity is between 3000 and 7000 A/m, hybrid models with high accuracy, as proposed in this paper, should be applied. Piecewise relation models of magnetic permeability and magnetization angle are significant for improving the accuracy of electromagnetic engineering calculations of electrical steel, and these new models could be applied in further industrial applications. 相似文献
11.
Ni(II)-dien complex was prepared and characterized by X-ray diffraction. The crystal belongs to triclinic system, space group
P-1, with crystallographic parametersa=0.888 13(18) nm,b=0.890 10(18) nm,c=1. 591 8(3) nm, α=77.71(3)°, β=89.12(3)°, γ=61.24(3)°,Z=2. The two dien molecules coordinate to the central Ni atom, the six nitrogen atoms form a distorted octahedron. Preliminary
pharmacological tests showed this complex had antitumor activity against HepG2 and HL-60 cell linesin vitro.
Foundation item, Supported by the National Natural Science Foundation of China (29972034)
Biography: Li Tao (1976-), male, Ph. D candidate, research direction: ophthalmology and chemicalbiology. 相似文献
12.
Ammoxidation of 3,4-dichlorotoluene (DCT) to prepare 3,4-dichlorobenzonitrile (DCBN) over silica supported vanadium phosphorus
oxide catalysts has been studied. On the VPO/SiO2 catalyst, the influence of the reaction temperature, the molar ratio of air/DCT, the molar ratio of NH3/DCT in the feed gas and the space velocity (v
1) on the conversion, yield and selectivity was observed. The most appropriate reaction condition is: reactionT=673 K,n(DCT):n(NH3):n(air)=1:7:30 andv
1=250 h−1. At this optimum reaction condition, the conversion of DCT is 97.8%; the molar yield of DCBN is 67.4%. It was found that
the addition of element phosphorus can improve the yield of DCBN compared with VO/SiO2 catalyst.
Foundation item: Supported by Youth Chen-Guang Project of the Committee of Science and Technology of Wuhan (20015005042)
Biography: Huang Chi(1972-), male, Ph D, Lecture, research direction: ammoxidation. 相似文献
13.
ZHAO Lihong TIAN Zhidong TANG Zheng WANG Ziyu ZHU Benpeng WANG Lili XIONG Rui SHI Jing 《武汉大学学报:自然科学英文版》2007,12(6):1039-1042
Polycrystalline samples of a novel spin-liquid compound Tb2Ti2O7 were prepared by a standard solid-state reaction. X-ray diffraction at room temperature confirms that the synthesized compound of Tb2Ti2O7 is single phase with cubic unit cell constant a0 of 1.015 44 nm. Magnetic susceptibility measurements in the temperature range between 100 and 300 K give an effective moment of 9.44 μB and Curie-Weiss temperature of 12.68 K, respectively, indicating the dominance of antiferromagnetic interactions. However, below 50 K, the magnetic behavior of Tb2Ti2O7 deviates from Curie-Weiss law, whose origin remains suspicion. 相似文献
14.
The giant magneto-optical Faraday effect of nanometer ferromagnetic metal-semiconductor matrix Fe-ln2O3 granular films prepared by the radio frequency sputtering are studied. The result shows that the Faraday rotation angle θF value of the granular film samples with Fe volume fraction x = 35% is of the order of 10^5(°)/cm at room temperature. Temperature dependence of the Faraday rotation angle θF of Fe0.35(In2O3)0.65 granular films shows that θF value below 10 K increases rapidly with the decrease of the temperature, and when T= 4.2 K, θF value is 106(°)/cm. Through the study of the dependence of low field susceptibility on temperature and the hysteresis loops at different temperatures, it has been found that when the temperature decreases to a critical point Tp = 10 K, the transformation of state from ferro-agnetic to spin-glass-like occurs in Fe0.35(In2O3)0.65 granular films. The remarkable increase of the Faraday rotation angle θF value of Fe0.35(In2O3)0.65 granular films below 10 K seems to arise from the sp-d exchange interaction of the granular film samples in the spin-glass-like state. 相似文献
15.
JIANG Huiming ZHANG Shubiao JIN Rongchao MA Yunhua 《武汉大学学报:自然科学英文版》2007,12(6):1099-1104
Piperidine absorbs CO2 and H2O in air to form a molecular complex: piperidium-l-piperidinecarboxylate-H2O. The structure of the complex was characterized by X-ray single crystal diffraction. The crystal structure was determined to be triclinic, space group P1^-with a=0.648 6(8) nm, b=0.809 200) nm, c= 1.357 1(16) nm, a=96.96706)°, β =102.506(15)°,γ=104.202 05)°, Z=2. The complex is stabilized via five hydrogen bonds between the three components, N-O electrostatic interaction and O-O interaction (electron transfer) betweenl-piperidinecarboxylate and H2O. Due to electron transference of carbamate ion, the oxygen atom in water molecule is strongly negatively charged and the O-H bond is considerably shorter than that of the free molecule of water. The formation of the molecular complex is a reversible process and will decompose upon heating. The mechanism of formation and stabilization is further investigated herein. 相似文献
16.
ZHANG XianPing MA YanWei GAO ZhaoShun YU ZhengGuang WANG DongLiang WATANABE K GUO JianDong 《科学通报(英文版)》2007,52(18):2477-2480
Nano-SiC doped MgB2 tapes were prepared by the in situ powder-in-tube method. Heat treatment was performed at 650℃ for 1 h. XRD data indicate that SiC particles had reacted with the MgB2 during sintering process. MgB2 core seemed to be denser after SiC doping, and the critical temperature was slightly depressed. The critical current density Jc of the SiC doped tapes was significantly enhanced in magnetic fields up to 14 T compared to the undoped ones. For the 5% SiC doped samples, Jc was in- creased by a factor of 32 at 4.2 K, 10 T. The enhancement of Jc-B properties in SiC doped MgB2 tapes is considered to be due to the enhancement of grain linkages and the introduction of effective flux pining centers. The substitution of B by C in MgB2 grains is thought to be the main reason for the improve- ment of the flux pinning ability in SiC doped MgB2 tapes. 相似文献
17.
Synthesis and crystal structure of new supramolecular adducts of [PtCl6]2− with cucurbit [7] uril: [(H3O)2 (PtCl6)]3 (C42H42N28O14)2·H2O 总被引:1,自引:0,他引:1
A novel supramolecular adduct [(H3O)2 (PtCl6)]3 (C42H42N28O14)2·H2O (1) was synthesized by mixing [PtCl6]2− and cucurbit [7] uril in solution of hydrochloric acid. The crystal structure was determined by single crystal X-ray diffraction
analysis. The crystal belongs to orthorhombic system and space group F dd2 with cell dimensions:a=4. 705 33 (5) nm,b=7. 153 80 (6) nm,c=1. 894 61 (2) nm,Z=16,V=63, 7744 (11) nm3,D
c
=1.534 g/cm3, μ=3. 007 mm−1,F(000)=29 120,R
1=0.070 7,wR
2=0. 169 2. In crystal, the cucurb [7] uril molecules from two zig-zag chains.
Foundation item: Supported by the National Natural Science Foundation of China (20172040)
Biography: Yan kun (1977-), female, Master, research direction: macrocyclic chemistry. 相似文献
18.
XU Chao LI Guodong LI Xiaowei WANG Ligang 《科学通报(英文版)》2006,51(17):2046-2049
Iron-based rare-earth intermetallic compounds LaFe13?xSix (1.2≤x≤2.6) and CeFe13?xSix (2.4≤x≤2.6) both have the cubic NaZn13-type structure with Fm3c(Oh6) space-group symmetry[1―3]. Fujita et al. [4] demonstrated that the cubic NaZn13-type LaFe13?xSi 相似文献
19.
ShiChuang ZhuQuan-yao ShuHong JiangZhong-xing 《武汉大学学报:自然科学英文版》2004,9(1):105-108
Poly ( N, N, N-trimethyl ( 2-pyrrol-l-yl ) ethyl ammonium iodide )/V2O5 ( PTPAI/V2O5) nanocomposites were synthesized by sol-gel method. This method involved formation of vanadium pentoxide xerogel in the prcscnce of polypyrrole derivatives solution. X-ray diffraction(XRD) indicated that the polypyrrole derivative particles encapsulated in the fibrous V2O5 network and the layered distance significantly increased from 1. 077 39 to 1. 354 56 nm. The interaction between polypyrrole and V2O5 in the ‘nanocomposites‘ was characterized by IR spectroscopy. The Scanning Electron Microscope(SEM) micrographs reveal the structural contrasts between the hybrid materials and the pristine vanadium oxide xerogel. 相似文献
20.
ZHOURui ZHOUYan HUKai JIZhen-ping CHENGGong-zhen 《武汉大学学报:自然科学英文版》2005,10(3):572-576
Three different spin-lattice relaxation times ( T1 ) of water were obtained in activated alumina-water slurry system, which indicate that there exist three states of water: bound water, pore water and bulk water. The chemical shift (δ11) decreases as the amount of water added to the system increases due to the differences in contribution of these three states of water in the samples. The δ11 value for adsorbed water decreases nearly linearly and T1 increases with elevating temperature, which result from the decrease in the content of bound water by the increase in thermal motion. 相似文献