碳纳米管中氢等离子体的介电特性及微波吸收机理研究

运用双流体理论和唯象模型,导出了碳纳米管中氢等离子体的复介电常数和微波吸收系数,构建了铁催化高压歧化生成的碳纳米管中氢等离子体的微波吸收模型,从理论上证明了铁催化高压歧化生成的碳纳米管氢等离子体中的带电粒子对微波产生的碰撞吸收是其主要微波吸收机理,揭示了铁催化高压歧化生成的碳纳米管对2.45 GHz的微波产生强烈吸收的物理机制.     

铁磁性金属填充碳纳米管的微波吸收机理研究

深入探讨了铁磁性金属填充碳纳米管的微波吸收机理,对铁纳米粒子填充碳纳米管的微波吸收特性进行了数值模拟,计算了其自然共振频率,模拟结果与实验数据相吻合理论上证明了铁磁性金属填充碳纳米管对微波的强烈吸收主要是样品中铁磁性金属纳米粒子在微波作用下产生了磁共振的结果研究发现,随着铁磁性金属填充碳纳米管薄膜厚度的增加,其共振频率...     

蒽甲醇修饰单壁碳纳米管的研究

利用蒽甲醇对单壁碳纳米管进行了化学修饰，并利用透射电镜、紫外可见吸收光谱、荧光光谱、拉曼光谱对修饰后的单壁碳纳米管进行了表征分析．通过对比吸附前后的紫外可见吸收光谱发现，吸附后的光谱强度下降大约57．1％，说明单壁碳纳米管吸附上了蒽甲醇．通过拉曼光谱分析发现，吸附后单壁碳纳米管的拉曼光谱中主要峰的位置向长波方向移动了6～7cm^-1，认为拉曼光谱发生移动的原因是单壁碳纳米管吸附蒽甲醇前后状态的改变导致的．     

蒽甲醇修饰单壁碳纳米管的研究

利用蒽甲醇对单壁碳纳米管进行了化学修饰，并利用透射电镜、紫外可见吸收光谱、荧光光谱、拉曼光谱对修饰后的单壁碳纳米管进行了表征分析．通过对比吸附前后的紫外可见吸收光谱，发现吸附后的光谱强度约下降了57．1%左右，说明单壁碳纳米管吸附上了蒽甲醇．通过拉曼光谱分析，发现吸附后单壁碳纳米管的拉曼光谱中主要峰的位置向长波方向移动了6～7cm^-1，分析认为拉曼光谱发生移动的原因是单壁碳纳米管吸附蒽甲醇前后状态的改变导致的。     

Fe_2O_3分子与单壁碳纳米管之间相互作用的研究

文章采用密度泛函理论(DFT),研究了一个、两个Fe2O3分子在单壁碳纳米管(9,0),(10,0)和(14,0)内部的稳定结构和电子性质,获得了随着单壁碳纳米管直径的增加,结合能逐渐增大,而带隙却减小.且由于Fe2O3分子填充单壁碳纳米管内后两者之间发生了相互作用,使得电荷从单壁碳纳米管转移到了Fe2O3分子;与放入一个Fe2O3分子的单壁碳纳米管相比,放入两个Fe2O3分子时,分子和碳纳米管结合能更大,结构更稳定.     

导带弯曲对球形量子点光学性质的影响及压力效应

在有效质量近似下,采用三角势近似异质结界面处导带弯曲,并计及流体静压力效应,利用变分原理研究了有限高势垒GaN/AlxCa1-xN球形量子点杂质态一阶线性和三阶非线性光吸收系数随着电子面密度及流体静压力的变化关系.数值计算结果指出,随电子面密度的增加,吸收系数峰值的位置向短波方向移动(即蓝移),且一阶线性吸收峰随之增高,三阶非线性吸收峰随之降低;随压力的增加,吸收系数峰值的位置先向长波方向移动(红移),然后向短波方向移动(蓝移),且一阶线性吸收峰随之降低,三阶非线性吸收峰随之升高.结果表明,压力效应是明显的,导带弯曲效应是不可忽略的.     

氮掺杂(10,0)单壁碳纳米管的电子结构

利用密度泛函第一原理研究不同氮掺杂方式(10,0)单壁碳纳米管的电子结构. 当氮原子取代碳纳米管中的碳原子时, (10,0)单壁碳纳米管转变为n型半导体. 当氮原子吸附在碳纳米管表面时, (10,0)单壁碳纳米管转变为p型半导体, 同时与吸附氮原子相连碳原子的p轨道上的小部分电子被激发至d轨道上.      

大气压氩气微波等离子体参数的光谱诊断

为了深入了解大气压下氩气微波等离子射流内部电子的状态,利用发射光谱法对大气压下氩气微波等离子体进行了诊断.以玻尔兹曼斜率法对等离子体中电子激发温度进行测算,以斯塔克展宽计算电子密度.研究了等离子体射流方向上不同区域电子激发温度和电子密度的分布规律及微波功率对电子激发温度和电子密度的影响.结果表明,在本实验条件下等离子体射流电子激发温度为4 000～6 000 K,电子数量密度为(2.4～2.8)×1018 cm-3,电子激发温度和电子密度的最大值均出现在距波导管底边20 mm处,并以此处为中心,分别向上下2个方向呈现不完全对称的递减分布,微波功率增加影响等离子体电子密度和电子温度的交替上升.     

自由电子密度对等离子体隐身的影响

本文研究了不均匀非磁化等离子体片的自由电子密度与目标隐身的关系,给出不同等离子体自由电子密度分布时,对不同频段的雷达电磁波的衰减.研究发现,等离子体的自由电子密度应与雷达频率相关.雷达在高频、甚高频等低频段工作时,等离子体隐身的效果不理想;雷达工作在L、S、C、X等高频频段时,等离子体隐身效果显著.此外,我们发现对不同的雷达频率,等离子体存在一个最佳碰撞频率使入射电磁波衰减最大,该频率接近入射电磁波的频率.     

荷电对单壁碳纳米管稳定性的影响

采用基于密度泛函理论的DMol3程序对荷电的短开口单壁碳纳米管进行了结构优化计算. 结果表明, 体系的总能量随荷电量按抛物线规律变化, 体系的最高占据分子轨道能量随荷电量按线性规律变化, 碳管荷一定量负电荷时总能量最低, 碳管具有正的电子亲合势, 荷一定量负电荷的单壁碳纳米管比电中性的单壁碳纳米管结构更稳定. 荷电量较小时, 单壁碳纳米管的原子结构随荷电量的变化很小, 忽略碳管原子结构的变化仍能得到体系的总能量和最高占据分子轨道能量随荷电量变化的正确定性结果. 荷电量较大时, 开口单壁碳纳米管的端口原子结构首先受到影响, 形成喇叭口形状. 随着荷电量的增加, 碳管端口的原子结构将变得不稳定, 最终导致碳管原子结构的破坏.     

Markedness and its Interpretation in Language Use

Language markedness is a common phenomenon in languages, and is reflected from hearing, vision and sense, i.e. the variation in the three aspects such as phonology, morphology and semantics. This paper focuses on the interpretation of markedness in language use following the three perspectives, i.e. pragmatic interpretation, psychological interpretation and cognitive interpretation, with an aim to define the function of markedness.     

Features of Women's language

Language is a means of verbal communication. People use language to communicate with each other. In the society, no two speakers are exactly alike in the way of speaking. Some differences are due to age, gender, statue and personality. Above all, gender is one of the obvious reasons. The writer of this paper tries to describe the features of women＇s language from these perspectives： pronunciation, intonation, diction, subjects, grammar and discourse. From the discussion of the features of women＇s language, more attention should be paid to language use in social context. What＇s more, the linguistic phenomena in a speaking community can be understood more thoroughly.     

An Analysis of Catherine＇s Character——Wuthering Heights

Wuthering Heights, Emily Bronte＇s only novel, was published in December of 1847 under the pseudonym Ellis Bell. The book did not gain immediate success, but it is now thought one of the finest novels in the English language. Catherine is the key character of this masterpiece, because everybody and everything center on her though she had a short life. We can understand this masterpiece better if we know Catherine well.     

Lower Paleozoic oil relationships within Williston Basin, Canada

The Williston Basin is a significant petroleum province, containing oil production zones that include the Middle Cambrian to Lower Ordovician, Upper Ordovician, Middle Devonian, Upper Devonian and Mississippian and within the Jurassic and Cretaceous. The oils of the Williston Basin exhibit a wide range of geochemical characteristics defined as "oil families", although the geochemical signature of the Cambrian Deadwood Formation and Lower Ordovician Winnipeg reservoired oils does not match any "oil family". Despite their close stratigraphic proximity, it is evident that the oils of the Lower Palaeozoic within the Williston Basin are distinct. This suggests the presence of a new "oil family" within the Williston Basin. Diagnostic geochemical signatures occur in the gasoline range chromatograms, within saturate fraction gas chromatograms and biomarker fingerprints. However, some of the established criteria and cross-plots that are currently used to segregate oils into distinct genetic families within the basin do not always meet with success, particularly when applied to the Lower Palaeozoic oils of the Deadwood and Winnipeg Formation.     

低渗透非均质砂岩油藏启动压力梯度研究

理论推导与室内实验相结合,建立了低渗透非均质砂岩油藏启动压力梯度确定方法。首先借助油藏流场与电场相似的原理,推导了非均质砂岩油藏启动压力梯度计算公式。其次基于稳定流实验方法,建立了非均质砂岩油藏启动压力梯度测试方法。结果表明:低渗透非均质砂岩油藏的启动压力梯度确定遵循两个等效原则。平面非均质油藏的启动压力梯度等于各级渗透率段的启动压力梯度关于长度的加权平均;纵向非均质油藏的启动压力梯度等于各渗透率层的启动压力梯度关于渗透率与渗流面积乘积的加权平均。研究成果可用于有效指导低渗透非均质砂岩油藏的合理井距确定,促进该类油藏的高效开发。     

On Tragic Consciousness In The Works By Ernest Hemingway

As an American modern novelist who were famous in the literary world, Hemingway was not a person who always followed the trend but a sharp observer. At the same time, he was a tragedy maestro, he paid great attention on existence, fate and end-result. The dramatis personae's tragedy of his works was an extreme limit by all means tragedy on the meaning of fearless challenge that failed. The beauty of tragedy was not produced on the destruction of life, but now this kind of value was in the impact activity. They performed for the reader about the tragedy on challenging for the limit and the death.     

Design and analysis of generic LBS application developing platform

Location based services is promising due to its novel working style and contents.A software platform is proposed to provide application programs of typical location based services and support new applications developing efficiently. The analysis shows that this scheme is easy implemented, low cost and adapt to all kinds of mobile nework system.     

Achieving Unusual States of Matter Under High Pressure

正The periodicity of the elements and the non-reactivity of the inner-shell electrons are two related principles of chemistry,rooted in the atomic shell structure.Within compounds,Group I elements,for example,invariably assume the+1 oxidation state,and their chemical properties differ completely from those of the p-block elements.These general rules govern our understanding of chemical structures and reactions.Using first principles calcula-     

Exchange-Correlation and Electronic Excitation Energies from Pairing Matrix Fluctuations

We have developed an adiabatic connection to formulate the ground-state exchange-correlation energy in terms of pairing matrix linear fluctuations.This formulation of the exchange-correlation energy opens a new channel for density functional approximations based on the many-body perturbation theory.We illustrate the potential of such approaches with an approximation based on the particle-particle Random Phase Approximation(pp-RPA).This re-     

Density Functional Theory for the Response of Periodic Systems to Electric Fields Based on the Vector Potential Approach

正The electronic and nuclear(structural/vibrational)response of 1D-3D nanoscale systems to electric fields gives rise to a host of optical,mechanical,spectral,etc.properties that are of high theoretical and applied interest.Due to the computational difficulty of treating such large systems it is convenient to model them as infinite and periodic(at least,in first approximation).The fundamental theoretical/computational problem in doing so is that